Sustainable and affordable supply of clean, safe, and adequate water is one of the most challenging issues facing the world. Membrane separation technology is one of the most cost-effective and widely applied technologies for water purification. Polymeric membranes such as cellulose-based (CA) membranes and thin-film composite (TFC) membranes have dominated the industry since 1980. Although further development of polymeric membranes for better performance is laborious, the research findings and sustained progress in inorganic membrane development have grown fast and solve some remaining problems. In addition to conventional ceramic metal oxide membranes, membranes prepared by graphene oxide (GO), carbon nanotubes (CNTs), and mixed matrix materials (MMMs) have attracted enormous attention due to their desirable properties such as tunable pore structure, excellent chemical, mechanical, and thermal tolerance, good salt rejection and/or high water permeability. This review provides insight into synthesis approaches and structural properties of recent reverse osmosis (RO) and nanofiltration (NF) membranes which are used to retain dissolved species such as heavy metals, electrolytes, and inorganic salts in various aqueous solutions. A specific focus has been placed on introducing and comparing water purification performance of different classes of polymeric and ceramic membranes in related water treatment industries. Furthermore, the development challenges and research opportunities of organic and inorganic membranes are discussed and the further perspectives are analyzed.
The anodic polarization response of magnesium alloy AZ31 was first characterized during exposure to aerated 0.1 M NaCl solutions with millimolar additions of NaVO3, Na3PO4, Na2HPO4, NaF and various pairings to assess their ability to inhibit corrosion kinetics and retard localized corrosion. Each of the candidate inhibitors reduced the corrosion rate of the alloy to some degree. A Na3PO4–NaVO3 pair produced a good inhibiting effect decreasing the corrosion rate to about 10−7 A/cm2, which was two orders of magnitude lower than the uninhibited control case. A Bliss Independence assessment indicated that this inhibitor pair acted synergistically. A Na2HPO4–NaVO3 pair reduced the corrosion rate to 10−6 A/cm2 but was not assessed to be acting synergistically. The NaVO3–NaF pair did not reduce the corrosion rate significantly compared to the control case and was an antagonistic pairing. SEM imaging showed film formation due to exposure, which appears to be the origin of the observed inhibition. The resistance to localized corrosion was assessed as the difference in the breakdown potential and the corrosion potential, with larger values indicating a lower probability of localized corrosion during free corrosion exposures. The effects of the inhibitors on this characteristic were mixed, but each of the inhibitor pairs yielded potential differences in excess of 100 mV. A conceptual conversion coating process based on a mixture of vanadate and phosphate compounds were demonstrated. A fluoride-bearing formulation produced coatings whose total impedance was increased by a factor of two compared to an uncoated control. A fluoride-free formulation produced coatings whose corrosion resistance was increased by more than a factor of three.
The increase in the number of space debris is a serious threat to the safe operation of in-orbit spacecraft. The propagation law of the impact signal in the stiffened panel of the spacecraft’s sealed bulkhead is very complicated, and there is less research on the impact source location in the high-stiffened panel. In this paper, an adaptive energy compensation threshold filtering (AECTF) method based on acoustic emission is proposed, which can realize large-scale, fast and accurate locating of the impact source on the stiffened panel with less resource consumption. The influence law of the stiffeners on the lamb wave is analyzed by finite element simulation, and the Lamb wave energy factor curve is obtained. The correctness of the simulation is verified by the locating experiment on the impact point. The results show that the proposed AECTF method has better adaptability and can correctly locate the impact points in complicated locations. By selecting the appropriate frequency band to filter the signal, the locating accuracy and stability can be improved. When the frequency band is 100–200 kHz, the locating result is optimal, the average absolute error is 7.0 mm, the average relative error is 0.86%, and the error standard deviation is 3.5 mm. This study will generate fresh insight into the impact location technology of high-stiffened panel and provide a reference for the in-orbit spacecraft health monitoring system.
Thin, supported inorganic mesoporous membranes are used for the removal of salts, small molecules (PFAS, dyes, and polyanions) and particulate species (oil droplets) from aqueous sources with high flux and selectivity. Nanofiltration membranes can reject simple salts with 80–100% selectivity through a space charge mechanism. Rejection by size selectivity can be near 100% since the membranes can have a very narrow size distribution. Mesoporous membranes have received particular interest due to their (potential) stability under operational conditions and during defouling operations. More recently, membranes with extreme stability became interesting with the advent of in situ fouling mitigation by means of ultrasound emitted from within the membrane structure. For this reason, we explored the stability of available and new membranes with accelerated lifetime tests in aqueous solutions at various temperatures and pH values. Of the available ceria, titania, and magnetite membranes, none were actually stable under all test conditions. In earlier work, it was established that mesoporous alumina membranes have very poor stability. A new nanofiltration membrane was made of cubic zirconia membranes that exhibited near-perfect stability. A new ultrafiltration membrane was made of amorphous silica that was fully stable in ultrapure water at 80 °C. This work provides details of membrane synthesis, stability characterization and data and their interpretation.
Composite materials are widely used, but they are often subjected to impacts from foreign objects, causing structural damage. To ensure the safety of use, it is necessary to locate the impact point. This paper investigates impact sensing and localization technology for composite plates and proposes a method of acoustic source localization for CFRP composite plates based on wave velocity-direction function fitting. This method divides the grid of composite plates, constructs the theoretical time difference matrix of the grid points, and compares it with the actual time difference to form an error matching matrix to localize the impact source. In this paper, finite element simulation combined with a lead-break experiment is used to explore the wave velocity-angle function relationship of Lamb waves in composite materials. The simulation experiment is used to verify the feasibility of the localization method, and the lead-break experimental system is built to locate the actual impact source. The results show that the acoustic emission time-difference approximation method can effectively solve the problem of impact source localization in composite structures, and the average localization error is 1.44 cm and the maximum localization error is 3.35 cm in 49 experimental points with good stability and accuracy.