Considerable research has been conducted over recent decades on the role of non‑metallic inclusions and their link to the machinability of different steels. The present work reviews the mechanisms of steel fractures during different mechanical machining operations and the behavior of various non-metallic inclusions in a cutting zone. More specifically, the effects of composition, size, number and morphology of inclusions on machinability factors (such as cutting tool wear, power consumption, etc.) are discussed and summarized. Finally, some methods for modification of non-metallic inclusions in the liquid steel are considered to obtain a desired balance between mechanical properties and machinability of various steel grades.
1 January 2014 in Advances in Materials Science and Engineering
The characterization of nonmetallic inclusions is of importance for the production of clean steel in order to improve the mechanical properties. In this respect, a three-dimensional (3D) investigation is considered to be useful for an accurate evaluation of size, number, morphology of inclusions, and elementary distribution in each inclusion particle. In this study, the application of various extraction methods (chemical extraction/etching by acid or halogen-alcohol solutions, electrolysis, sputtering with glow discharge, and so on) for 3D estimation of nonmetallic Al2O3inclusions and clusters in high-alloyed steels was examined and discussed using an Fe-10 mass% Ni alloy and an 18/8 stainless steel deoxidized with Al. Advantages and limitations of different extraction methods for 3D investigations of inclusions and clusters were discussed in comparison to conventional two-dimensional (2D) observations on a polished cross section of metal samples.
In this study, CaO-containing wastes from pulp and paper industries such as fly ash (FA) and calcined lime mud (LM) were utilized to neutralize and purify acidic wastewaters from the pickling processes in steel mills. The investigations were conducted by laboratory scale trials using four different batches of wastewaters and additions of two types of CaO-containing waste materials. Primary lime (PL), which is usually used for the neutralization, was also tested in the same experimental set up in the sake of comparison. The results show that these secondary lime sources can effectively increase the pH of the acidic wastewaters as good as the commonly used primary lime. Therefore, these secondary lime sources could be potential candidates for application in neutralization processes of industrial acidic wastewater treatment. Moreover, concentrations of metals (such as Cr, Fe, Ni, Mo and Zn) can decrease dramatically after neutralization by using secondary lime. The LM has a purification effect from the given metals, similar to the PL. Application of fly ash and calcined lime mud as neutralizing agents can reduce the amount of waste from pulp and paper mills sent to landfill and decrease the need for nature lime materials in the steel industry.
Three CoCrFeMnNi high-entropy alloys (HEAs) were produced by vacuum induction melting, induction melting under inert gas atmosphere, and melting under inert gas atmosphere followed by air exposure, respectively. The different manufacturing conditions for the three investigated alloys resulted in different levels and types of inclusions. The alloys melted under vacuum or inert gas contained Al2O3 inclusions formed by impurity Al, due to its high oxidation tendency. The molten alloy exposed in air showed an excessive oxidation. During oxidation of the molten alloy in air, impurity Al was initially oxidized, and fine MnCr2O4 inclusions were formed rather than pure Al2O3 inclusions. This difference was analyzed based on thermodynamic calculations. Specifically, the influence of impurity content on the inclusion characteristics was investigated for the three HEAs. Moreover, the inclusion characteristics were found to have an influence on mechanical properties of the alloys also. In air-exposed HEA, smaller inclusions were formed, resulting in a higher dislocation density at the matrix/inclusion interface and thus strengthening of the HEA. Thus, it is proposed that atmospheric conditions could be an important factor to control the inclusion characteristics and to form fine inclusion particles, which could improve the mechanical properties of HEAs.