In this study, the influence of thermal treatments on the properties of the martensitic stainless steel X30Cr13 (EN 10088-3: 1.4028) were investigated. These steels are characterized by a high hardness as well as corrosion resistance and can be specifically adjusted by heat treatment. In particular, the austenitizing temperature ${\vartheta }_A$ and cooling rate $\dot{T}$ affect the hardness and corrosion properties of martensitic stainless steels. In order to investigate these influences, the Jominy end quench tests were performed at varying austenitizing temperatures. The aim is to determine the hardness and corrosion properties as a function of the austenitizing temperature and the cooling rate. The austenitizing temperature strongly influences the solubility of alloying elements within the austenitic lattice as well as the grain size, and thus affects both precipitation and phase transformation kinetics. In consequence, different austenitizing temperatures lead to different macroscopic material properties, like hardness and pitting corrosion potential. The heat treatment was simulated using finite element (FE) method and compared with time-temperature sequences measured at different locations of the Jominy end quench sample using thermocouples. That allows determining the cooling rate $\dot{T}$ between 800 ${}^{\circ }\mathrm{C}$ and 500 ${}^{\circ }\mathrm{C}$ and to assign it to each location of the Jominy end quench sample. The numerical estimations were in close conformity with the experimental values. By assigning the hardness and pitting corrosion potentials to the respective cooling rates as a function of the austenitizing temperature, it is possible to determine optimum process windows for the required properties.

In the pipe manufacturing and pipe processing industry, the demand for cost-effective pipes with high strength and good ductility is increasing. In the present study, the inductive longitudinal welding process was combined with a Quenching and Partitioning (Q&P) treatment to manufacture pipes with enhanced mechanical properties. The aim of the Q&P process is to establish a martensitic structure with increased retained austenite content. This allows for the beneficial use of both phases: the strength of martensite as well as the ductility of retained austenite. A 42SiCr steel, developed for Q&P processes, was joined at the longitudinal seam by a high-frequency induction (HFI) welding process and was subsequently heat-treated. The applied heat treatments included normalizing, austenitizing, quenching, and two Q&P strategies (Q&P-A/Q&P-B) with distinct quenching (T_q = 200/150 °C) and partitioning temperatures (T_p = 300/250 °C). Investigations of the microstructures revealed that Q&P tubes exhibit increased amounts of retained austenite in the martensitic matrix. Differences between the weld junction and the base material occurred, especially regarding the morphology of the martensite; the martensite found in the weld junction is finer and corresponds more to the lath-type morphology, compared to the base material in the circumference. In all zones of the welded tube circumference, retained austenite has been found in similar distributions. The mechanical testing of the individual tubes demonstrated that the Q&P treatments offer increased strength compared to all other states and significantly improved ductility compared to the quenched condition. Therefore, the approach of Q&P treatment of HFI-welded tubes represents a route for the mass production of high-strength tubular products with improved ductility.

Hot formed sheet components made of Martensitic Stainless Steels (MSS) can achieve ultra-high strengths in combination with very high corrosion resistance. This enables to manufacture complex lightweight sheet components with longer lifespan. Nevertheless, the hot formability of MSS sheets has not been accurately evaluated considering high temperatures and complex stress and strain states. In this work, the hot sheet formability of three MSS alloys under thermomechanical process conditions was investigated. Initially, mechanical properties of this sheet material were determined by uniaxial tensile test. Finite Element Method (FEM) simulation of a hot deep drawing process was performed under consideration of thermo physical calculated material models using the software JMatPro^® and Simufact Forming^® 15.0. The resulting strains and cooling rates developed locally in the work piece during the forming process were estimated. The numerical results were validated experimentally. Round cups were manufactured by hot deep drawing process. The resulting maximum drawing depth and hardness were measured. In general, all three alloys developed very good formability at forming temperatures between 700 and 900 °C and increased hardness values. However, they are highly susceptible to chemical composition, austenitization temperature, dwell time, and flange gap. A statistic approach is given to explain the correlation between hardness and its influencing factors.

The deep drawability of three Martensitic Stainless Steels (MSS) alloys under conventional press hardening thermomechanical process conditions was investigated. The three alloys differ in the content of the main elements C and Cr. Firstly, the metallurgical properties of the alloys were determined, i.e., the phase mass fraction diagrams and the concentration of alloying elements in solid solution at the austenitic temperatures with help of the JMatPro^® software version 7.0. Derived from this analysis, specific thermomechanical process parameters were defined to evaluate experimentally and numerically the hot sheet formability of the alloys during the deep drawing process. The hot deep drawability of the MSS alloys was experimentally assessed. The hot deep drawability was evaluated with the resulting maximum drawing depth values. In general, all three alloys developed very good formability at forming temperatures between 700 and 900 °C. However, they are susceptible to chemical composition, austenization temperature, dwell time, and flange gap. The hot formability behavior of the alloys as well as the resulting hardness showed very good concordance with the calculated metallurgical values. Finally, a numerical analysis was conducted using Simufact Forming^® 15.0 software. The interval time during hot blank transfer to the tool determines the initial and final forming temperature. The effect of the time interval on the forming temperature was analyzed numerically and validated experimentally. It was also possible to determine the maximum level of plastic strain in the deep drawn cup.

With the aim of analyzing the post-deformation Recrystallization (PDRX) of 22MnB5 steel and the grain size evolution after hot forming of the sheet and using the BAEHR 805 A/D thermo-mechanical simulator, several isothermal stress relaxation tests were performed in a temperature range of 800 to 950 °C, a predeformation range of 0.4 to 0.8 and a strain rate range of 0.01 to 0.8 s⁻¹. As a result of isothermal stress relaxation after deformation, PDRX kinetics can be described based on an Avrami equation as a function of temperature, degree of predeformation and strain rate. As the temperature increases, the recrystallization kinetics accelerates. The strain rate also has a positive influence on the fast PDRX. Predeformation has the opposite effect, as the consumption of stored energy occurred in predeformation process of relaxation tests. Furthermore, the microstructure evolution is described as a function of the predeformation parameters. The investigation of the microstructure after isothermal stress relaxation tests showed that the PDRX kinetics corresponds to the calculations. Furthermore, EBSD analysis helped to analyze the effects of certain stress relaxation conditions on the martensite morphology. The results indicate that a lower temperature and higher strain rate lead to fine martensite packages. In contrast, the martensite block width increases when applying higher strain rates.

The cushion-ram pulsation (CRP) technology offers a significant increase in formability by the novel stepwise deep drawing with holding pauses. The influence of different incremental drawing depths and breaks on the deep drawability of 22MnB5 during press hardening with CRP is investigated for unheated and heated tools. Softening induced by the holding times during hot forming with CRP can play a relevant role in achieving higher drawing depths and is consequently described. The forming analysis is carried out by means of FE simulation and experiments. The influence of softening on the improved forming capacity can consequently be quantified and a recommendation for the CRP technology in press hardening can be determined.