The objective of this study was to assess the use of Concarpus biochar as a soil amendment for reducing heavy metal accessibility and uptake by maize plants (Zea mays L.). The impacts of biochar rates (0.0, 1.0, 3.0, and 5.0% w/w) and two soil moisture levels (75% and 100% of field capacity, FC) on immobilization and availability of Fe, Mn, Zn, Cd, Cu and Pb to maize plants as well as its application effects on soil pH, EC, bulk density, and moisture content were evaluated using heavy metal-contaminated soil collected from mining area. The biochar addition significantly decreased the bulk density and increased moisture content of soil. Applying biochar significantly reduced NH4OAc- or AB-DTPA-extractable heavy metal concentrations of soils, indicating metal immobilization. Conocarpus biochar increased shoot dry biomass of maize plants by 54.5-102% at 75% FC and 133-266% at 100% FC. Moreover, applying biochar significantly reduced shoot heavy metal concentrations in maize plants (except for Fe at 75% FC) in response to increasing application rates, with a highest decrease of 51.3% and 60.5% for Mn, 28% and 21.2% for Zn, 60% and 29.5% for Cu, 53.2% and 47.2% for Cd at soil moisture levels of 75% FC and 100% FC, respectively. The results suggest that biochar may be effectively used as a soil amendment for heavy metal immobilization and in reducing its phytotoxicity.

Limited water resources in arid and semi-arid regions require innovative management to maintain crop production while minimizing the amounts of water used for irrigation. We investigated the impact of the particle size of natural clinoptilolite zeolite (CZ) on water content (WC) and hydraulic properties of a loamy sand soil. WC was measured using 5TE sensors installed at five depths (10, 20, 30, 40, and 50 cm) in soil columns (7.4 cm ID, 56 cm length). Three sizes of macro- and nano-CZ particles (20, 2.0, and 0.2 µm) were added to the soil at an application rate of 1%. The columns were subject to 14 wetting/drying cycles from 24 February to 8 December 2020. The HYDRUS-1D model was used to simulate WC and soil water storage inside the soil columns. WC increased with the decreasing particle size of CZ, especially when columns were subject to long drying periods. The larger surface area and smaller pore size of CZ altered the pore-size distribution of the loamy sand soil and increased the amount of microporosity inside the soil system, leading to increased water retention. Available water and soil water storage were increased by 3.6–14.7% and 6.8–10.5%, respectively, with larger increases with the decrease in CZ particle size. Variations in infiltration rate and hydraulic conductivity were statistically significant only with the smallest CZ particle size, with a reduction of 25.6% and 19.3% compared to the control, respectively. The HYDRUS-1D model accurately simulated WC and soil water storage, with only slight overestimation of WC (2.4%) at depths ≤ 30 cm. The results suggest that, in light-textured soils, the application of CZ in the ultra-fine nanoparticle size would increase water-holding capacity and reduce hydraulic conductivity, which would enhance the efficiency of water use and contribute to water conservation in dry regions.

Surface modification of nanoscale zero-valent iron (nZVI) using polymer stabilizers (e.g., sodium carboxymethyl cellulose, CMC) is usually used to minimize aggregation, increase stability, and enhance transport of nZVI. We investigated the stability and dynamic aggregation of bare and CMC–nZVI as affected by variations in pH, ionic strength (IS), and nZVI particle concentration. CMC coating of nZVI resulted in smaller hydrodynamic size and larger zeta potential. The largest hydrodynamic size of nZVI was associated with bare nZVI at high IS (100 mM), pH close to the point of zero charge (PZC, 7.3–7.6), and larger particle concentration (1.0 g L⁻¹). The increase in the zeta potential of CMC–nZVI reached one- to four-fold of that for bare nZVI, and was greater at pH values close to PZC, high IS, and larger particle concentration. The stability of CMC–nZVI was increased by 61.8, 93.1, and 57.5% as compared to that of bare nZVI at IS of 1, 50 and 100 mM, respectively. Calculations of Derjaguin, Landau, Verwey and Overbeek (DLVO) interaction energy were in agreement with stability results, and showed the formation of substantial energy barriers at low IS indicating greater nZVI stability. Our results suggest that at IS above 50 mM and nZVI particle concentration larger than 0.1 g L⁻¹, the likelihood of nZVI aggregation is high. Nevertheless, CMC polymer stabilizer would enhance the stability and transport of nZVI even under these unfavorable solution chemistry conditions.

Improving the physical properties and water retention of sandy soils is of critical importance in arid and water-scarce regions such as Saudi Arabia. The impacts of organic amendments of different particle sizes coupled with natural clay deposits on improving the soil physio-chemical characteristics, nutrient availability, and growth of Sudan grass were investigated in this study. A loamy sand soil was amended with natural clay deposits at 2.5%, 5.0%, and 10% (w/w) application rates, and in combination with 1.0% (w/w) wheat straw of different particle sizes. The water infiltration, evaporation, and retention characteristics of the amended soil were studied for 9 weeks, and then Sudan grass was grown for 7 weeks. The impacts of the particle size of wheat straw on soil properties and nutrient availability were significant (p < 0.05) when combined with clay deposits. The highest application rate of clay (10%) demonstrated the highest water content (20.63–21.73%), and increased P and K availability to 35.54 and 6980 mg kg⁻¹, respectively, in soil, which were 33% and 88% higher, respectively, compared to the control. Plant N, P, and K concentrations were increased to 0.95%, 0.26%, and 4.33%, respectively, which were 2–3.5-fold higher than the control. Therefore, the integrated application of natural clay deposits and wheat straw of fine particle size could be an effective strategy in improving plant production in water-scarce regions.