The aim of this paper is to analyse changes in the physicochemical elements in groundwater in the vicinity of a small municipal solid waste landfill site located within the territory of the European Union on the basis of 7-year hydrochemical research. Samples of groundwater and leachate near the examined landfill were collected four times a year during two periods, between 2008 and 2012 during the use of the landfill and between 2013 and 2014 at the stage of its closure. The research results were analysed on the basis of general physicochemical properties: pH; total organic carbon (TOC); electrical conductivity (EC); inorganic elements: Cr, Zn, Cd, Cu, Pb, Hg; and one organic element—polycyclic aromatic hydrocarbon (PAH). The analysis was carried out in accordance with the EU and national legislation requirements regarding landfill monitoring. The assessment of the groundwater and analysis indicators of the leachate pollution allowed interpretation of the impact of the municipal solid waste landfill on the state of the water environment in the immediate vicinity. The results show that the increased values of Cd, EC, and TOC turned out to be the determinants of the negative impact of leachate on the groundwater quality below the landfill. The integrated water threat model determined the potential negative impact of a landfill site. The extent depended on local environmental conditions and the self-cleaning process. Deterioration of the chemical status in the quality of the groundwater within the landfill area was a consequence of the lack of efficiency of the existing drainage system, which may result from the 19-year period of its use. The applied correlation relationship between physicochemical elements between leachate and groundwater with a time shift due to the extended time of migration of contaminants or mass transfer in waterlogged ground can be an important tool to identify the threat of groundwater pollution in the area of landfill sites.

This research identifies the productivity of landfill gas actively captured at a municipal waste landfill site with a waste mass exceeding 1 million Mg from sectors in the operational and non-operational phases, considering meteorological conditions. Based on the analysis of landfill gas, including emissions and composition (CH₄, CO₂, O₂, and other gases), the processes occurring demonstrate the impact of the decomposition of deposited waste on the activity of the deposit. With average monthly gas emissions exceeding 960,000 m³, the average content of CH₄ (30–63%) and CO₂ (18–42%) and the varied content of O₂ (0.3–9.8%) in individual sectors of the landfill site were significant. The statistically significant relationship between CH₄, CO₂, and landfill gas emissions exhibited a noticeable decrease in methane content. Despite the abandonment of waste storage, a high correlation is present between the emission level and methane content (0.59) and carbon dioxide (0.50). In the operational part of the landfill, this relationship is also statistically significant but to a lesser extent; Spearman’s R-value was 0.42 for methane and 0.36 for carbon dioxide. The operational and post-operational phases of the municipal waste landfill demonstrated a noticeable impact from the amount of precipitation, relative humidity, and air temperature, on landfill gas productivity. The generally progressive decline in the activity of the waste deposit, which reflects a decreasing trend in the methane content of approximately 2% annually in the total composition of landfill gas, as well as the share below 50%, indicates the need only to utilise landfill without producing energy.

This paper presents the changes in concentration of seven biogenic indices in the Wisłok River water and determines the water treatment processes required in order to obtain water fit for consumption. The investigations were conducted during 2004–2013, and water samples were collected at a measuring-control point was situated at 67.9 km on the river at the surface water intake for the water supply to the Rzeszów city dwellers. Analysis of the research results allows for the forecasting of technological and organizational changes in the treatment processes of the abstracted water. It was found that only the mean concentration of Kjeldahl nitrogen exceeded the value admissible for class I, which allowed the Wisłok River water to be classified as class II with good potential and determined the water quality category as A2, which indicates the necessity for typical performance physical and chemical treatment. Downward trends in the contents of the tested nutrients occurred during the period of investigation, except for nitrite nitrogen. Statistically significant downward trends were registered for ammonium nitrogen, Kjeldahl nitrogen, total nitrogen and phosphates. The decline in nutrient concentrations in the water of Wisłok is a tangible result of the introduction of new standards of water resource management in the catchment, compliant with the European Union legislation.

Seasonal and monthly changes of biogenic and oxygen indices in the water of two streams in 2007-10 are discussed in this paper. The streams have similar catchment areas that area managed and used in different ways. The Krzyworzeka stream catchment is covered by rural areas, whereas the Serafa stream flows through built-up and urbanized areas. Statistical testing using U Mann-Whitney’s nonparametric test was conducted to determine the differences of oxygen and biogenic water quality index values between the growing season and outside the growing season. Statistically significant decreases in ammonium, nitrate, and total nitrogen concentrations, as well as oxygen dissolved in Krzyworzeka Stream, were registered during the growing season. In the Serafa water only the concentrations of dissolved oxygen and biological oxygen demand decreased significantly. On this basis it was established that in clean waters vegetation development considerably influences the content of biogenic compounds. Serious pollution of stream water causes vegetation and the intensity of biochemical processes in water to not cause any clear reduction in biogenic compound concentrations.