Molybdenum disulfide nanosheets (MoS2 NSs) were prepared using a solvothermal synthesis approach. The synthesized MoS2 nanosheets were used to modify a screen-printed electrode (MoS2 NSs / SPE), which was then utilized as the working electrode for the voltammetric analysis of carmoisine. The MoS2 NSs / SPE demonstrated enhanced electrocatalytic activity towards the oxidation of carmoisine. The oxidation peak currents of carmoisine were found to be linearly proportional to its concentration over a range of 0.1 to 400.0 μM, with a detection limit as low as 0.03 μM under optimized conditions. The MoS2 NSs / SPE also demonstrated effective performance in detecting carmoisine even when tartrazine was present, indicating its potential for simultaneous determination of both compounds. The oxidation peak potentials of the two azo dyes were sufficiently separated by 200 mV, making the MoS2 NSs / SPE suitable for the simultaneous detection of carmoisine and tartrazine using differential pulse voltammetry.
28 December 2023 in Journal of Advanced Research in Fluid Mechanics and Thermal Sciences
Polymers can be utilized for a wide variety of applications since they are lightweight and inexpensive, and their mechanical qualities are usually more than enough. Polymers often undergo a petrochemical production process and have a relatively lengthy elimination time. Green chemistry and green production are crucial in today's technology, which relies increasingly on non-toxic polymers made from natural ingredients. Biopolymers are a type of organic polymer that can break down naturally and pose no threat to human health or the environment. Here, we will take a quick look at the polymer structures that go into making eco-friendly composites in the future. Important polymer types and engineering studies for material manufacturing have been uncovered as a means of avoiding green production's negative effects on the environment. Possible future use of biopolymers as binders in composite materials and their effects on the environment.
23 February 2025 in Journal of Electrochemical Science and Engineering
In this paper, we describe the use of a screen-printed graphite electrode modified with a two-dimensional leaf-like zeolitic imidazolate framework-L (Zn), ZIF-L (Zn) for the deter¬mination of sulphite. We started by using linear sweep voltammetry to investigate the redox properties of the modified electrode at different scan rates (10 to 400 mV s-1). Next, we evaluated sulphite oxidation in the modified electrode. Using differential pulse voltammetry (DPV), the linear dynamic range of 0.04-900.0 µM and the limit of detection (3s/m) of 0.01 μM were obtained. DPV was also used to quantify sulphite in various real samples using the standard addition method.
This work aimed to produce silver nanoparticles (AgNPs) by efficient green synthesis techniques, namely rapid green synthesis and modified microwave-assisted green synthesis methods. The study used fish scale collagen (FsCol) as a stabilizer to assess its impact on the dimensions and configurations of AgNPs. Four samples were prepared with varying concentrations of FsCol. The synthesized AgNPs were characterized using Ultraviolet-visible (UV-vis) spectroscopy, scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX), Fourier Transform Infrared Spectroscopy (FTIR), X-Ray diffraction analysis (XRD), Dynamic Light Scattering (DLS), and Transmission electron microscopy (TEM) techniques. The obtained sizes are as follows: 85 ± 15 nm, 70 ± 10 nm, 50 ± 10 nm, and 28-40 nm. The UV-vis spectroscopy revealed a shift in the absorbance peaks from 400 to 446 nm. The SEM method showed a spherical form in all of the samples. The element silver was detected in the EDX examination, along with the presence of oxygen (O) and carbon (C). The FTIR analysis revealed that the peaks seen at 3307 cm-1 were attributed to the stretching of O-H bonds, while the mountain at 1638 cm-1 belonged to the extension of N-H bonds (amide A). Additionally, the band observed at 1638 cm-1 indicated the presence of CO bonds (amide I).The 2140 cm-1 and 1302 cm-1 peaks may be attributed to the C2H2 group present in the plant components and the N-H bending (Amide III), respectively. The XRD pattern indicates that the synthesis process resulted in the formation of crystalline AgNPs. The particle sizes measured using DLS were 121 nm, 96.36 nm, 82.3 nm, and 48.50 nm. The TEM approach revealed that all samples had a spherical morphology with varying sizes: 80-100 nm, 50-80 nm, 40-60 nm, and 28-42 nm. The synthesized AgNPs were tested for their antibacterial properties against the pathogenic pathogens Escherichia coli (E.coli) and Staphylococcus aureus (S. aureus). The influence of AgNPs on bacteria was amplified as the particle size decreased, resulting in a larger inhibitory zone for the smaller particles.
7 July 2023 in International Journal of Applied Pharmaceutics
Biopolymers are a prominent class of functional materials ideal for high-value applications, and they fascinate researchers and experts from various fields. Polymers are flexible building blocks in many chemical combinations and blend to create composite materials with complementary qualities. The biomedical use of polymeric biomaterials was analyzed scientifically and technologically in this study, along with a compilation of their uses, manufacture, mechanical qualities, and key characteristics for the biomedical sector. The volume of scholarly publications and patents demonstrates the current knowledge of polymeric biomaterials. These biomaterials may now supplement, strengthen, or perform a particular role in the human body. Immune reactions persist due to the complexity of biological systems, impeding the growth of tissues and functioning organs in a laboratory setting.