Dental and emaciated fluorosis is derived from the chronic intake of fluoride ions (F⁻) by consumption of food, tooth products and drinking water from groundwater. Recent reports indicate that in some regions of Mexico, the incidence of fluorosis in temporary and permanent dentitions have increased in recent years. The purpose of the present investigation was to determine the presence and distribution of F⁻ ions in semi-confined aquifers, located in the basins of Lerma-Chapala and Valley of México. Temperature (T), pH, electrical conductivity (EC) and alkalinity were determined in situ, in 27 groundwater wells. The hardness, chloride ions (Cl⁻), free chlorine (Cl₂), total dissolved solids (TDS) and bicarbonates (HCO₃⁻), were determined in the laboratory. The high content of bicarbonate ions (HCO₃⁻) is associated with the alteration of silicates and the presence of chloride ions (Cl⁻) due to the anthropogenic activity. The highest value of fluoride ions (F⁻) (1.31 mg/L) was identified in a well of the Lerma-Chapala basin and in 25% of the samples (1.056 mg/L) of the Valley of México basin. The groundwater in the Lerma-Chapala basin is of the Ca-HCO₃ type and the water in the Valley of Mexico basin is Na-HCO₃ and Ca-HCO₃. According to the Gibbs diagram, the water of the Toluca Valley aquifer is recharged by local meteoric precipitation and consequent the water-rock interaction occurs. The correlation analysis shows the significant relationship between F⁻ and CE (R = 0.5933), F⁻ and alkalinity (R = 0.6924), F⁻ and HCO₃⁻ (R = 0.6924) and F⁻ and TDS (R = 0.5933). The correlations confirm that the content of fluoride ions present in groundwater is associated with high concentrations of bicarbonate ions and the presence of sodium, due to a process of alteration of the silicates.

The removal of pollutants from textile wastewater via electrochemical oxidation and a coupled system electrooxidation—Salix babylonica, using boron-doped diamond electrodes was evaluated. Under optimal conditions of pH 5.23 and 3.5 mA·cm⁻² of current density, the electrochemical method yields an effective reduction of chemical oxygen demand by 41.95%, biochemical oxygen demand by 83.33%, color by 60.83%, and turbidity by 26.53% at 300 minutes of treatment. The raw and treated wastewater was characterized by infrared spectroscopy to confirm the degradation of pollutants. The wastewater was oxidized at 15-minute intervals for one hour and was placed in contact with willow plants for 15 days. The coupled system yielded a reduction of the chemical oxygen demand by 14%, color by 85%, and turbidity by 93%. The best efficiency for the coupled system was achieved at 60 minutes, at which time the plants achieved more biomass and photosynthetic pigments.

Sanitary landfills are considered one of the main sources of contamination of water resources due to the generation of leachate with a high content of dissolved organic matter (DOM), inorganic material, and toxic elements. This study aimed to determine the influence of leachate on the physicochemical quality and hydrogeochemical processes which determine the chemical composition of groundwater in an area near a municipal sanitary landfill site. In situ parameters (pH, temperature, electrical conductivity, dissolved oxygen, ORP), physicochemical parameters (HCO₃⁻, PO₄³⁻, Cl⁻, NO₃⁻, SO₄²⁻, NH₄⁺, Ca²⁺, Mg²⁺, Na⁺, K⁺), and dissolved organic matter were analyzed. The content of dissolved organic matter (DOM) was determined by 3D fluorescence microscopy. The presence of Cl⁻, NO₃⁻, NH₄⁺, PO₄³⁻, BOD, and COD indicated the presence of contamination. The significant correlation between NO₃⁻ and PO₄³⁻ ions (r = 0.940) and DOM of anthropogenic origin in the 3D fluorescence spectra confirm that its presence in the water is associated with the municipal landfill site in question. The type of water in the area is Mg-HCO₃, with a tendency to Na-HCO₃ and Na-SO₊-Cl. The water-rock interaction process predominates in the chemical composition of water; however, significant correlations between Na⁺ and Ca²⁺ (r = 0.876), and between K⁺ and Mg²⁺ (r = 0.980) showed that an ion exchange process had taken place. Likewise, there is enrichment by HCO₃⁻ and SO₄²⁻ ions due to the mineralization of the organic matter from the leachate. The groundwater quality that supplies the study area is being affected by leachate infiltration from the sanitary landfill.