Green synthesis processes are regarded as safer alternative to usual physical, chemical and microbial methods due to their cost effectiveness, environmental friendly nature and easy handling. In the present study, an eco-friendly and facile method for biogenic synthesis of silver nanoparticles (AgNPs) has been developed using fruit extract of Gmelina arborea, an abundantly available medicinal plant in North Eastern region of India. The prepared AgNPs were characterized by UV–Vis spectroscopy, transmission electron microscopy (TEM), selected area electron diffraction pattern and energy dispersive X-ray spectrum. TEM studies showed the as-synthesized AgNPs were stable, almost spherical and crystalline with the particles size varying from 8 to 32 nm. The average diameter of the particles was 17.0 ± 1.6 nm. The catalytic effectiveness of the prepared green catalyst, AgNP, was also investigated in catalytic degradation of Methylene Blue (MB) dye. The catalytic degradation reaction was completed within 10 min, signifying excellent catalytic properties of silver nanoparticles in reduction of MB

Consumers increasingly prefer healthy and nutritious diet worldwide, and demands for fresh fruits and vegetables are rapidly growing. Fresh produce are perishable commodities, and physical damage, moisture loss, biochemical changes, and postharvest microbial decay are primary causes of quality loss and reduced shelf-life. Packaging, including plastic films and coatings is an effective strategy to improve postharvest-life of whole and cut fruits and vegetables. However, plastic packaging is a significant environmental concern globally. Biopolymer based films and/or coatings are environment-friendly alternative packaging for food. But, these biopolymers, derived from plant, animal and microbial sources, lack some of the primary physico-chemical and mechanical properties compared to conventional plastic packaging. Reinforcement of biopolymer with nanomaterials addresses these shortcomings, and adds functional properties such as antimicrobial and/or antioxidant activities to the nanocomposites. Organic (e.g. nanocellulose fibrils), and inorganic (e.g. montmorillonite, zinc oxide, silver) nanomaterials are effective in achieving these improvements in biopolymer based nanocomposite. Plant-extracts and compounds derived from plant (e.g. essential oil) are also effective in imparting antimicrobial and antioxidant properties to biopolymer based nanocomposites. This is an extensive review of research works on effectiveness of biopolymer based nanocomposite films and coatings used for packaging of whole and cut fruits and vegetables to extend their shelf-life. Numerous reports have demonstrated effectiveness of biopolymer based nanocomposites in improvement in shelf-life of packaged and/or coated whole and cut fruits and vegetables by at least 4–5 days to as much as a few months.

Zinc oxide nanoparticles (ZnONPs) were synthesized by green protocol using Mimusops elengi fruit extract as a novel natural resource. The synthesized particles were polyhedral (mostly hexagonal) in shape between 14 - 48 nm with an average size of 24.75 ± 0.78 nm. Nano zinc oxide (ZnO) at concentrations of 2% (w/w) and 4% (w/w), were incorporated into agar matrix. Solution casting method was used to fabricate the bionanocomposite films with ZnONPs in agar. Surface morphology, particle size, crystallinity, thermal stability and functional groups were determined using SEM, TEM, XRD, TGA and FTIR, respectively. Loading of ZnONPs in composite films improved thermal stability, elongation and film thickness, whereas tensile strength and transparency decreased. The films were used for packaging of green grapes, and appearance of the fruit was observed during ambient storage. Grapes packaged in composite films showed fresh appearance up to 14 and 21 days in ambient conditions for 2% (w/w) and 4% (w/w) ZnONPs in films, respectively. The results showed the potential of the fabricated agar-ZnO nanocomposite film as a promising packaging material to enhance postharvest shelf-life of fresh fruits like green grapes.