In the present study, we adopt an easy and cost-effective route for preparing Cu₂ZnSnS₄ (CZTS)-absorber nanoparticles by a mechanochemical method using non-toxic and environmentally benign solvents (butanol, methyl ethyl ketone, and ethanol). The gram-scale synthesis of absorber nanoparticles was achieved in a non-hazardous, zero-waste process without using high-vacuum equipment. The effects of annealing and Na incorporation on the properties of spin-coated CZTS thin films were scrutinized. The deposited samples showed kesterite crystal structure and single phase. The morphological results revealed an improvement in the surface morphology after annealing. The optical bandgaps of the thin films lied in the range of 1.50–1.57 eV with p-type nature. Finally, photovoltaic devices were fabricated, and their cell performance parameters were studied. An efficiency of 0.16% was observed. The present study provides a potential route for the cost-effective fabrication of CZTS-based photovoltaic devices.

A graphene–cadmium sulfide (Gr–CdS) nanocomposite was prepared by a chemical solution method, and its material properties were characterized by several analysis techniques. The synthesized pure CdS nanoparticles (NPs) and Gr–CdS nanocomposites were confirmed to have a stoichiometric atomic ratio (Cd/S = 1:1). The Cd 3d and S 2p peaks of the Gr–CdS nanocomposite appeared at lower binding energies compared to those of the pure CdS NPs according to X-ray photoelectron spectroscopy analyses. The formation of the Gr–CdS nanocomposite was also evidenced by the structural analysis using Raman spectroscopy and X-ray diffraction. Transmission electron microscopy confirmed that CdS NPs were uniformly distributed on the graphene sheets. The absorption spectra of both the Gr–CdS nanocomposite and pure CdS NPs thin films showed an absorption edge at 550 nm related to the energy band gap of CdS (~2.42 eV). The Cu(In,Ga)Se₂ thin film photovoltaic device with Gr–CdS nanocomposite buffer layer showed a higher electrical conversion efficiency than that with pure CdS NPs thin film buffer layer. In addition, the water splitting efficiency of the Gr–CdS nanocomposite was almost three times higher than that of pure CdS NPs.

Transition metal oxide aerogels are a fascinating class of compounds that have received considerable attention in the last decade owing to their unique and exceptional properties, including high porosity, large surface area, and ultralow density. In this study, α-Ni(OH)₂ aerogels and annealed NiO/Ni aerogels were used to design and fabricate a two-electrode supercapacitor device. The physicochemical properties of the as-synthesized aerogels were characterized through X-ray diffraction, scanning electron microscopy, transmission electron microscopy, the Brunauer–Emmett–Teller theory, and X-ray photoelectron spectroscopy studies. The annealed NiO/Ni aerogels showed a (specific capacitance of 1060 F/g) specific capacity of 422 C/g at 1 A/g current density and with good cycling stability (up to 10,000 cycles). The supercapacitor also demonstrated an energy density of 32.4 Wh/kg and power density of 1800 W/kg at a current density of 2 A/g. The specific capacitance of NiO/Ni aerogels was more than twice that of the α-Ni(OH)₂ aerogels. The practical applications of the aerogel were demonstrated by fabricating a two-electrode device.