A graphene–cadmium sulfide (Gr–CdS) nanocomposite was prepared by a chemical solution method, and its material properties were characterized by several analysis techniques. The synthesized pure CdS nanoparticles (NPs) and Gr–CdS nanocomposites were confirmed to have a stoichiometric atomic ratio (Cd/S = 1:1). The Cd 3d and S 2p peaks of the Gr–CdS nanocomposite appeared at lower binding energies compared to those of the pure CdS NPs according to X-ray photoelectron spectroscopy analyses. The formation of the Gr–CdS nanocomposite was also evidenced by the structural analysis using Raman spectroscopy and X-ray diffraction. Transmission electron microscopy confirmed that CdS NPs were uniformly distributed on the graphene sheets. The absorption spectra of both the Gr–CdS nanocomposite and pure CdS NPs thin films showed an absorption edge at 550 nm related to the energy band gap of CdS (~2.42 eV). The Cu(In,Ga)Se₂ thin film photovoltaic device with Gr–CdS nanocomposite buffer layer showed a higher electrical conversion efficiency than that with pure CdS NPs thin film buffer layer. In addition, the water splitting efficiency of the Gr–CdS nanocomposite was almost three times higher than that of pure CdS NPs.

The feasibility of achieving in situ sulfur (S) and nitrogen (N) co-doped carbon nano-onions (CNOs and SN–CNOs) via a simple flame-pyrolysis technique without using sophisticated high-vacuum annealing or expensive nanodiamond-based complex processes is demonstrated for the first time. The characteristic onion-like feature of 0.34 nm remained intact with a high degree of ordering and graphitization, even though the S and N heteroatoms were co-doped simultaneously. The in situ co-doped SN–CNO demonstrated high supercapacitor device performance with a high energy density of 25 Wh kg⁻¹ at a maximum power density of 18 kW kg⁻¹, maintaining 98% specific capacitance over 10,000 cycles at 10 A g⁻¹. These are the highest achieved device performance values of a fullerene family electrode material to date.

D-penicillamine (PA) is a sulfur group-containing drug prescribed for various health issues, but overdoses have adverse effects. Therefore, regular, selective, and sensitive sensing is essential to reduce the need for further treatment. In this study, diphenylamine (DPA) was electropolymerized in an aqueous acidic medium. The PA detection sensitivity, selectivity, and limit of detection were enhanced by electropolymerizing DPA on an electrochemically reduced graphene oxide (ERGO)/glassy carbon (GC) surface. The formation of p-DPA and ERGO was investigated using various techniques. The as-prepared p-DPA@ERGO/GC revealed the excellent redox-active (N–C to N=C) sites of p-DPA. The p-DPA@ERGO/GC electrode exhibited excellent electrochemical sensing ability towards PA determination because of the presence of the –NH–functional moiety and effective interactions with the –SH group of PA. The p-DPA@ERGO/GC exhibited a high surface coverage of 9.23 × 10⁻¹² mol cm⁻². The polymer-modified p-DPA@ERGO/GC electrode revealed the amperometric determination of PA concentration from the 1.4 to 541 μM wide range and the detection limit of 0.10 μM. The real-time feasibility of the developed p-DPA@ERGO/GC electrode was tested with a realistic PA finding in human blood serum samples and yielded a good recovery of 97.5–101.0%, confirming the potential suitability in bio-clinical applications.