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To use calcite mud waste generated from the paper production process, calcite mud was treated by calcination and then applied as a sorbent agent to remove phosphorus from an aqueous solution. The pre-treatment muds were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. The effects of calcite mud with different calcination temperatures on phosphorus removal were investigated. Different sorbent dosages, contact times, and initial phosphorus concentration conditions were also studied to understand the phosphorus removal mechanism. The results show that phosphorus removal efficiency was increased by increasing the calcination temperature of the mud. The phosphorus removal efficiency over 10 min increased by 35%, 82%, 98%, and 100% with 4.5, 6.75, 9.0, and 11.25 mg, respectively, of calcite mud calcined at 1000 °C. However, the efficiency decreased as initial phosphorus concentration increased. To study the phosphorus removal trend, the pseudo-first-order, pseudo-second-order, and intraparticle diffusion kinetic models were used. The Langmuir and Freundlich isotherm models were also used to further investigate the phosphorus adsorption mechanism characteristics of the calcite mud.
Hong Vu; Mohd Khan; Van Tran; Dang Quang; Van-Duong Dao; Seongho Lee; Ji Ahn; Seok-Ho Jung. Use of Calcite Mud from Paper Factories in Phosphorus Treatment. Sustainability 2020, 12, 5982 .
AMA StyleHong Vu, Mohd Khan, Van Tran, Dang Quang, Van-Duong Dao, Seongho Lee, Ji Ahn, Seok-Ho Jung. Use of Calcite Mud from Paper Factories in Phosphorus Treatment. Sustainability. 2020; 12 (15):5982.
Chicago/Turabian StyleHong Vu; Mohd Khan; Van Tran; Dang Quang; Van-Duong Dao; Seongho Lee; Ji Ahn; Seok-Ho Jung. 2020. "Use of Calcite Mud from Paper Factories in Phosphorus Treatment." Sustainability 12, no. 15: 5982.
In present work, environmentally benign green aragonite crystals were synthesized from waste chicken eggshells and bivalve seashells through a simple and low-cost wet carbonation method. This method involves a constant stirring of calcium oxide slurry and magnesium chloride suspension in aqueous solution with constraint carbon dioxide injection at 80 °C. The physicochemical properties of the synthesized aragonite were further compared with the aragonite synthesized from commercial calcium oxide. The morphological analysis, such as acicular shape and optimum aspect ratio (~21), were confirmed by scanning electron microscopy. The average crystal size (10–30 µm) and specific surface area (2–18 m2 g−1) were determined by particle size and Brunauer–Emmett–Teller analysis, respectively. Moreover, a schematic crystal growth mechanism was proposed to demonstrate the genesis and progression of aragonite crystal. Green aragonite can bridge the void for numerous applications and holds the potential for the commercial-scale synthesis with eggshells and bivalve seashells as low-cost precursors.
Lulit Habte; Mohd Danish Khan; Natnael Shiferaw; Adeeba Farooq; Mee-Hye Lee; Seok-Ho Jung; Ji Whan Ahn. Synthesis, Characterization and Mechanism Study of Green Aragonite Crystals from Waste Biomaterials as Calcium Supplement. Sustainability 2020, 12, 5062 .
AMA StyleLulit Habte, Mohd Danish Khan, Natnael Shiferaw, Adeeba Farooq, Mee-Hye Lee, Seok-Ho Jung, Ji Whan Ahn. Synthesis, Characterization and Mechanism Study of Green Aragonite Crystals from Waste Biomaterials as Calcium Supplement. Sustainability. 2020; 12 (12):5062.
Chicago/Turabian StyleLulit Habte; Mohd Danish Khan; Natnael Shiferaw; Adeeba Farooq; Mee-Hye Lee; Seok-Ho Jung; Ji Whan Ahn. 2020. "Synthesis, Characterization and Mechanism Study of Green Aragonite Crystals from Waste Biomaterials as Calcium Supplement." Sustainability 12, no. 12: 5062.
In the present work, waste eggshells were used as a precursor for the synthesis of aragonite crystals through the wet carbonation method. Cadmium (Cd2+) and lead (Pb2+) were removed by the synthesized aragonite from synthetic wastewater. The influence of initial solution pH, contact time, Cd2+ and Pb2+ concentration, and sorbent dosage were evaluated. The major sorption was observed in the first 100 mins and 360 mins for Pb2+and Cd2+ respectively reaching sorption equilibrium at 720 mins (12 hr). The sorption capacity toward Pb2+ was much higher than toward Cd2+. Both heavy metals displayed high sorption capacities at initial pH 6. The pseudo-second-order kinetic model fits well with the experimental data with a higher correlation coefficient R2. Two isotherm models were also evaluated for the best fit with the experimental data obtained. Langmuir isotherm best fits the sorption of the metals on aragonite synthesized from eggshells. X-ray diffraction (XRD) and Scanning electron microscopy (SEM) results of sorbent after sorption showed that the mechanism of sorption was dominated by surface precipitation. Therefore, aragonite crystals synthesized from waste eggshells can be a potential substitute source for the removal of Cd2+ and Pb2+ from contaminated water.
