Efficiency from hole-selective contacts: Perovskite/silicon tandem solar cells must stabilize a perovskite material with a wide bandgap and also maintain efficient charge carrier transport. Al-Ashouri et al. stabilized a perovskite with a 1.68–electron volt bandgap with a self-assembled monolayer that acted as an efficient hole-selective contact that minimizes nonradiative carrier recombination. In air without encapsulation, a tandem silicon cell retained 95% of its initial power conversion efficiency of 29% after 300 hours of operation. Science , this issue p. 1300
1 January 2014 in Journal of Extracellular Vesicles
Background: Extracellular vesicles (EVs) have clinical importance due to their roles in a wide range of biological processes. The detection and characterization of EVs are challenging because of their small size, low refractive index, and heterogeneity.Methods: In this manuscript, the size distribution of an erythrocyte‐derived EV sample is determined using state‐of‐the‐art techniques such as nanoparticle tracking analysis, resistive pulse sensing, and electron microscopy, and novel techniques in the field, such as small‐angle X‐ray scattering (SAXS) and size exclusion chromatography coupled with dynamic light scattering detection.Results: The mode values of the size distributions of the studied erythrocyte EVs reported by the different methods show only small deviations around 130 nm, but there are differences in the widths of the size distributions.Conclusion: SAXS is a promising technique with respect to traceability, as this technique was already applied for traceable size determination of solid nanoparticles in suspension. To reach the traceable measurement of EVs, monodisperse and highly concentrated samples are required.
The normal field instability in magnetic liquids is investigated experimentally by means of a radioscopic technique which allows a precise measurement of the surface topography. The dependence of the topography on the magnetic field is compared to results obtained by numerical simulations via the finite-element method. Quantitative agreement has been found for the critical field of the instability, the scaling of the pattern amplitude and the detailed shape of the magnetic spikes. The fundamental Fourier mode approximates the shape to within 10% accuracy for a range of up to 40% of the bifurcation parameter of this subcritical bifurcation. The measured control parameter dependence of the wavenumber differs qualitatively from analytical predictions obtained by minimization of the free energy.
Four common size analysis techniques were applied to engineered silica nanoparticles suspended in purified water, in physiological buffer and in cell culture medium, and the results were compared using uncertainty estimates.
The successful translation of nanoparticle-based systems into commercial products depends upon the ability to reliably measure important physical and chemical properties of these particles. The density of nanoparticles is one such property, because it provides important information about the composition of the material. In this work, an analytical centrifugation approach based on line-start centrifugal sedimentation and flotation measurements is described. The two independent measurements permit both the size and the density of these nanoparticles to be determined with excellent precision. A set of monodisperse polystyrene nanoparticles of different sizes is used to demonstrate this method. The density and size measurements are validated by comparison to accurate Small Angle X-ray Scattering (SAXS) analysis for particles within the size range of SAXS, i.e. less than ∼300 nm in diameter. Both sedimentation and flotation measurements produce consistent high resolution size distributions of the particles and the measured size and density values are identical, within experimental uncertainty, to the SAXS results. This approach has the potential to provide useful characterisation of a range of particles of interest, for example, for medical application, such as liposomes and polymeric drug carriers.