In this study, the durability of phosphogypsum (PG)-based cemented backfill was investigated by drying-wetting cycles to explore deterioration of its strength and the release of impurities. The leachates in this test were composed of deionized water, 5% Na₂SO₄ solution, 5% NaCl solution, and a range of sulfuric acid solutions with pH values of 1.5, 3, and 5. After drying-wetting cycles, unconfined compressive strength (UCS), visual deterioration, porosity, microstructure and concentrations of phosphate and fluoride in the leachates were measured. The results showed that both saline and acidic solutions could lead to strength reduction of PG-based cemented backfill under different deterioration mechanisms. The mechanical damage of salinity was caused by micro-cracking and degradation of C–S–H. However, the H⁺ broke the backfill by dissolving hydration products, leaving the conjunctures between PG particles weakened. Furthermore, the environmental impact was investigated by measuring the concentration of phosphate and fluoride in the leachates. In acidic solutions, the release of phosphate and fluoride was greatly enhanced by H⁺. Compared to the great strength deterioration in saline leachates, the concentration of phosphate and fluoride were similar to that of deionized water, indicating that saline solutions had little impact on the release of hazardous impurities.

The cemented phosphogypsum (PG) backfill technique provides a new method for massive consumption of PG, and therefore alleviating the environmental pollution of PG. This study considered the effects of slurry preparation on the performance of cemented PG backfill. A L₁₆(4⁴) orthogonal experiment was designed to analyze four factors, namely the solid content, phosphogypsum-to-binder ratio (PG/B ratio), stirring time and stirring speed, with each factor having four levels. According to the range analysis, the solid content played the dominant role in controlling the bleeding rate, while the setting times strongly depended on the PG/B ratio. In terms of strength development of the backfill, the PG/B ratio was shown to be the most significant factor determining the unconfined compressive strength (UCS), followed by the solid content, stirring time and stirring speed. Furthermore, the results showed that the slurry preparation affected the environmental behavior of impurities that originated in PG. By analyzing the concentrations of impurities in the bleeding water of the slurry as well as the leachates of the tank leaching test, the results showed that the release of F⁻ and SO₄²⁻ was aggravated clearly with the increase in the PG/B ratio, while the release of PO₄³⁻ always remained at relatively low levels.

Tailings storage facilities (TSFs) are known as a time-bomb. The numerous failures of TSFs and the heavy catastrophic consequences associated with each failure of TSFs indicate that preventing measures are necessary for existing TSFs. One of the preventing measures is to construct catch dams along the downstream near TSFs. The design of catch dams requires a good understanding of the dynamic interaction between the tailings slurry flow and the catch dams. There are, however, very few studies on this aspect. In this study, a numerical code, named LS-DYNA, that is based on a combination of smoothed particle hydrodynamics and a finite element method, was used. The numerical modeling shows that the tailings slurry flow can generally be divided into four stages. In terms of stability analysis, a catch dam should be built either very close to or very far from the TSF. When the catch dam with an upstream slope of a very small inclination angle is too close to the tailings pond, it can be necessary to build a very high catch dam or a secondary catch dam. As the impacting force can increase and decrease with the fluctuations back-and-forth of the tailings slurry flow, the ideal inclination angle of the upstream slope of the catch dam is between 30° and 37.5°, while the construction of a catch dam with a vertical upstream slope should be avoided. However, a catch dam with steeper upstream slopes seems to be more efficient in intercepting tailings flow and allowing the people downstream to have more time for evacuation. All these aspects need to be considered to optimize the design of catch dams.

Filling mining offers significant technical advantages in controlling rock mass movement and preventing disasters. Investigating the correlation between the macro- and micro-scale characteristics of filling materials will help optimize this process. The paper analyzes the variation patterns and mechanisms of the pore structure and mechanical strength characteristics of the filling body based on low-field nuclear magnetic resonance (NMR) technology and fractal theory, exploring the relationship between microstructure and macroscopic features. Results indicate that as the cement-to-sand ratio or mass concentration decreases, the total pore structure count in the filling material increases, predominantly consisting of micropores that account for over 76%. The complexity of total pores, micropores, mesopores, and macropores progressively decreases. Mechanical strength exhibits a positive correlation with both the cement-to-sand ratio and mass concentration. A reduced cement-to-sand ratio diminishes hydration products, lowering the cohesive strength of tailings particles. As mass concentration increases, the internal structure of the filling body becomes denser, enhancing its mechanical properties. An increase in pore number progressively improves pore connectivity, reducing fluid flow resistance. The porosity of the pore structure exhibits a strong correlation with fractal dimension, mechanical strength, and permeability coefficient, with a coefficient of determination ranging from 0.631 to 0.996. The strength prediction model constructed using mesopore porosity and material intrinsic characteristics also demonstrated excellent accuracy.