Using durable materials is a sustainable solution for extending the lifetime of constructions. The use of crystalline admixtures makes cementitious materials more durable. They plug pores, capillary tracts and microcracks, blocking the entrance of water due to the formation of crystals that prevent the penetration of liquids. The literature has covered the performance of these admixtures on concrete, but studies on mortars are still scarce. The aim of this study is to investigate the effect of an aggressive environment (sulphuric acid solution—3 wt%) on mortars produced with different percentages of a crystalline admixture (1%, 1.5% and 2% by weight of cement content). Physical and mechanical properties were studied after immersing the mortars in a H₂SO₄ solution for 90 days. It was found that, after a 90-day sulphuric acid exposure, mortars with the crystalline admixture showed greater compressive strength than the control mortar, besides exhibiting lower mass loss. However, the crystalline admixture did not produce any significant effect on the capillary water absorption coefficient. In a nonaggressive environment, and in the short term, the crystalline admixture did not have a significant effect on the compressive strength, the capillary water absorption coefficient or the ultrasonic pulse velocity.

In view of the global sustainable development, it is imperative that supplementary cementing materials (SCM) be used for replacing cement in the concrete industry and several researchers have shown that mineral admixtures can enhance the workability of lightweight aggregate concrete (LWAC) mixture and its strength. In view of the beneficial effects of using SCM in LWAC, this article aims to verify the possible influence of the use of different types of SCM in the segregation phenomenon of LWAC. Three different SCM were studied: Silica Fume (SF), Fly Ash (FA) and Posidonia oceanica Ash (PA). For each SCM, three mixtures were prepared, considering three different percentage substitutions of cement. An image analysis technique was applied to estimate the segregation in each sample. The results show that a substitution of cement by other materials with different grain size, considering a constant water binder ratio, may also result in a variation of the consistency of concrete and the viscosity of the mortar matrix, which may contribute to increase or reduce segregation.

Lightweight aggregate concretes (LWAC) are versatile and interesting materials for projects that require greater structural efficiency. Due to the difference that exists between the densities of the materials used in these types of concrete, during transport and mainly compaction, their aggregates tend to separate from the mortar matrix, floating towards the surface, a phenomenon called segregation. Segregation in LWAC can affect its durability properties, its density, and directly affect its structural efficiency. In this work, different concrete densities (1700 kg/m³ and 1900 kg/m³) manufactured with different dosages (two different lightweight aggregates) and compaction methods (one or two layers) were analyzed to verify the impact of segregation on its structural efficiency. For this purpose, the segregation index of the LWAC was obtained by means of the image analysis technique. In addition, to obtain their structural efficiency, the density and compressive strength were obtained at different heights of the tested specimens. The results show the vibration of the samples in two layers leads to a more efficient elimination of trapped air, a reduction in the risk of segregation, and better structural efficiency.

Obtaining durable materials that lengthen the service life of constructions and thereby contribute to sustainability requires research into products that improve the durability of cementitious materials under aggressive conditions. This paper studies the effects of sulfuric acid exposure on four mortar types (control mortar, mortar with nanosilica, mortar with zinc stearate, and mortar with an ethyl silicate coating), and evaluates which of them have better performance against the acid attack. After 28 days of curing, the samples were exposed to a sulfuric acid attack by immersing them in a 3% w/w of H₂SO₄ solution. Physical changes (mass loss, ultrasonic pulse velocity, open porosity, and water absorption), and mechanical changes (compressive strength) were determined after the sulfuric acid exposure. A scanning electron microscope (SEM) was used to characterize the morphology of the surface mortars after the exposure. The control mortar had the highest compressive strength after the acid attack, although of the four types, the zinc stearate mortar showed the lowest percentage of strength loss. The zinc stearate mortar had the lowest mass loss after the acid exposure; moreover, it had the lowest capillary water absorption coefficient (demonstrating its hydrophobic effect) both in a non-aggressive environment and acid attack.