The quasistable state in the photoinduced phase transition for the quasi-one-dimensional quarter-filled organic conductor has been examined by ultrafast reflective measurements and time-dependent model calculations incorporating both electron-electron and electron-phonon interactions. The transient optical conductivity spectrum over a wide probe photon-energy range revealed that photoexcitation induced a new type of charge-disproportionate state. Additionally, coherent and incoherent oscillations dependent on probe photon energies were found, as predicted by the calculation.
11 November 2014 in Chemistry – A European Journal
Radical anion salts of metal phthalocyanines (M = Cu II , Pb II , V IV O and Sn IV Cl 2 ) with the {cryptand(Na + )} cations have been obtained and studied.