Lulit Habte; Natnael Shiferaw; Mohd Danish Khan; Thenepalli Thriveni; Ji Whan Ahn. Sorption of Cd2+ and Pb2+ on Aragonite Synthesized from Eggshell. Sustainability 2020, 12, 1174 .
AMA StyleLulit Habte, Natnael Shiferaw, Mohd Danish Khan, Thenepalli Thriveni, Ji Whan Ahn. Sorption of Cd2+ and Pb2+ on Aragonite Synthesized from Eggshell. Sustainability. 2020; 12 (3):1174.
Chicago/Turabian StyleLulit Habte; Natnael Shiferaw; Mohd Danish Khan; Thenepalli Thriveni; Ji Whan Ahn. 2020. "Sorption of Cd2+ and Pb2+ on Aragonite Synthesized from Eggshell." Sustainability 12, no. 3: 1174.
For decades, researchers have debated whether climate change has an adverse impact on diseases, especially infectious diseases. They have identified a strong relationship between climate variables and vector’s growth, mortality rate, reproduction, and spatiotemporal distribution. Epidemiological data further indicates the emergence and re-emergence of infectious diseases post every single extreme weather event. Based on studies conducted mostly between 1990-2018, three aspects that resemble the impact of climate change impact on diseases are: (a) emergence and re-emergence of vector-borne diseases, (b) impact of extreme weather events, and (c) social upliftment with education and adaptation. This review mainly examines and discusses the impact of climate change based on scientific evidences in published literature. Humans are highly vulnerable to diseases and other post-catastrophic effects of extreme events, as evidenced in literature. It is high time that human beings understand the adverse impacts of climate change and take proper and sustainable control measures. There is also the important requirement for allocation of effective technologies, maintenance of healthy lifestyles, and public education.
Mohd Danish Khan; Hong Ha Thi Vu; Quang Tuan Lai; Ji Whan Ahn. Aggravation of Human Diseases and Climate Change Nexus. International Journal of Environmental Research and Public Health 2019, 16, 2799 .
AMA StyleMohd Danish Khan, Hong Ha Thi Vu, Quang Tuan Lai, Ji Whan Ahn. Aggravation of Human Diseases and Climate Change Nexus. International Journal of Environmental Research and Public Health. 2019; 16 (15):2799.
Chicago/Turabian StyleMohd Danish Khan; Hong Ha Thi Vu; Quang Tuan Lai; Ji Whan Ahn. 2019. "Aggravation of Human Diseases and Climate Change Nexus." International Journal of Environmental Research and Public Health 16, no. 15: 2799.
In this study, we present a low-cost and simple method to treat spent lead–acid battery wastewater using quicklime and slaked lime. The sulfate and lead were successfully removed using the precipitation method. The structure of quicklime, slaked lime, and resultant residues were measured by X-ray diffraction. The obtained results show that the sulfate removal efficiencies were more than 97% for both quicklime and slaked lime and the lead removal efficiencies were 49% for quicklime and 53% for slaked lime in a non-carbonation process. After the carbonation step, the sulfate removal efficiencies were slightly decreased but the lead removal efficiencies were 68.4% for quicklime and 69.3% for slaked lime which were significantly increased compared with the non-carbonation process. This result suggested that quicklime, slaked lime, and carbon dioxide can be a potential candidate for the removal of sulfate and lead from industrial wastewater treatment.
Hong Ha Thi Vu; Shuai Gu; Thenepalli Thriveni; Mohd Danish Khan; Lai Quang Tuan; Ji Whan Ahn. Sustainable Treatment for Sulfate and Lead Removal from Battery Wastewater. Sustainability 2019, 11, 3497 .
AMA StyleHong Ha Thi Vu, Shuai Gu, Thenepalli Thriveni, Mohd Danish Khan, Lai Quang Tuan, Ji Whan Ahn. Sustainable Treatment for Sulfate and Lead Removal from Battery Wastewater. Sustainability. 2019; 11 (13):3497.
Chicago/Turabian StyleHong Ha Thi Vu; Shuai Gu; Thenepalli Thriveni; Mohd Danish Khan; Lai Quang Tuan; Ji Whan Ahn. 2019. "Sustainable Treatment for Sulfate and Lead Removal from Battery Wastewater." Sustainability 11, no. 13: 3497.
