In this study, synthesis and characterization of chitosan/maghemite (Cs/Fe₂O₃) composites thin film has been described. Its properties were characterized using Fourier transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and ultraviolet-visible spectroscopy (UV-Vis). FTIR confirmed the existence of Fe–O bond, C–N bond, C–C bond, C–O bond, O=C=O bond and O–H bond in Cs/Fe₂O₃ thin film. The surface morphology of the thin film indicated the relatively smooth and homogenous thin film, and also confirmed the interaction of Fe₂O₃ with the chitosan. Next, the UV-Vis result showed high absorbance value with an optical band gap of 4.013 eV. The incorporation of this Cs/Fe₂O₃ thin film with an optical-based method, i.e., surface plasmon resonance spectroscopy showed positive response where mercury ion (Hg²⁺) can be detected down to 0.01 ppm (49.9 nM). These results validate the potential of Cs/Fe₂O₃ thin film for optical sensing applications in Hg²⁺ detection.

Great efforts have been devoted to the invention of environmental sensors as the amount of water pollution has increased in recent decades. Chitosan, cellulose and nanocrystalline cellulose are examples of biopolymers that have been intensively studied due to their potential applications, particularly as sensors. Furthermore, the rapid use of conducting polymer materials as a sensing layer in environmental monitoring has also been developed. Thus, the incorporation of biopolymer and conducting polymer materials with various methods has shown promising potential with sensitively and selectively toward heavy metal ions. In this feature paper, selected recent and updated investigations are reviewed on biopolymer and conducting polymer-based materials in sensors aimed at the detection of heavy metal ions by optical methods. This review intends to provide sufficient evidence of the potential of polymer-based materials as sensing layers, and future outlooks are considered in developing surface plasmon resonance as an excellent and valid sensor for heavy metal ion detection.

The emergence of unintentional poisoning and uncontrolled vector diseases have contributed to sensor technologies development, leading to the more effective detection of diseases. In this study, we present the combination of graphene-based material with surface plasmon resonance technique. Two different graphene-based material sensor chips were prepared for rapid and quantitative detection of dengue virus (DENV) and cobalt ion (Co²⁺) as an example of typical metal ions. As the fundamental concept of surface plasmon resonance (SPR) sensor that relies on the refractive index of the sensor chip surface, this research focused on the SPR signal when the DENV and Co²⁺ interact with the graphene-based material sensor chip. The results demonstrated that the proposed sensor-based graphene layer was able to detect DENV and Co²⁺ as low as 0.1 pM and 0.1 ppm respectively. Further details in the detection and quantification of analyte were also discussed in terms of sensitivity, affinity, and selectivity of the sensor.

In this study, X-ray photoelectron spectroscopy (XPS) was used to study chitosan–graphene oxide (chitosan–GO) incorporated with 4-(2-pyridylazo)resorcinol (PAR) and cadmium sulfide quantum dot (CdS QD) composite thin films for the potential optical sensing of cobalt ions (Co²⁺). From the XPS results, it was confirmed that carbon, oxygen, and nitrogen elements existed on the PAR–chitosan–GO thin film, while for CdS QD–chitosan–GO, the existence of carbon, oxygen, cadmium, nitrogen, and sulfur were confirmed. Further deconvolution of each element using the Gaussian–Lorentzian curve fitting program revealed the sub-peak component of each element and hence the corresponding functional group was identified. Next, investigation using surface plasmon resonance (SPR) optical sensor proved that both chitosan–GO-based thin films were able to detect Co²⁺ as low as 0.01 ppm for both composite thin films, while the PAR had the higher binding affinity. The interaction of the Co²⁺ with the thin films was characterized again using XPS to confirm the functional group involved during the reaction. The XPS results proved that primary amino in the PAR–chitosan–GO thin film contributed more important role for the reaction with Co²⁺, as in agreement with the SPR results.

In this study, the incorporation of surface plasmon resonance (SPR) spectroscopy with novel chitosan-graphene oxide/cadmium sulphide quantum dots (CdS QDs) active layer for cobalt ion (Co²⁺) detection has been developed. The interaction of different Co²⁺ concentrations with the novel modified active layer was monitored using the SPR technique. From the SPR results, detection range, sensitivity, full width at half maximum (FWHM), detection accuracy (DA) and signal-to-noise ratio (SNR) have been analysed. The results showed the detection range of this optical sensor was 0.01 to 10 ppm, and it was saturated for higher concentration of Co²⁺. The sensitivity obtained was 0.1188 ppm⁻¹ for low concentration of Co²⁺ ranged from 0.01 to 1 ppm. The FWHM and DA were consistent for all concentration of Co²⁺, while the SNR of the SPR signal increased with the Co²⁺ concentration. The SPR angle shifts were also fitted using Langmuir, Freundlich and Sips (Langmuir-Freundlich) isotherm models, where Sips model fitted the best with the binding affinity of 0.939 ppm⁻¹. The results proved that the novel chitosan-graphene oxide/CdS QDs modified gold thin film can detect Co²⁺ via SPR spectroscopy.

In this research, surface plasmon resonance (SPR) spectroscopy was used for sensing copper ion by combining the SPR with nanocrystalline cellulose modified by hexadecyltrimethylammonium bromide and graphene oxide composite (CTA-NCC/GO) thin film. The binding of Cu²⁺ on CTA-NCC/GO thin film was monitored by using SPR spectroscopy. By using the obtained SPR curve, detection range, binding affinity, sensitivity, full width at half maximum (FWHM), data accuracy (DA), and signal-to-noise ratio (SNR) have been calculated. The results showed that the sensor detection range was 0.01 until 0.5 ppm, and that it reached a saturation value. Moreover, the resonance angle shift followed the Langmuir isotherm model with a binding affinity constant of 4.075 × 10³ M⁻¹. A high sensitivity of 3.271° ppm⁻¹ also was obtained for low Cu²⁺ concentration ranged from 0.01 to 0.1 ppm. For the FWHM, the lowest value calculated was at 0.08 and 0.1 ppm, which is 3.35°. The DA of the SPR signal consecutively highest at 0.08 and 0.1 ppm. Besides that, the SNR of the SPR signal increases with the Cu²⁺ concentrations. The CTA-NCC/GO thin film morphological properties were also studied by using atomic force microscopy. The rms roughness values, which were obtained before and after in contact with Cu^2+, were 3.51 nm and 2.46 nm, respectively.