Despite the current boost in the use of electric vehicles to reduce the automotive sector’s footprint, combustion vehicles are and will be present in our cities in both the immediate and long term. In this sense, catalytic converters, which are exhaust gas post-treatment systems for vehicle emission control, are critical for complying with increasingly stringent environmental regulations. This work proposes a systematic review to identify the most relevant knowledge regarding the parameters (materials, geometries, and engine conditions), conditions (cold start, oxygen storage, and deactivation), and mathematical models to consider in the design of catalytic converters. The Scopus database contains 283 records related to this review’s objective. After applying the inclusion and exclusion criteria, 65 reports were retrieved for evaluation. A table was created to present the results and prepare this manuscript. The evaluation revealed that the following topics were active: the study of non-noble catalyst materials, as well as new substrate materials and geometries, for designing more compact and cost-effective catalytic converters; the development of strategies to improve conversion during cold starts; and the development of accurate and fast estimation models.
7 September 2020 in Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles
The majority of on-road vehicles today are powered by internal combustion engines, which are, in most cases, burning petroleum-derived liquid fuels mixed with bio-components. The power to weight ratio of internal combustion engines combined with the high energy content of conventional fuels, which can be refilled easily in matter of minutes, makes them ideal for all kinds of road transportation. Since the introduction of EURO emissions norms, the emissions from the Transport sector in the European Union have undergone significant reduction. There are several alternatives to fossil fuels with similar properties, which can replace their usage in the Transport sector. The main focus of research in recent decades has been on biofuels, which can be produced from several sources. The production of biofuels is usually energy more intensive than production of fossil fuels, but their usage can contribute to emission reduction in the Transport sector. In recent years, a lot of effort was also put into promotion of electric vehicles as zero emissions vehicles. This statement should be reconsidered, since the greenhouse impact of electrical vehicles is not negligible. Conversely, in some cases, an electrical vehicle can have an even higher emission impact than modern vehicles with sophisticated internal combustion engines. This is characteristic for countries where the majority of the electricity is produced in coal power plants. With the decrease of greenhouse gas emissions in the Electricity Production sector, and with the increase of battery capacity, the role of electric vehicles in the Transport sector will probably increase. Despite significant research and financial investments in electric vehicles development, the transport sector in near future will be mostly powered by internal combustion engines and petroleum-derived liquid fuels. The amount of pollution from transport sector will be further regulated with stricter emission norms combined with smaller amount of alternative fuel usage.
28 February 2022 in International Journal of Environmental Science and Technology
Numerical prediction of cavitation erosion is a great scientific and technological challenge. In the past, many attempts were made—many successful. One of the issues when a comparison between a simulation and erosion experiments is made, is the great difference in time scale. In this work, we do not attempt to obtain quantitatively accurate predictions of erosion process but concentrate qualitatively on cavitation mechanisms with quantitative prediction of pressure pulses which lead to erosion. This is possible, because of our recent experimental work on simultaneous observation of cavitating flow and cavitation erosion by high speed cameras. In this study, the numerical simulation was used to predict details of the cavitation process during the vapor collapse phase. The fully compressible, cavitating flow simulations were performed to resolve the formation of the pressure waves at cavitation collapse. We tried to visualize the mechanisms and dynamics of vapor structures during collapse phase at the Venturi geometry. The obtained results show that unsteady Reynolds-averaged Navier–Stokes (URANS) simulation of cavitation is capable of reproducing four out of five mechanisms of cavitation erosion, found during experimental work.
The presented paper aims to study the influence of mineral diesel fuel and synthetic Gas-To-Liquid fuel (GTL) on the injection process, fuel flow conditions, and cavitation formation in a modern common-rail injector. First, the influence on injection characteristics was studied experimentally using an injection system test bench, and numerically using the one-dimensional computational program. Afterward, the influence of fuel properties on internal fuel flow was studied numerically using a computational program. The flow inside the injector was considered as multiphase flow and was calculated through unsteady Computational Fluid Dynamics simulations using a Eulerian–Eulerian two-fluid approach. Finally, the influence of in-cylinder back pressure on the internal nozzle flow was studied at three distinctive back pressures. The obtained numerical results for injection characteristics show good agreement with the experimental ones. The results of 3D simulations indicate that differences in fuel properties influence internal fuel flow and cavitation inception. The location of cavitation formation is the same for both fuels. The cavitation formation is triggered regardless of fuel properties. The size of the cavitation area is influenced by fuel properties and also from in-cylinder back pressure. Higher values of back pressure induce smaller areas of cavitation and vice versa. Comparing the conditions at injection hole exit, diesel fuel proved slightly higher average mass flow rate and velocities, which can be attributed to differences in fluid densities and viscosities. Overall, the obtained results indicate that when considering the injection process and internal nozzle flow, GTL fuel can be used in common-rail injection systems with solenoid injectors.
Plastic is one of the most widely used materials worldwide. The problem with plastic arises when it becomes waste, which needs to be treated. One option is to transform plastic waste into synthetic fuels, which can be used as replacements or additives for conventional fossil fuels and can contribute to more sustainable plastic waste treatment compared with landfilling and other traditional waste management processes. Thermal and catalytic pyrolysis are common processes in which synthetic fuels can be produced from plastic waste. The properties of pyrolytic oil are similar to those of fossil fuels, but different additives and plastic stabilizers can affect the quality of these synthetic fuels. The quality of fuels and the permissible particle sizes and number density are regulated by fuel standards. Particle size in fuels is also regulated by fuel filters in vehicles, which are usually designed to capture particles larger than 4 μm. Problems can arise with the number density (quantity) of particles in synthetic fuels compared to that in fossil fuels. The present work is a numerical study of how particle size and number density (quantity) influence cavitation phenomena and cavitation erosion (abrasion) in common-rail diesel injectors. The results provide more information on whether pyrolysis oil (synthetic fuel) from plastic waste can be used as a substitute for fossil fuels and whether their use can contribute to more sustainable plastic waste treatments. The results indicate that the particle size and number density slightly influence cavitation phenomena in diesel injectors and significantly influence abrasion.