A new retrieval of total column water vapour (TCWV) from daytime measurements over land of the Ocean and Land Colour Instrument (OLCI) on-board the Copernicus Sentinel-3 missions is presented. The Copernicus Sentinel-3 OLCI Water Vapour product (COWa) retrieval algorithm is based on the differential absorption technique, relating TCWV to the radiance ratio of non-absorbing band and nearby water vapour absorbing band and was previously also successfully applied to other passive imagers Medium Resolution Imaging Spectrometer (MERIS) and Moderate Resolution Imaging Spectroradiometer (MODIS). One of the main advantages of the OLCI instrument regarding improved TCWV retrievals lies in the use of more than one absorbing band. Furthermore, the COWa retrieval algorithm is based on the full Optimal Estimation (OE) method, providing pixel-based uncertainty estimates, and transferable to other Near-Infrared (NIR) based TCWV observations. Three independent global TCWV data sets, i.e., Aerosol Robotic Network (AERONET), Atmospheric Radiation Measurement (ARM) and U.S. SuomiNet, and a German Global Navigation Satellite System (GNSS) TCWV data set, all obtained from ground-based observations, serve as reference data sets for the validation. Comparisons show an overall good agreement, with absolute biases between 0.07 and 1.31 kg/m² and root mean square errors (RMSE) between 1.35 and 3.26 kg/m². This is a clear improvement in comparison to the operational OLCI TCWV Level 2 product, for which the bias and RMSEs range between 1.10 and 2.55 kg/m² and 2.08 and 3.70 kg/m², respectively. A first evaluation of pixel-based uncertainties indicates good estimated uncertainties for lower retrieval errors, while the uncertainties seem to be overestimated for higher retrieval errors.

The retrieval of sun-induced chlorophyll fluorescence is greatly beneficial to studies of marine phytoplankton biomass, physiology, and composition, and is required for user applications and services. Customarily phytoplankton chlorophyll fluorescence is determined from satellite measurements through a fluorescence line-height algorithm using three bands around 680 nm. We propose here a modified retrieval, making use of all available bands in the relevant wavelength range, with the goal to improve the effectiveness of the algorithm in optically complex waters. For the Ocean and Land Colour Instrument (OLCI), we quantify a Fluorescence Peak Height by fitting a Gaussian function and related terms to the top-of-atmosphere reflectance bands between 650 and 750 nm. This algorithm retrieves, what we call Fluorescence Peak Height by fitting a Gaussian function upon other terms to top-of-atmosphere reflectance bands between 650 and 750 nm. This approach is applicable to Level-1 and Level-2 data. We find a good correlation of the retrieved fluorescence product to global in-situ chlorophyll measurements, as well as a consistent relation between chlorophyll concentration and fluorescence from radiative transfer modelling and OLCI/in-situ comparison. Evidence suggests, the algorithm is applicable to complex waters without needing an atmospheric correction and vicarious calibration, and features an inherent correction of small spectral shifts, as required for OLCI measurements.

The aerosol layer height (ALH) is an important parameter that characterizes aerosol interaction with the environment. An estimation of the vertical distribution of aerosol is necessary for studies of those interactions, their effect on radiance and for aerosol transport models. ALH can be retrieved from satellite-based radiance measurements within the oxygen absorption band between 760 and 770 nm ($O_2$A band). The oxygen absorption is reduced when light is scattered by an elevated aerosol layer. The Ocean and Land Colour Imager (OLCI) has three bands within the oxygen absorption band. We show a congruent sensitivity study with respect to ALH for dust and smoke cases over oceans. Furthermore, we developed a retrieval of the ALH for those cases and an uncertainty estimation by applying linear uncertainty propagation and a bootstrap method. The sensitivity study and the uncertainty estimation are based on radiative transfer simulations. The impact of ALH, aerosol optical thickness (AOT), the surface roughness (wind speed) and the central wavelength on the top of atmosphere (TOA) radiance is discussed. The OLCI bands are sufficiently sensitive to ALH for cases with AOTs larger than 0.5 under the assumption of a known aerosol type. With an accurate spectral characterization of the OLCI $O_2$A bands better than 0.1 nm, ALH can be retrieved with an uncertainty of a few hundred meters. The retrieval of ALH was applied successfully on an OLCI dust and smoke scene. The found ALH is similar to parallel measurements by the Tropospheric Monitoring Instrument (TROPOMI). OLCI’s high spatial resolution and coverage allow a detailed overview of the vertical aerosol distribution over oceans.

