The effect of tin content in an Al-Sn alloy in the range from 0 to 100 at.% on its mechanical properties was studied. An increase in the tin content leads to a monotonic decrease in the microhardness and conditional yield stress of the Al-Sn alloy from 305 to 63 MPa and from 32 to 5 MPa, respectively. In addition, Young’s modulus and the shear modulus of the Al-Sn alloy decreases from 65 to 52 GPa and from 24 to 20 GPa, respectively. The effect of tin content in the Al-Sn matrix alloy in the range from 0 to 50 at.% on the strength of a carbon fiber/aluminum-tin-matrix (CF/Al-Sn) composite wire subject to three-point bending was also investigated. Increasing tin content up to 50 at.% leads to a linear increase in the composite wire strength from 1450 to 2365 MPa, which is due to an increase in the effective fiber strength from 65 to 89 at.%. The addition of tin up to 50 at.% to the matrix alloy leads to the formation of weak boundaries between the matrix and the fiber. An increase in the composite wire strength is accompanied by an increase in the average length of the fibers pulled out at the fracture surface. A qualitative model of the relationship between the above parameters is proposed.
Research on carbon fiber oxide coatings is primarily focused on metal matrix composites. Such coatings act as a diffusion barrier between a matrix and a fiber and, in addition, they can be weak boundaries that significantly increase the mechanical properties of metal matrix composites. A simple and economical method of coating deposition is the sol-gel method. However, it does not allow for control of the thickness of the carbon fiber coating. To eliminate this limitation, a combined method is used that includes sol-gel technology and electrochemical deposition. The paper presents the results of studies on the production of SiO2 coatings on carbon fibers by the above method. The effect of current density, deposition time, salt concentration, pH of the reaction medium, TEOS/H2O molar ratio, and alcohol concentration in the reaction medium on the structure and thickness of the coatings was studied.
17 January 2022 in Composites Part A: Applied Science and Manufacturing
The process of the production of a CF/Al-wire by pulling carbon fibers through an aluminum melt has at least 15 parameters. The main parameters include the power of ultrasonic treatment, the time of contact of the fiber with the matrix melt, and the melt temperature. In addition, the presence of a barrier coating on the fiber surface and its thickness significantly affects the properties of the resulting material. The importance of these parameters is due to their direct effect on the chemical interaction between the aluminum matrix and the carbon fiber. This interaction leads to the formation of aluminum carbide, a hygroscopic, brittle phase that ultimately significantly reduces the strength of such composites. In this regard, limiting a chemical reaction at the matrix/fiber interface in the production of CF/Al composites is one of the main technological problems. The main goal of this work is to pragmatically elucidate the effect of the above parameters on the strength of CF/Al composites. It is shown that the strength of a CF/Al-wire can reach 2000 MPa.
Taking the example of a composite wire with an Al-25% Sn alloy matrix reinforced with carbon fiber, the dependence of composite bending strength on interface shear strength was determined. Samples of the composite wire with different interface shear strengths were obtained by heat treatment at temperatures from 300 to 600 °C. The highest bending strength of 2450 MPa was observed for composite wire samples with the lowest interface shear strength. With an increase in the shear strength of the interface, a decrease in the strength was observed. The study of the surface of carbon fiber extracted from the composite showed that heat treatment led to the formation of aluminum carbide crystals on the fiber surface, the size and number of which increased with increasing temperature. As a result, there was an increase in the shear strength of the interface. The evaluation of the work of fracture of a composite with different strengths of the interface between the matrix and the fiber demonstrated that as the strength of the interface increases, the work of fracture decreases, due to the premature fracture of the composite through crack propagation in one plane. Based on the experimental data, the refined mixture rule according to the Weibull distribution, and an assessment of the critical stress of crack propagation according to the Griffith–Orowan–Irwin concept, the dependence of composite strength on the shear strength of the interface was estimated. Due to this, the critical shear strength was calculated at which the greatest strength of the composite can be achieved, these values being 107 MPa and 2675 MPa, respectively. It is shown that the contribution of the work of overcoming the friction force to the total work of fracture at relatively small values of shear strength can be several times greater than the total contribution of all other types of energy.