The Baode block on the eastern margin of the Ordos Basin is a key area for the development of low-rank coalbed methane (CBM) in China. In order to find out the genesis of CBM and its storage and seepage space in Baode block, the isotopic testing of gas samples was carried out to reveal the origin of CH₄ and CO₂, as well, mercury intrusion porosimetry, low temperature nitrogen adsorption, and X-ray CT tests were performed to characterize the pores and fractures in No. 4 + 5 and No. 8 + 9 coal seams. The results showed that the average volume fraction of CH₄, N₂, and CO₂ is 88.31%, 4.73%, and 6.36%, respectively. No. 4 + 5 and No. 8 + 9 coal seams both have biogenic gas and thermogenic methane. Meanwhile, No. 4 + 5 and No. 8 + 9 coal seams both contain CO₂ generated by coal pyrolysis, which belongs to organic genetic gas, while shallow CO₂ is greatly affected by the action of microorganisms and belongs to biogenic gas. The average proportion of micropores, transition pores, mesopores, and macropores is 56.61%, 28.22%, 5.10%, and 10.07%, respectively. Samples collected from No. 4 + 5 coal seams have developed more sorption pores. Meanwhile, samples collected from No. 8 + 9 coal seams exhibited a relatively low degree of hysteresis (Hg retention), suggesting good pore connectivity and relatively high seepage ability, which is conducive to gas migration. The connected porosity of coal samples varies greatly, mainly depending on the relative mineral content and the proportion of connected pores.

In order to clarify the characteristics of fine-grained sedimentary lithofacies and the depositional models in lacustrine environments of the Chang 7 Member of the Upper Triassic Yanchang Formation in the Ordos Basin, we focus on the lacustrine lithofacies classification and controlling factors. Based on the typical field sections of the southern Ordos Basin, combined with the methods of organic geochemical analysis, polarizing microscopic observation, XRD and elemental geochemistry, we summarize the main controlling factors of the lithofacies under different sedimentary environments and establish the sedimentary model under different sedimentary backgrounds. Results show that the Chang 7 Member of the Ordos Basin includes six major lithofacies types, i.e., quasi-laminated clayey shale facies, blocky silty mudstone facies, quasi-laminated silty shale facies, laminated silty shale facies, blocky mixed mudstone facies, and laminated argillaceous siltstone facies. Al₂O₃, MgO, CaO, Na₂O, K₂O, and SiO₂ are relatively depleted, while TiO₂, TFe₂O₃, and P₂O₅ are relatively enriched in the Chang 7₂₊₃. Meanwhile, the trace elements are relatively enriched in Cd, Cu, Mo, U, and V. The fine-grained sedimentary facies were influenced by various sedimentary environments, such as paleoclimate, redox conditions, productivity and terrigenous input. According to lithofacies types and genetic mechanisms of the Chang 7 Member in the study area, two types of lithofacies assemblages are identified. The rapid rise in lake level during the deposition of the Chang 7₂₊₃ resulted in an anoxic water column, high productivity, and low terrigenous input under a humid climate and weak-to-moderate weathering conditions. Therefore, clayey shale lithofacies assemblage is developed in the lower Chang 7 Member.

To increase the carbon conversion of char in gasification, this paper aimed to reveal the gasification behaviours of char residues. Char residues with different ash contents in this work were prepared from Shenmu char and Tejing char. Those char residues were gasified by different CO₂ gas mixtures at different temperatures. The gasification process of char residue was different from the end stage of the gasification process of the corresponding raw char: the gasification rate of the char residue increased at first and then decreased, whereas the gasification rate of the corresponding raw char kept decreasing during the end stage of gasification. The highest gasification rate was achieved at a lower conversion in the gasification of char residue than in the gasification of the corresponding raw char. Catalytic minerals, high temperature, and high CO₂ partial pressure benefited the gasification of gasified char residues. The char residues that contained more catalytic minerals were more reactive in gasification and were less sensitive to changes in temperature and CO₂ partial pressure. The Modified Random Pore Model (MRPM) and Random Pore Model (RPM) were used to predict the gasification kinetics of the chars, and the MRPM describes the gasification processes of gasified char residues well.

The study on the factors influencing the biogenic gas production of low rank coal beds is of great significance to the search of the favorable biogenic gas enrichment areas of similar coal beds and the guidance of the microbial stimulation technologies. In this paper, the lignite samples taken from the Jiergalangtu Sag in the Erlian Basin were selected to carry out the simulation experiment of biogenic coalbed methane under different temperatures, pH values, oxidation-reduction potentials (Eh) and trace element concentrations. Then, the influences on biogenic gas production were discussed and the optimal biogenic gas production condition was determined. And the following research results were obtained. First, in the simulation experiments, the biogenic gas production of coal beds increases first and then decreases with the increase of temperature, pH and trace element concentration and the decrease of Eh. Second, in the case of temperature 30–35 °C, pH 7.0–7.5 and Eh −225 mV, the metabolism of methanogen is the most active and the most favorable for the generation of biogenic gas, so biogenic gas production can be promoted by adding the trace elements (Fe²⁺ and Ni²⁺) of proper concentration. It is concluded that a proper burial depth (300–600 m), a weak runoff hydrodynamic condition and an anaerobic environment constitute the favorable conditions for the generation of biogenic gas in the Jiergalangtu Sag, Erlian Basin. Moreover, the addition of appropriate trace elements can be an effective means of microbial stimulation.

The evolution of fracture zone controls the safety of underground coal gasification (UCG) in terms of gas emission and water leakage. In order to understand the fracture propagation in the confining rock of a UCG cavity with various influence factors, this paper implemented a set of numerical models based on different geological and operating conditions. Analysis was implemented on the mechanism of fracture propagation and its evolution characteristics, suggesting that (a) continuum expansion of the cavity leads a near-field fracture circle in confining rock initially, followed by the roof caving and successive propagation of shear band. (b) The key observed influence factors of fracture propagation are the grade of confining rock, overburden pressure, dimension of the cavity and gasifying pressure, the linear relationships between them, and the fracture height. Additionally, the fracture depth in the base board was mainly caused by tensile fracture. (c) A model was proposed based on the evolution of fracture height and depth in roof and base board, respectively. Validation of this model associated with orthogonal tests suggests a good capacity for predicting fracture distribution. This paper has significance in guiding the design of the gasifying operation and safety assessment of UCG cavities.

Using carbon dioxide as a gasification agent for underground coal gasification (UCG) can not only reduce carbon dioxide emissions but is also expected to lead to a new natural gas technology revolution and ensure national energy security. To explore the effect of the oxygen content in oxygen-enriched carbon dioxide gasification agents on the results of gasification experiments, underground gasification experiments under different oxygen-enrichment conditions were designed, and quantitative parameters were used to analyze and evaluate the gas produced in the gasification experiments. The results showed that as the oxygen content in the oxygen-enriched carbon dioxide gasification agent increased, the CO and H₂ in the combustible gas gradually increased, and the calorific value of the combustible gas also slowly increased, reaching a peak value under the gasification condition of 60% oxygen concentration, and then decreased slightly; the product formation rate and the gas production per unit mass of coal fluctuated. The coal consumption rate increased with time and was relatively stable. According to theoretical calculations for the gasification energy recovery evaluation system, the overall energy recovery rate was 56.34%, and the energy utilization rate was relatively high. Research on quantitative indicators based on gas production data has good practical significance for evaluating the gasification efficiency of UCG, which can be used to better evaluate and control the reaction process of UCG.