Despite the current boost in the use of electric vehicles to reduce the automotive sector’s footprint, combustion vehicles are and will be present in our cities in both the immediate and long term. In this sense, catalytic converters, which are exhaust gas post-treatment systems for vehicle emission control, are critical for complying with increasingly stringent environmental regulations. This work proposes a systematic review to identify the most relevant knowledge regarding the parameters (materials, geometries, and engine conditions), conditions (cold start, oxygen storage, and deactivation), and mathematical models to consider in the design of catalytic converters. The Scopus database contains 283 records related to this review’s objective. After applying the inclusion and exclusion criteria, 65 reports were retrieved for evaluation. A table was created to present the results and prepare this manuscript. The evaluation revealed that the following topics were active: the study of non-noble catalyst materials, as well as new substrate materials and geometries, for designing more compact and cost-effective catalytic converters; the development of strategies to improve conversion during cold starts; and the development of accurate and fast estimation models.

The majority of on-road vehicles today are powered by internal combustion engines, which are, in most cases, burning petroleum-derived liquid fuels mixed with bio-components. The power to weight ratio of internal combustion engines combined with the high energy content of conventional fuels, which can be refilled easily in matter of minutes, makes them ideal for all kinds of road transportation. Since the introduction of EURO emissions norms, the emissions from the Transport sector in the European Union have undergone significant reduction. There are several alternatives to fossil fuels with similar properties, which can replace their usage in the Transport sector. The main focus of research in recent decades has been on biofuels, which can be produced from several sources. The production of biofuels is usually energy more intensive than production of fossil fuels, but their usage can contribute to emission reduction in the Transport sector. In recent years, a lot of effort was also put into promotion of electric vehicles as zero emissions vehicles. This statement should be reconsidered, since the greenhouse impact of electrical vehicles is not negligible. Conversely, in some cases, an electrical vehicle can have an even higher emission impact than modern vehicles with sophisticated internal combustion engines. This is characteristic for countries where the majority of the electricity is produced in coal power plants. With the decrease of greenhouse gas emissions in the Electricity Production sector, and with the increase of battery capacity, the role of electric vehicles in the Transport sector will probably increase. Despite significant research and financial investments in electric vehicles development, the transport sector in near future will be mostly powered by internal combustion engines and petroleum-derived liquid fuels. The amount of pollution from transport sector will be further regulated with stricter emission norms combined with smaller amount of alternative fuel usage.