The piezoelectric properties of PVDF mainly depend on its β-phase. In this work, we investigated through Piezoresponse Force Microscopy (PFM) the piezoelectric properties of PVDF composite films when we induce the formation of β-phase crystals adding a nanofiller, like graphene nanoplatelets (GNPs) or zinc-oxide nanorods (ZnO-NRs), but without applying any electrical poling. At first, we fabricated piezoelectric PVDF nanocomposite films by the solution casting method. Then, we investigated the piezoelectric response of the different samples produced and we investigated the correlation between piezoresponse, morphology and structural characteristics of the nanocomposite. The morphology of the produced samples was investigated through field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). The β-phase formation was assessed through Fourier Transform Infrared Spectroscopy (FT-IR) measurements.

Lightweight multifunctional electromagnetic (EM) absorbing materials with outstanding thermal properties, chemical resistance and mechanical stability are crucial for space, aerospace and electronic devices and packaging. Therefore, 3D porous graphene aerogels are attracting ever growing interest. In this paper we present a cost effective lightweight 3D porous graphene-based aerogel for EM wave absorption, constituted by a poly vinylidene fluoride (PVDF) polymer matrix filled with graphene nanoplatelets (GNPs) and we show that the thermal, electrical, mechanical properties of the aerogel can be tuned through the proper selection of the processing temperature, controlled either at 65 °C or 85 °C. The produced GNP-filled aerogels are characterized by exceptional EM properties, allowing the production of absorbers with 9.2 GHz and 6.4 GHz qualified bandwidths with reflection coefficients below −10 dB and −20 dB, respectively. Moreover, such aerogels show exceptional thermal conductivities without any appreciable volume change after temperature variations. Finally, depending on the process parameters, it is shown the possibility to obtain water repellent aerogel composites, thus preventing their EM and thermal properties from being affected by environmental humidity and allowing the realization of EM absorber with a stable response.