In this study, a melt-compounding process was used to produce ordinary polypropylene (PP)/thermoplastic polyurethane (TPU) blends and modified impact-resistant polypropylene (MPP)/TPU blends. The influences of TPU on the blending morphology, melting behavior, crystallization behavior, and mechanical properties of these blends were investigated. Differential scanning calorimetry results show that using TPU influences the crystalline and melting behavior of PP/TPU blends, but not of MPP/TPU blends. X-ray diffraction analysis indicated that the presence of TPU neither influences the crystalline structure of PP nor creates new crystalline peaks. The mechanical property test results revealed that PP/TPU blends demonstrate better tensile strength, Young’s modulus, and flexural strength, whereas MPP/TPU blends exhibit higher energy absorption and impact strength. This study is expected to produce optimal products with the preferred continuous and dispersive phases for end users, designing multiple and compatible functionalities of blends.
With the development of technology, fibers and textiles are no longer exclusive for the use of clothing and decoration. Protective products made of high-strength and high-modulus fibers have been commonly used in different fields. When exceeding the service life, the protective products also need to be replaced. This study proposes a highly efficient recycling and manufacturing design to create more added values for the waste materials. With a premise of minimized damage to fibers, the recycled selvage made of high strength PET fibers are reclaimed to yield high performance staple fibers at a low production cost. A large amount of recycled fibers are made into matrices with an attempt to decrease the consumption of new materials, while the combination of diverse plain woven fabrics reinforces hybrid-fabric fibrous planks. First, with the aid of machines, recycled high strength PET fibers are processed into staple fibers. Using a nonwoven process, low melting point polyester (LMPET) fibers and PET staple fibers are made into PET matrices. Next, the matrices and different woven fabrics are combined in order to form hybrid-fabric fibrous planks. The test results indicate that both of the PET matrices and fibrous planks have good mechanical properties. In particular, the fibrous planks yield diverse stab resistances from nonwoven and woven fabrics, and thus have greater stab performance.
This study proposes fabric composites with improved static and dynamic puncture via increasing a friction force to restrain the slide of filaments as well as the compression and abrasion between the fibers and the puncture probe. The the bi-layered shell layers of composite fabrics are composed of aramid staple fibers and nylon staple fibers and a layer of low-melting-point polyester (LPET). The nonwoven layer consisting of recycled aramid and nylon staple fibers provides a shear effect to dissipate part of the puncture energy. Reinforcing interlayers include a woven fabric and PET filaments that are circularly aggregated between the surface layers, providing isotropic filament reinforcement and strengthening the resistance against the tip of the puncture probe. The reinforcing filaments may slide after the employment of needle punching, and to compensate for this disadvantage, the LPET layers are used to thermal bond the composite fabrics and the total thickness is controlled at 2 mm. The thermally bonded fabric composites are evaluated in terms of puncture resistance, thereby examining the effects of fabric structure and thermal bonding. According to the test results, the optimal composite structure is the sample N/L/W/F/L/N, which was reinforced by the LPET adhesive layer and irregularly aligned filaments. The sample which used the LPET adhesive layer had a positive influence on static puncture resistance and dynamic puncture resistance, preventing the slide of filaments, but the poor interfacial combination only contributed to limited reinforcement.