Alkaline rocks are worldwide observed as hosts for rare metal (Zr-REE-Nb) minerals. The classification of the ore bearing rock type is challenging due to the fact that textures and mineral assemblage are obscured by post-magmatic alteration. In addition, the alteration causes fine and intricate intergrowth of the ore minerals with associated gangue. Hence, intensive comminution is necessary to liberate the ore minerals, which is one parameter hampering the economical use of this deposit type. This study provides a quantitative mineralogical investigation of the ore bearing rock suite at Khalzan Buregtei as an example of rare metal deposits. R1-R2 multication parameters are shown to be highly appropriate as quantitative mineralogical indicators based on readily available major element datasets to visualize and quantify alteration types of the ore bearing rock suite. The ore minerals were found to be associated with a cluster-forming assemblage of post-magmatic phases. Automated mineralogy was applied to quantify the textural properties of the ore mineral clusters. This finding permits efficient pre-concentration of rare metal ore at coarser particle size fraction, requiring less energy consuming comminution.

The Barberton region of South Africa is characterized by a broad variety of granite types that range in age from ca. 3.5 Ga to 2.7 Ga and reflect the processes involved in the formation of Archaean continental crust on the Kaapvaal Craton. These granites are subdivided into three groups, as follows: A tonalite-trondhjemite-granodiorite (TTG) suite diapirically emplaced at 3 450 Ma and 3 250 Ma into pre-existing metamorphosed greenstone belt material. TTG melts were derived from melting amphibolite in the lower crust, with individual plutons being emplaced at various crustal levels. The dome-and-keel geometry that characterizes the TTG-greenstone dominated crust at this time is inconsistent with a plate tectonic domain and reworking was likely controlled by gravity inversion or ‘sagduction’; Regionally extensive potassic batholiths (the GMS suite) were emplaced at 3 110 Ma during a period of crustal thickening and melting of a TTG-dominated lower crust. Subsequent to emplacement of the voluminous GMS granites, the thickened continental crust had stabilized sufficiently for large sedimentary basins to form; Late granite plutons were emplaced along two distinct linear and sub-parallel arrays close to what might have been the edge of a Kaapvaal continent at 2 800 to 2 700 Ma. They are subdivided into high-Ca and low-Ca granites that resemble the I- and S-type granites of younger orogenic episodes. The high-Ca granites are consistent with derivation from older granitoids in the lower crust, whereas the low-Ca granites may have been derived by melting metasedimentary precursors in the lower-mid crust. Granites with similar characteristics are associated with a subduction zone in younger terranes, although the recognition of such a feature at Barberton remains unclear. The petrogenesis of granites in the Barberton region between 3.5 Ga and 2.7 Ga provides a record of the processes of Archaean crustal evolution and contributes to discussions related to the onset of plate tectonics.

This review compares genetic parameters of 12 orogenic gold deposits. The set of examples is considered to represent largely the variability of orogenic gold deposit (OGD) characteristics. The data are presented in tables and include following definitive parameters: regional geologic settings, nature of hosts rocks and mineralization, ore controlling structures, ages of host rocks and mineralization and timing of mineralization relative to metamorphism, hydrothermal alteration mineralogy and ore mineral assemblages, isotopic signatures, physical conditions of ore formation and proposed origin of ore fluids aa well as gold reserves, production, and grades. This allows comparison of deposits from different geologic terrains having different ages and formed under different P-T conditions. The data are further discussed before the background of the orogenic gold system and the crustal metamorphic models that provide different scenarios to explain the source of ore fluids. The orogenic gold system model advocates a metal and fluid source external to the terrain in which mineralization occurred, but the model applies only for 3 of the 12 deposits studied. All other deposits formed most likely from a crustal source, which would favor the crustal metamorphic model. However, the formation of hypozonal OGDs cannot be accounted for by the crustal metamorphic model or by the metamorphic devolatilization model. The data identify a set of coherent signatures in OGDs, but there seem to be no unified model for all possible environmental conditions and facets of ore formation and fluid sources, tectonic and lithologic setting, and scale of gold endowment.

The 3.33 to 3.26 Ga Mendon Formation in the Palaeoarchaean Barberton greenstone belt, South Africa, forms the uppermost unit of the Onverwacht Group. It is dominated by ultramafic volcanic rocks interbedded with thin layers of cherty sediments that show pervasive alteration, including widespread serpentinisation, silicification and chert and quartz veining. The BARB4 drill core of the ICDP Barberton drilling project exposes a unique section through the Mendon Formation in the Manzimnyama Syncline. The komatiites are pervasively altered to an assemblage comprising quartz, chlorite, carbonate, talc, biotite, and, locally, plagioclase, K-feldspar, muscovite, amphibole, stilpnomelane and ankerite. The overlying sediments are made up of banded iron formations and rare beds of siliciclastic rocks. Though the altered komatiites are pervasively silicified, SiO₂ contents do not exceed 58 wt.%, and their major and trace element geochemistry is similar to other komatiitic rocks of the Mendon Formation, particularly those of the M2v-member. Quartz veins and, less commonly, quartz-carbonate and quartz-carbonate-plagioclase veins are found throughout the core. Overall, composition and texture of the veins differ from primary and early diagenetic veins found in silicified komatiites elsewhere in the Barberton greenstone belt. In the BARB4 drill core, the veins are generally coarse-grained, and the immediate wall rocks are locally foliated along the vein margins. In addition, the δ¹⁸O values of vein quartz range from 14.1 to 15.3‰, significantly lower than the values typically found in veins on the modern seafloor that formed during low temperature hydrothermal seafloor alteration (~22 to 32‰). Fluid inclusions in vein quartz are homogeneous two-phase (L+V) aqueous inclusions that occur in trans- and intragranular trails and clusters. Intragranular and isolated fluid inclusions have a similar homogenisation temperature (T_h) of 130 to 200°C, with most data ranging between 145 and 175°C. Salinities cluster in three different groups of high (20 to 27wt.% NaCl equiv.), medium (10 to 15wt.% NaCl equiv.) and low salinity (0.3 to 1.5wt.% NaCl equiv.). The composition and microthermometric characteristics of the fluid inclusions analysed within the drill core show similarities to those found in quartz veins in silicified komatiites of the Mendon Formation, which are interpreted to have been entrapped during metamorphism. P-T calculations based on fluid inclusion microthermometry reveal conditions of 230 to 400 MPa and 250 to 400°C. Similar conditions of 240 to 270°C have been obtained using oxygen isotope thermometry, assuming a metamorphic fluid with a δ¹⁸O value of 6‰. Collectively, the δ¹⁸O values, together with the texture and composition of the veins, are interpreted to indicate a metamorphic origin of the veins. The presence of high salinity inclusions indicates the occurrence of a highly saline fluid that locally mixed with the dominant lower salinity fluids. The high salinity might have been derived from fluid circulation through evaporites.