Climate change is considered to be a potential cause of global warming, which leads to a continuous rise in the global atmospheric temperature. This rising temperature also alters precipitation conditions and patterns, thereby causing frequent occurrences of extreme calamity, particularly droughts and floods. Much evidence has been documented by the Intergovernmental Panel on Climate Change, illustrating fluctuations in precipitation patterns caused by global climate change. Recent studies have also highlighted the adverse impact of climate change on river flow, groundwater recovery, and flora and fauna. The theoretical political approach and scientific progress have generated ample opportunities to employ previously allusive methods against impacts caused by varying climatic parameters. In this study, the current state of India’s water environment policy is compared with that of South Korea. The “3Is”—ideas, institutions, and interests—which are considered pillars in the international field of political science, are used as variables. The concept of “ideas” highlights the degree of awareness regarding climate change while formulating water environment policy. Here, the awareness of India’s management regarding emerging water issues related to climate change are discussed and compared with that of South Korea. The concept of “institutions” illustrates the key differences in water environment policy under the umbrella of climate change between both countries within the associated national administrations. India’s administrations, such as the Ministry of Environment, Forests, and Climate Change; the Ministry of Water Resources, River Development, and Ganga Rejuvenation; the Ministry of Rural Development; and the Ministry of Housing and Urban Affairs, are used as a case study in this work. Finally, the concept of “interest” elaborates the prioritization of key issues in the respective water environment policies. Common interests and voids in the policies of both countries are also briefly discussed. A comparison of India’s water environment policies with that of South Korea is made to expose the gaps in India’s policies with respect to climate change, thereby seeking to identify a solution and the optimal direction for the future of the water environment policy of India.
Mohd Danish Khan; Sonam Shakya; Hong Ha Thi Vu; Ji Whan Ahn; Gnu Nam. Water Environment Policy and Climate Change: A Comparative Study of India and South Korea. Sustainability 2019, 11, 3284 .
AMA StyleMohd Danish Khan, Sonam Shakya, Hong Ha Thi Vu, Ji Whan Ahn, Gnu Nam. Water Environment Policy and Climate Change: A Comparative Study of India and South Korea. Sustainability. 2019; 11 (12):3284.
Chicago/Turabian StyleMohd Danish Khan; Sonam Shakya; Hong Ha Thi Vu; Ji Whan Ahn; Gnu Nam. 2019. "Water Environment Policy and Climate Change: A Comparative Study of India and South Korea." Sustainability 11, no. 12: 3284.
In this study, we utilized lime mud waste from paper mills to synthesize calcium hydroxide (Ca(OH)2) nanoparticles (NPs) and investigate their application for the removal of phosphorus from aqueous solution. The NPs, composed of green portlandite with hexagonal shape, were successfully produced using a precipitation method at moderately high temperature. The crystal structure and characterization of the prepared Ca(OH)2 nanoparticles were analyzed by field emission scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. The effects of Ca(OH)2 NP dosage and contact time on removal of phosphorus were also investigated. The results show that the green portlandite NPs can effectively remove phosphorus from aqueous solution. The phosphorus removal efficiencies within 10 min are 53%, 72%, 78%, 98%, and 100% with the different mass ratios of Ca(OH)2 NPs/phosphorus (CNPs/P) of 2.2, 3.5, 4.4, 5.3, and 6.2, respectively. Due to the efficient phosphorus removal, the calcium hydroxide nanoparticles (CNPs) could be a potential candidate for this application in domestic or industrial wastewater treatment.
Hong Ha Thi Vu; Mohd Danish Khan; Ramakrishna Chilakala; Tuan Quang Lai; Thriveni Thenepalli; Ji Whan Ahn; Dong Un Park; Jeongyun Kim. Utilization of Lime Mud Waste from Paper Mills for Efficient Phosphorus Removal. Sustainability 2019, 11, 1524 .
AMA StyleHong Ha Thi Vu, Mohd Danish Khan, Ramakrishna Chilakala, Tuan Quang Lai, Thriveni Thenepalli, Ji Whan Ahn, Dong Un Park, Jeongyun Kim. Utilization of Lime Mud Waste from Paper Mills for Efficient Phosphorus Removal. Sustainability. 2019; 11 (6):1524.
Chicago/Turabian StyleHong Ha Thi Vu; Mohd Danish Khan; Ramakrishna Chilakala; Tuan Quang Lai; Thriveni Thenepalli; Ji Whan Ahn; Dong Un Park; Jeongyun Kim. 2019. "Utilization of Lime Mud Waste from Paper Mills for Efficient Phosphorus Removal." Sustainability 11, no. 6: 1524.