Rock destruction under high‐temperature conditions is a key issue for nuclear waste treatment projects, underground coal gasification, and improvement of the use of geothermal energy for heating. Therefore, in this study, various methods and techniques were integrated to study the changes in mechanical properties, mineral composition, and microscopic fracture characteristics of Sichuan sandstone treated at 600°C. First, the fracture toughness and indirect tensile strength of untreated sandstones and high‐temperature treated sandstones were tested by the MTS testing machine, and the double‐K model (DKFM) was used to estimate the unstable fracture toughness. Then, the diffraction spectra of sandstone were analyzed with an X‐ray diffractometer to determine the mineral composition change after heat treatment. Finally, the microscopic features of sandstone were observed through a scanning electron microscope (SEM) and optical microscope. The results show the following. (1) There is no significant change in the tensile strength and fracture toughness of Sichuan sandstone treated at 600°C. (2) The brittleness of Sichuan sandstone decreases and the ductility increases after high‐temperature treatment. (3) The unstable fracture toughness value Kun obtained by the double‐K model (DKFM) is significantly larger than the apparent fracture toughness value Kif. (4) After treatment at 600°C, the clay minerals in the sandstone changed significantly. Kaolinite is dehydroxylated to metakaolinite, which may increase the ductility of the rock.
1 January 2021 in Advances in Materials Science and Engineering
High temperature can change the mechanical properties of granite, with significant nonlinear characteristics, and at the same time change its microstructure. Therefore, two kinds of granites are used in this paper: one is normal temperature granite and the other is granite treated at 600°C, and a detailed comparative study is made. The fracture toughness of two kinds of rocks was tested by fracture tests, and the results were analyzed by a nonlinear fracture mechanics model (SEL). At the same time, in order to understand the influence of high temperature on the mineral composition and microstructure of granite, XRD, optical microscope, and SEM were used to observe the mineral composition, microcracks, and fracture morphology of granite. The results show the following: (1) high temperature significantly changes the fracture mechanics parameters of granite. The fracture toughness of granite treated at 600°C is significantly lower than that of untreated granite, which is reduced by more than 60%. (2) No obvious size effect was found in the untreated granite, while the size effect of the granite after treatment at 600°C was significant. (3) The granite after high‐temperature treatment showed strong nonlinear characteristics, and the SEL can reasonably describe and explain its nonlinear fracture characteristics. (4) The brittleness of the granite treated at 600°C decreased and the ductility increased. The microscopic morphology of the fracture was rough, with obvious steps and rivers. The microcracks and porosity had increased significantly, but the main components did not change significantly.
This paper investigates the unstable fracture toughness of specimens of different heights using the double‐K model for three‐point bending tests on notched concrete beams. It is shown that unstable fracture toughness exhibits a significant size effect. The modified maximum tangential stress (MMTS) criterion is used to explain the size effect of unstable fracture toughness. The MMTS criterion considers the higher order terms of the Williams series expansion of the stress field. The results show that the MMTS criterion can reasonably estimate unstable fracture toughness. It is recommended that the minimum height of the specimen be 200 mm when three‐point bending tests on notched beams are used to determine unstable fracture toughness.
In this paper, confined explosions of HMX-based thermobaric explosives containing oxidizers in a spherical chamber were studied by changing the type of the oxidizer and the oxygen concentration in the environment. Based on an in-house developed optical-electrical system, the optical radiation signals of Al2O3 during the afterburning reaction were recorded. The results show that aluminum particles (5.4 µm) were strongly dependent on the oxygen concentration in the environment. Increasing the oxygen concentration can prolong the oxidation duration of Al and enhance the optical radiation intensity of Al2O3. The optical radiation result for Al2O3 in O2 and air showed that aluminum particles (the mass fraction was 33 %) were not completely oxidized in the air, and the oxidation duration was 500–700 µs. Moreover, the pressure data of the blast waves was obtained using a pressure-measurement system. The results showed that an increase in the oxygen concentration of the explosive could further enhance the total impulse, especially an addition of KP (its mass fraction was 10 %) could increase the total impulse by about 9 %.