In this work, polyaniline (PANI) is synthesized via oxidative polymerization of aniline and purified using organic solvents where the emeraldine phase is isolated by employing a phase separation system. The above contributes to the increase in the percentage yield compared to previous works and the possibility of being used as a single phase. In addition, the PANI/AgNPs composite is prepared in situ at the polymerization of aniline, adding silver nitrate and glycine to create the AgNPs inside the PANI matrix by controlling the pH, temperature, time of reaction and incorporating a new purification technique.

The reaction of cyclic carbonates with amines is the most attractive among the synthesis methods for isocyanate-free polyurethane. Non-isocyanate polyurethane films with SiO₂ NPs fabricated by a sol-gel process are reported, where cyclic carbonates (CC) were produced under mild conditions by CO₂ insertion in an epoxide complex in the presence of LiCl. A reaction of CC and polyamines was carried out in a low concentration polymer matrix of PVA. The materials were characterized by ¹H-NMR, FTIR, UV-Vis, SEM, TGA, DTG, and a KD₂ pro technique. polymer FTIR results are consistent with the literature, even with the use of a non-conventional methodology, where the found chemical interactions values were 3330, 2930 and 1637 cm⁻¹. There are differences in the polymers’ morphologies due to the presence and absence of SiO₂ NPs according to SEM, where the spherical morphology and homogenous particle size distribution of NPs around 100 nm. According to TGA results, all polymers showed their last stage decomposition after 300 °C and polymers with higher concentration of NPs showed even better stability. Due to the obtained results, the polymers have the potential to be used for thermal insulation without negative effect on the environment.