Cemented carbide (WC–Co) is applied as the substrate instead of conventional ones such as Si, Ti, and Nb, on which nanocrystalline BDD films are deposited by hot filament chemical vapor deposition. Then the WC–Co/BDD electrodes are investigated by Field Emission Scanning Electron Microscopy (FE-SEM), Micro-Raman Spectroscopy, X-ray photoelectron spectroscopy (XPS), a four-point probe method, accelerated life test (ALT), and electrochemical analysis. According to the results, the BDD films deposited on the WC–Co substrate are highly uniform and pinhole-free with a grain size of 100 nm and a low compressive stress. The WC–Co/BDD electrode has a wide potential window of 3.8 V and low background currents in 0.5 mol L⁻¹ H₂SO₄ electrolytes and shows a quasi-reversible behavior in the K₃[Fe(CN)₆] redox system. The electrode has a service life of more than 400 h in the ALT with 3 mol L⁻¹ H₂SO₄ electrolytes at a constant current density of 1 A cm⁻². These electrochemical performances of BDD films on the WC–Co substrate is similar to or even slightly better than that on the commonly used substrates. Finally, phenol is used as a pollutant to test the activity of the WC–Co/BDD electrode. The results of replicated experiments show that the average COD reduces from the initial 5795 to 85 mg L⁻¹, and the average current efficiency is about 46%. This suggests that the WC–Co/BDD electrode has a good mineralization capacity in phenol with a high concentration.

The tribological properties of ultra-high-molecular-weight polyethylene (UHMW-PE) play a significant role in artificial joint materials. Graphite fluoride (GrF), a novel solid lubricant, was incorporated into ultra-high-molecular-weight polyethylene (UHMW-PE) at different concentrations via ball milling and heat pressing to prepare the GrF-UHMW-PE composites. The structure, hardness, and tribological behavior of the composites were investigated using X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectrometry, ball indentation hardness, and a reciprocating ball-on-plane friction tester, respectively. The results of FT-IR showed that hydrogen bonds (C-F···H-C) could be formed between GrF and UHMW-PE. The hardness of the composites was significantly enhanced by increasing the GrF concentrations. GrF in the composites displayed superior lubricant properties and the coefficient of friction (COF) of the composites was significantly decreased at lower concentrations of GrF viz. 0.1 and 0.5 wt%. The addition of GrF also significantly enhanced the anti-wear properties of the composites, which was a combined effect of lubrication as well as hardness provided by GrF. At 0.5 wt% GrF concentration, the COF and the wear rate were reduced by 34.76% and 47.72%, respectively, when compared to UHMW-PE. As the concentration of GrF increased, the wear modes of the composites transitioned from fatigue wear to abrasive wear. Our current work suggested that GrF-UHMW-PE composites could be a suitable candidate for artificial joint materials.

The distribution of substrate temperature plays a decisive role on the uniformity of polycrystalline diamond films on cemented carbide tools with a long flute, prepared by a hot filament chemical vapor deposition (HFCVD). In this work, the heat dissipation mode at the bottom of tools is a focal point, and the finite volume method (FVM) is conducted to simulate and predict the temperature field of tools, with the various materials of the holder placed under the tools. The simulation results show that the thermal conductivity of the holder affects the temperature difference of the individual tools greatly, but only affects the temperature of different tools at the same XY plane slightly. Moreover, the ceramic holder can reduce the difference in temperature of an individual tool by 54%, compared to a copper one. Afterwards, the experiments of the deposition of diamond films is performed using the preferred ceramic holder. The diamond coatings on the different positions present a highly uniform distribution on their grain size, thickness, and quality.

The friction coefficient versus time curve of PE-UHMW and PE-UHMW/GO composite materials treated differently under water lubrication.

Microcrystalline diamond powders are deposited directly by a HFCVD apparatus with adding amounts of trimethyl borate in gas mixture. The study establishes the relationship between the boron...