By using nc-Ni coatings as a model system, systematic experiments were designed to evaluate the interaction between the microstructural and mechanical properties tailored by electrodeposition conditions. A direct correlation between grain size and texture was established for the first time. The grain size of the (111) crystalline plane decreases with the texture coefficient (RTC) regardless of the process conditions, and that of the (220) plane has different trends. Then, a peculiar phenomenon is revealed that the dependence of hardness on grain size is accurately described by the Hall-Petch relationship when changing the temperature or pH, but with different slopes, while it deviates from such a relationship with changing current density, denoting more underlying mechanisms related to texture. Finally, a surprising degree of influence of texture on hardness and elastic modulus is also presented, with the overall trend of hardness increasing with texture; and when the RTC of (111) exceeds 40%, the elastic modulus increases with texture, implying a fundamental relationship between modulus and texture. Texture predominates over the other factors on the elastic modulus, revealing the importance of elastic anisotropy. Significantly, the present work suggests a useful tailoring routine to fabricate high quality nc-Ni coatings with the desired structure and mechanical properties.
A super-hydrophobic aluminum alloy surface with decorated pillar arrays was obtained by hybrid laser ablation and further silanization process. The as-prepared surface showed a high apparent contact angle of 158.2 ± 2.0° and low sliding angle of 3 ± 1°. Surface morphologies and surface chemistry were explored to obtain insights into the generation process of super-hydrophobicity. The main objective of this current work is to investigate the maximum spreading factor of water droplets impacting on the pillar-patterned super-hydrophobic surface based on the energy conservation concept. Although many previous studies have investigated the droplet impacting behavior on flat solid surfaces, the empirical models were proposed based on a few parameters including the Reynolds number (Re), Weber number (We), as well as the Ohnesorge number (Oh). This resulted in limitations for the super-hydrophobic surfaces due to the ignorance of the geometrical parameters of the pillars and viscous energy dissipation for liquid flow within the pillar arrays. In this paper, the maximum spreading factor was deduced from the perspective of energy balance, and the predicted results were in good agreement with our experimental results with a mean error of 4.99% and standard deviation of 0.10.