Excessive levels of Fe, Mn and As are the main factors affecting groundwater quality in Songliao plain, northeast China. However, there are few studies on the source and mobilization mechanisms of Fe, Mn and As in the groundwater of Northeastern China. This study takes Shuangliao city in the middle of Songliao plain as an example, where the source and mobilization mechanisms of iron, manganese and arsenic in groundwater in the study area were analyzed by statistical methods and spatial analysis. The results show that the source of Fe and Mn in the groundwater of the platform is the iron and manganese nodules in the clay layer, while, in the river valley plain, it originates from the soil and the whole aquifer. The TDS, fluctuation in groundwater levels and the residence time are the important factors affecting the content of Fe and Mn in groundwater. The dissolution of iron and manganese minerals causes arsenic adsorbed on them to be released into groundwater. This study provides a basis for the rational utilization of groundwater and protection of people’s health in areas with high iron, manganese and arsenic contents.

Groundwater from deep confined aquifers is often recommended for use because of it's low fluoride health risk. Thus, this study appraised groundwater fluoride hydrochemistry in a multi-aquifer system in Jilin Qianan to determine the non-carcinogenic health risk liable from exploiting the respective aquifers. 124 samples collected from the tertiary confined aquifer (N), quaternary confined aquifer (Q1), and quaternary phreatic aquifer (Q3) during surveys in 2001 and 2017 was analyzed using hydrochemical, statistical, spatial, and health risk assessment methods. Results show that the dominant water facies in the respective aquifer layers was Na+K-HCO3+CO3 except in Q1, where Ca+Mg - HCO3 + CO3 was marginally dominant. Fluoride concentrations outside the recommended guideline occurred in all the aquifers except N, where concentrations were optimum. The mean fluoride concentration of groundwater in the aquifers was of the order Q3 (2017) > Q3 (2001) > Q1 > N ( mean 2.09, 2.03, 1.41 and 0.75 mg/L with 51.85%, 57.44%, 36.36% and 0% occurring beyond recommended guideline values respectively). Silicate weathering, cation exchange, and fluorite dissolution in an alkaline environment were the significant fluoride contributing processes. Evaporation and MgF+ complex additionally influenced Q1 and Q3 (2017). The total hazard quotient (THQ) from oral and dermal pathways shows fluoride health risks in the order: infant > children > adult. The associated risks likely from using water in the respective aquifer layers is of the order Q3 (2017) > Q3 (2001) > Q1 > N. The mean groundwater fluoride in 2017 was marginally higher than that of 2001 ( 2.09>2.03 mg/L respectively) although the percentage of age group members disposed to fluoride risk from using water from Q3 decreased from 2001 to 2017. Knowledge of local hydrogeology in exploiting deep groundwater free of fluoride pollution and on-site defluoridation treatment of groundwater was recommended in the study area and other areas with similar characteristics.

Hydrogeochemical research and water quality evaluation are an important part of groundwater development and management projects in Dehui City, Jilin Province, China. We collected 217 groundwater samples in the study area and used two multivariate statistical methods, hierarchical cluster analysis and principal component analysis to classify groundwater; combined graphical method, piper diagram, and Gibbs diagram to characterize groundwater chemical types and distinguish the water chemical control mechanism; and fuzzy comprehensive evaluation method to evaluate groundwater quality. Three major categories have been identified. Most of the groundwater in the study area is Ca-HCO₃ type water. The water chemistry control mechanism is determined to be based on water-rock interaction and less evaporation. From east to west in the study area, the total dissolved solids (TDS) gradually increased, and water quality gradually deteriorated. In the whole region, 79.26% of the groundwater is suitable for drinking. With Yinma River at the boundary, the water quality in the eastern part is excellent, while that in the southwest is poor. After appropriate treatment, it can be used in industry and agriculture. The excess NO₃⁻ is mainly affected by human activities. The unique geological conditions of the Songnen Plain result in an excess amount of Fe³⁺ and Mn²⁺ in some areas. This study determined the chemical characteristics of groundwater in the study area and distinguished water quality levels. The results will be helpful for the development and management of groundwater resources.

The two-parameter recursive digital filter method (Eckhardt) and the conductivity mass balance (CMB) method are two widely used baseflow separation methods favored by hydrologists. Some divergences in the application of these two methods have emerged in recent years. Some scholars believe that deviation of baseflow separation results of the two methods is due to uncertainty of the parameters of the Eckhardt method and that the Eckhardt method should be corrected by reference to the CMB method. However, other scholars attribute the deviation to the fact that they contain different transient water components. This study aimed to resolve this disagreement by analyzing the effectiveness of the CMB method for correcting the Eckhardt method through application of the methods to 26 basins in the United States by comparison of the biases between the generated daily baseflow series. The results showed that the approach of calibrating the Eckhardt method against the CMB method provides a “false” calibration of total baseflow by offsetting the inherent biases in the baseflow sequences generated by the two methods. The baseflow sequence generated by the Eckhardt method usually includes slow interflow and bank storage return flow, whereas that of the CMB method usually includes high-conductivity water flushed from swamps and depressions by rainfall, but not low-conductivity interflow and bank storage return flow. This difference results in obvious peak misalignment and periodic deviation between the baseflow sequences obtained by the two methods, thereby preventing calibration. However, multi-component separation of streamflow can be achieved through comparison. Future research should recognize the deviations between the separation results obtained by the different methods, identify the reasons for these differences, and explore the hydrological information contained therein.

In order to evaluate the groundwater resources and aquifer system of the Jilin urban area (JUA), a groundwater numerical flow model was established by using the groundwater modeling system based on data from 190 boreholes. River stages were interpolated to control the groundwater flow field. The input parameters such as hydraulic conductivity and specific yield were based on data from 260 pumping test data. The model was calibrated by trial and error, simulated results were compared to the observed head and contour maps, which were generally in good agreement, and the root mean squared error was 0.66 m. Sensitivity analysis was carried out and recharge proved to be the most sensitive factor in this model. The water budget showed that the input was 2.07× 10⁸ m³/a, which was smaller than the output of 2.21 × 10⁸ m³/a. A groundwater level decline and cone of depression exist in the Songhua and Aolong river valley. The JUA aquifer systems can be well and efficiently modeled by constructing a numerical model. Based on the supply and demand analysis of water resources, the established model would finally provide a scientific basis to use the groundwater resources sustainably in JUA.