We investigated whether Top-of-Atmosphere Shortwave (TOA SW) anisotropy—essential to convert satellite-based instantaneous TOA SW radiance measurements into TOA SW fluxes—is sensitive to cloud-top effective radii and cloud-topped water vapor. Using several years of CERES SSF Edition 4 data—filtered for overcast, horizontally homogeneous, low-level and single-layer clouds of cloud optical thickness 10—as well as broadband radiative transfer simulations, we built refined empirical Angular Distribution Models (ADMs). The ADMs showed that anisotropy fluctuated particularly around the cloud bow and cloud glory (up to 2.9–8.0%) for various effective radii and at highest and lowest viewing zenith angles under varying amounts of cloud-topped moisture (up to 1.3–6.4%). As a result, flux estimates from refined ADMs differed from CERES estimates by up to 20 W ${\mathrm{m}}^{-2}$ at particular combinations of viewing and illumination geometry. Applied to CERES cross-track observation of January and July 2007—utilized to generate global radiation budget climatologies for benchmark comparisons with global climate models—we found that such differences between refined and CERES ADMs introduced large-scale biases of 1–2 W ${\mathrm{m}}^{-2}$ and on regional levels of up to 10 W ${\mathrm{m}}^{-2}$. Such biases could be attributed in part to low cloud-top effective radii (about 8 μ$\mathrm{m}$) and low cloud-topped water vapor (1.7 kg ${\mathrm{m}}^{-2}$) and in part to an inopportune correlation of viewing and illumination conditions with temporally varying effective radii and cloud-topped moisture, which failed to compensate towards vanishing flux bias. This work may help avoid sampling biases due to discrepancies between individual samples and the median cloud-top effective radii and cloud-top moisture conditions represented in current ADMs.

The retrieval of sun-induced chlorophyll fluorescence is greatly beneficial to studies of marine phytoplankton biomass, physiology, and composition and is required for user applications and services. Customarily phytoplankton chlorophyll fluorescence is determined from satellite measurements through a fluorescence line-height algorithm using three bands around 680 nm. We propose here a modified retrieval, making use of all available bands in the relevant wavelength range with the goal to improve the effectiveness of the algorithm in optically complex waters. For the Ocean and Land Colour Instrument (OLCI) we quantify a Fluorescence Peak Height from fitting a Gaussian function and related terms into the top-of-atmosphere reflectance bands between 650 and 750 nm. This algorithm retrieves, what we call Fluorescence Peak Height from fitting a Gaussian function upon other terms to top-of-atmosphere reflectance bands between 650 and 750 nm. This approach is applicable to Level-1 and Level-2 data. We find a good correlation of the retrieved fluorescence product to global in-situ chlorophyll measurements, as well as a consistent relation between chlorophyll concentration and fluorescence from radiative transfer modelling and OLCI/in-situ comparison. The algorithm is applicable to complex waters without needing an atmospheric correction and vicarious calibration and features an inherent correction of small spectral shifts, as required for OLCI measurements.

A new algorithm for the retrieval of day-time total column water vapour (TCWV) from measurements of a MSG-SEVIRI (Meteosat Second Generation Spinning Enhanced Visible and Infrared Imager) instrument is presented. The retrieval is based on a forward operator, at the core of which lies Radiative Transfer for TIROS Operational Vertical Sounder (RTTOV). This forward model relates TCWV and surface temperature to brightness temperatures in the split window at 11 and 12µm with the use of a first guess for temperature and humidity profiles from the ERA5 reanalysis. The forward model is then embedded in a full Optimal Estimation (OE) method, which yields pixel by pixel uncertainty estimates and performance indicators. The algorithm is applicable to any instrument which features the split window configuration, given a first guess for atmospheric conditions (i.e., from NWP) and an estimate of surface emissivity at 11 µm. The algorithm was developed within the framework of RealPEP (Near-Realtime Quantitative Precipitation Estimation and Prediction) in which the advancement of the estimation and nowcasting of extreme precipitation and flooding in Germany are studied. Thus, processing and validation has been limited to the German domain. Three independent ground-based TCWV observation data sets were used as reference, i.e., AERONET (Aerosol Robotic Network), GNSS Germany (Global Navigation Satellite System) and measurements from two MWR (Microwave Radiometer) sites. The validation concludes with good agreement, with absolute biases between 0.11 and 2.85 kg/m${}^2$, root mean square deviations (rmsds) between 1.63 and 3.24 kg/m${}^2$ and Pearson correlation coefficients ranging from 0.96 to 0.98. The retrievals uncertainty estimates were evaluated against AERONET. The comparison suggests that, in sum, uncertainties are estimated well, while still some error sources seem to be over- and underestimated. In limited case studies it could be shown that SEVIRI TCWV is capable to both display large scale variabilities in water vapour fields and reproduce the daily course of water vapour exposed by ground-based observations.