Amorphous alloy is an emerging metal material, and its unique atomic arrangement brings it the excellent properties of high strength and high hardness, and, therefore, have attracted extensive attention in the fields of electronic information and cutting-edge products. Their applications involve machining and forming, make the machining performance of amorphous alloys being a research hotspot. However, the present research on amorphous alloys and their machining performance is widely focused, especially for Fe-based amorphous alloys, and there lacks a systematic review. Therefore, in the present research, based on the properties of amorphous alloys and Fe-based amorphous alloys, the fundamental reason and improvement method of the difficult-to-machine properties of Fe-based amorphous alloys are reviewed and analyzed. Firstly, the properties of amorphous alloys are summarized, and it is found that crystallization and high temperature in machining are the main reasons for difficult-to-machine properties. Then, the unique properties, preparation and application of Fe-based amorphous alloys are reviewed. The review found that the machining of Fe-based amorphous alloys is also deteriorated by extremely high hardness and chemical tool wear. Tool-assisted machining, low-temperature lubrication assisted machining, and magnetic field-assisted machining can effectively improve the machining performance of Fe-based amorphous alloys. The combination of assisted machining methods is the development trend in machining Fe-based amorphous alloys, and even amorphous alloys in the future. The present research provides a systematic summary for the machining of Fe-based amorphous alloys, which would serve as a reference for relevant research.

Micro-structured surfaces possess excellent properties of friction, lubrication, drag reduction, antibacterial, and self-cleaning, which have been widely applied in optical, medical, national defense, aerospace fields, etc. Therefore, it is requisite to study the fabrication methods of micro-structures to improve the accuracy and enhance the performance of micro-structures. At present, there are plenty of studies focusing on the preparation of micro-structures; therefore, systematic review of the technologies and developing trend on the fabrication of micro-structures are needed. In present review, the fabrication methods of various micro-structures are compared and summarized. Specially, the characteristics and applications of ultra-precision machining (UPM) technology in the fabrication of micro-structures are mainly discussed. Additionally, the assistive technologies applied into UPM, such as fast tool servo (FTS) technology and slow tool servo (STS) technology to fabricate micro-structures with different characteristics are summarized. Finally, the principal characteristics and applications of fly cutting technology in manufacturing special micro-structures are presented. From the review, it is found that by combining different machining methods to prepare the base layer surface first and then fabricate the sublayer surface, the advantages of different machining technologies can be greatly exerted, which is of great significance for the preparation of multi-layer and multi-scale micro-structures. Furthermore, the combination of ultra-precision fly cutting and FTS/STS possess advantages in realizing complex micro-structures with high aspect ratio and high resolution. However, residual tool marks and material recovery are still the key factors affecting the form accuracy of machined micro-structures. This review provides advances in fabrication methods and assistive technologies of micro-structured surfaces, which serves as the guidance for both fabrication and application of multi-layer and multi-scale micro-structures.