This paper focuses on the distribution of volatile organic compounds (VOCs) in the surface water, soil, and groundwater within a chemical industry park in Eastern China. At least one VOC was detected in each of the 20 sampling sites, and the maximum number of VOCs detected in the surface water, groundwater, and soil were 13, 16, and 14, respectively. Two of the 10 VOCs with elevated concentrations detected in surface water, groundwater, and soil were chloroform and 1,2-dichloroethane. The characteristics of VOCs, which include volatility, boiling point, and solubility, could significantly affect their distribution in surface water, soil, and groundwater. However, due to the direct discharging of chemical industry wastewater into surface water, higher concentrations of VOCs (except chloroform) were detected in surface water than in soil and groundwater. Fortunately, the higher volatility of VOCs prevents the VOCs from impacting groundwater, which helps to maintain a lower concentration of VOCs in the groundwater than in both surface water and soil. This is because pollutants with relatively higher boiling points and lower solubilities have higher detection frequencies in soil, and contaminants with relatively lower boiling points and higher solubilities have higher detection frequencies in water, notably in surface water.

Trees play important roles in urban stormwater management; through the loosening of soils by root growth, they increase infiltration and reduce runoff, helping to mitigate flooding and recharge groundwater. Malus baccata with fibrous roots and Sophora japonica with tap roots were studied experimentally to assess their enhancement of soil infiltration. A blank test without a tree was conducted for comparison. Steady-state soil infiltration rates at the bottom of test tanks were measured as 0.28 m/d, 0.33 m/d, and 0.61 m/d for the blank test, M. baccata, and S. japonica, respectively. This represents a 19% increase in the infiltration rate by planting M. baccata and a 118% increase by planting S. japonica. A larger increase in the infiltration rate by S. japonica is consistent with the effects of deeper and more vertical roots that help loosen deeper soils. Spatial variations in soil infiltration rates were also measured. Infiltration rates for M. baccata (1.06 m/d and 0.62 m/d) were larger than those for S. japonica (0.91 m/d and 0.51 m/d) at the same depths (0.35 m and 0.70 m); this is consistent with the expected effects of the shallower and more lateral roots of M. baccata. This study furthers our understanding of the roles of trees in watersheds and urban environments.