In this study, the durability of phosphogypsum (PG)-based cemented backfill was investigated by drying-wetting cycles to explore deterioration of its strength and the release of impurities. The leachates in this test were composed of deionized water, 5% Na₂SO₄ solution, 5% NaCl solution, and a range of sulfuric acid solutions with pH values of 1.5, 3, and 5. After drying-wetting cycles, unconfined compressive strength (UCS), visual deterioration, porosity, microstructure and concentrations of phosphate and fluoride in the leachates were measured. The results showed that both saline and acidic solutions could lead to strength reduction of PG-based cemented backfill under different deterioration mechanisms. The mechanical damage of salinity was caused by micro-cracking and degradation of C–S–H. However, the H⁺ broke the backfill by dissolving hydration products, leaving the conjunctures between PG particles weakened. Furthermore, the environmental impact was investigated by measuring the concentration of phosphate and fluoride in the leachates. In acidic solutions, the release of phosphate and fluoride was greatly enhanced by H⁺. Compared to the great strength deterioration in saline leachates, the concentration of phosphate and fluoride were similar to that of deionized water, indicating that saline solutions had little impact on the release of hazardous impurities.

The cemented phosphogypsum (PG) backfill technique provides a new method for massive consumption of PG, and therefore alleviating the environmental pollution of PG. This study considered the effects of slurry preparation on the performance of cemented PG backfill. A L₁₆(4⁴) orthogonal experiment was designed to analyze four factors, namely the solid content, phosphogypsum-to-binder ratio (PG/B ratio), stirring time and stirring speed, with each factor having four levels. According to the range analysis, the solid content played the dominant role in controlling the bleeding rate, while the setting times strongly depended on the PG/B ratio. In terms of strength development of the backfill, the PG/B ratio was shown to be the most significant factor determining the unconfined compressive strength (UCS), followed by the solid content, stirring time and stirring speed. Furthermore, the results showed that the slurry preparation affected the environmental behavior of impurities that originated in PG. By analyzing the concentrations of impurities in the bleeding water of the slurry as well as the leachates of the tank leaching test, the results showed that the release of F⁻ and SO₄²⁻ was aggravated clearly with the increase in the PG/B ratio, while the release of PO₄³⁻ always remained at relatively low levels.

Using phosphogypsum (PG) as the aggregate of cemented backfill is an economical and effective method of PG utilization. However, the stability and performance of cemented backfill are challenged by the rich fluoride content in PG. In this study, the effects of citric acid pretreatment on PG defluorination, backfill performance and environmental behavior were investigated by washing PG with different concentrations of citric acid and washing times. The results showed that the citric acid pretreatment could significantly reduce the fluoride content in PG and promote the hydration reaction with the binder, thus greatly reducing the usage and cost of the binder in actual production. Considering the efficiency of defluorination, the optimal citric acid concentration and washing times were determined to be 4% and 7–8 times, respectively. In addition, after citric acid pretreatment, the viscosity and setting time of the backfill slurry and the porosity of the backfill reduced, and the strength of the backfill improved, which was conducive to slurry pipeline transportation and underground mine stability. Finally, a further analysis of environmental behavior was conducted and it was found that the citric acid washing greatly reduced the content of fluoride in the bleeding water of slurry and the backfill leachate, which met the integrated wastewater discharge standard in China. The results of this study can provide important guidance for the large-scale recycling and environmental management of PG.

The present study investigated the effects of protocols for slurry preparation on the release of pollutants into bleeding water from cemented phosphogypsum (PG) backfill. Backfill slurry was prepared using four different protocols in which different parameters varied, including binder/PG ratio, solid concentration, binder type and mixing procedure. The concentrations of phosphate, fluoride and sulfate and the pH values of the obtained bleeding water were measured. The results demonstrated that the slurry preparation protocols affected the quantities of pollutants through the concentrations of pollutants in bleeding water and the bleeding rate. On the one hand, the binder/PG ratio was the key factor influencing the concentrations of all pollutants in bleeding water. Comparatively speaking, the binder type and mixing procedure had an obvious influence on the fluoride concentration but had little influence on the phosphate and sulfate concentrations in the bleeding water. On the other hand, the protocols for slurry preparation affected the bleeding rate by determining the water retention and water content of the backfill slurry. The most effective protocol for slurry preparation for cemented PG backfill could reduce the bleeding rate and enhance the immobilization of pollutants, minimizing the phosphate concentration in bleeding water to below 0.2 mg/L. However, it appeared that the fluoride concentration was still tens of milligrams per liter (over the limit of 10 ten milligrams per liter), to which attention should be paid.

Compared with the post-treatment of pollutants, such as the removal of phosphate from wastewater, it is more important to develop effective emission control strategies to reduce phosphate pollution. Phosphogypsum (PG) is a typical solid waste byproduct of phosphate production and contains high amounts of residual phosphate. In order to control the phosphate emissions during the recycling of PG aggregates for cemented backfill, another solid waste product—iron tailings (ITs)—was added during the preparation of backfill slurry. The results showed that the ITs effectively accelerated the phosphate removal in cemented PG backfill, enabling the quick reduction in the phosphate concentration to the discharge standard (<0.5 mg/L) within 15 min. This means that the emissions of phosphate to bleeding water were effectively controlled. The adsorption experiment showed that phosphate was adsorbed by the ITs, and the adsorption data fitted well with the Langmuir adsorption model (R² = 0.98) and pseudo-second-order kinetic model (R² = 0.99), indicating that the phosphate adsorption of ITs was a monolayer chemical adsorption. Furthermore, an unconfined compressive strength (UCS) test was performed on the backfill with the addition of ITs. Compared to the control group (without ITs), the UCS of backfill with 20% ITs increased from 1.08 MPa to 1.33 MPa, indicating that the addition of solid waste could be beneficial to the strength development of the backfill by mitigating the interference of phosphate with the hydration process. The backfill cured for 28 d was selected for the toxic leaching test, and the phosphate concentration in the leachates was always below 0.02 mg/L, indicating that ITs can effectively immobilize phosphate in backfill for a long time.