Alkaline rocks are worldwide observed as hosts for rare metal (Zr-REE-Nb) minerals. The classification of the ore bearing rock type is challenging due to the fact that textures and mineral assemblage are obscured by post-magmatic alteration. In addition, the alteration causes fine and intricate intergrowth of the ore minerals with associated gangue. Hence, intensive comminution is necessary to liberate the ore minerals, which is one parameter hampering the economical use of this deposit type. This study provides a quantitative mineralogical investigation of the ore bearing rock suite at Khalzan Buregtei as an example of rare metal deposits. R1-R2 multication parameters are shown to be highly appropriate as quantitative mineralogical indicators based on readily available major element datasets to visualize and quantify alteration types of the ore bearing rock suite. The ore minerals were found to be associated with a cluster-forming assemblage of post-magmatic phases. Automated mineralogy was applied to quantify the textural properties of the ore mineral clusters. This finding permits efficient pre-concentration of rare metal ore at coarser particle size fraction, requiring less energy consuming comminution.
Very often, the production of silver causes devastating environmental issues, because of the use of toxic reagents like cyanide and mercury. Due to severe environmental damage caused by humans in the last decades, the social awareness regarding the sustainable production processes is on the rise. Terms like “sustainable” and “green” in product descriptions are becoming more and more popular and producers are forced to satisfy the rising environmental awareness of their customers. Within this work, an alternative environmental sound silver recovery process was developed for a vein type silver ore from Mina Porka, Bolivia. A foregoing characterization of the input material reveals its mineral composition. In the following mineral processing, around 92.9% silver was concentrated by separating 59.5 wt. % of non-silver minerals. Nitric acid leaching of the generated concentrate enabled a silver recovery of up to 98%. The dissolved silver was then separated via copper cementation to generate a metallic silver product of >99% purity. Summarizing all process steps, a silver yield of 87% was achieved in lab scale. A final upscaling trial was conducted to prove the process’ robustness. Within this trial, almost 4 kg of metallic silver with a purity of higher than 99.5 wt. % was produced.