Aqueous suspensions of goethite ( -FeOOH) nanorods form a mineral lyotropic nematic phase that aligns in a very low magnetic field (20 mT for samples 20 thick). The particles orient along the field direction at intensities smaller than 350 mT, but they reorient perpendicular to the field beyond 350 mT. This outstanding behavior is also observed in the isotropic phase which has a very strong magnetic-field induced birefringence that could be interesting for applications. We interpret these magnetic effects as resulting from a competition between a nanorod remanent magnetic moment and a negative anisotropy of its magnetic susceptibility.
This article confirms the existence of a strong linear relationship between turbidity and total suspended solids (TSS) concentration. However, the slope of this relation varies between dry and wet weather conditions, as well as between sites. The effect of this variability on estimating the instantaneous wet weather TSS concentration is assessed on the basis of the size of the calibration dataset used to establish the turbidity – TSS relationship. Results obtained indicate limited variability both between sites and during dry weather, along with a significant inter-event variability. Moreover, turbidity allows an evaluation of TSS concentrations with an acceptable level of accuracy for a reasonable rainfall event sampling campaign effort.
We performed small-angle X-ray scattering (SAXS) experiments on oriented samples of laponite clay gels obtained by slow evaporation. The SAXS patterns are clearly anisotropic, which demonstrates the existence of nematic-like orientational correlations of the laponite disc-like particles. The iso-intensity lines of the SAXS patterns are elliptical and roughly homothetic over the whole scattering vector range examined in this experiment. The value of the nematic order parameter, S =0 .55 ± 0.05, derived from the SAXS patterns is comparable to that of usual liquid crystals. This large value proves the importance of ori- entational correlations in these gels at concentrations higher than 0.02 g · cm−3 ,e ven in the absence of shear.