In the current study, the mechanistic understanding of the adsorption isotherm and thermodynamic aspects of cationic methylene blue (MB) dye adsorption onto cellulosic olive stones biomass from wastewater were investigated. The batch adsorption of MB onto the olive stones (black and green olive stones) was tested at a variety of pH, dye concentrations, temperatures, and biomass particle sizes. The adsorption thermodynamics such as Gibbs free energy, enthalpy, and entropy changes were also calculated. Moreover, the desorption studies of MB from the spent olive stones were studied to explore the re-usability of the biomasses. The results revealed that under the optimum pH of 10, the maximum MB uptake was achieved i.e. 80.2% for the green olive stones and 70.9% for the black olive stones. The green olive stones were found to be more efficient in remediating higher MB concentrations from water than the black olive stones. The highest MB removal of the green olive stones was achieved at 600 ppm of MB, while the highest MB removal of the black olive stones was observed at 50 ppm of MB. Furthermore, for almost all the concentrations studied (50–1000 ppm), the MB adsorption was the highest at the temperature of 45 °C (P value < 0.05). It was shown by the Fourier transform infrared that the electrostatic interaction and hydrogen bonding were proposed as dominant adsorption mechanisms at basic and acidic pH, respectively. While the hydrophobic-hydrophobic interaction was a dominant mechanism at neutral pH. The thermodynamic studies revealed that the adsorption process was endothermic, spontaneous, and favorable. Moreover, the real wastewater experiment and the desorption studies showed that the green and black olive stones were a cost-effective and promising adsorbents for MB remediation from wastewater on account of their high adsorption and desorption removal capacities.

Purpose of Review: The concern of mercury pollution and the impact that it poses on the marine environment were studied heavily since the case of the poison from Minamata bay in the 1960s. The present study provides an insight into the cycle of mercury and methylmercury in the marine environment and the bioindicators that reflect the exposure levels. The paper also used the driving forces, pressures, states, impacts, and responses (DPSIR) analysis to evaluate the global mercury and methylmercury contamination problem. Recent Findings: The high global budgets of atmospheric total mercury influence the ocean surface water. Therefore, the aquatic environment contamination level is in turn affected by the surrounding emission sources such as industrial and petroleum activities in addition to the transport and fate of mercury across the environmental compartments. This will increase the mercury levels in fish species and will cause an adverse risk to human health through biomagnification. Summary: This review presents a thorough description of mercury sources and emissions and their fate and transport across the different environmental compartments, despite the fact that serious mitigation measures were taken and guidelines were applied. The risk from fish consumption is still a serious concern as a result of the current mercury emissions and stability and persistent characteristics.

Bacteria play a variety of roles in the environment. They maintain the balance in the ecosystem and provide different ecosystem services such as in biogeochemical cycling of nutrients, biodegradation of toxic pollutants, and others. Therefore, isolation and identification of different environmental bacteria are important to most environmental research. Due to the high cost and time associated with the conventional molecular techniques, matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS) has gained considerable attention for routine identification of bacteria. This review aims to provide an overview of the application of MALDI-TOF MS in various environmental studies through bibliometric analysis and literature review. The bibliometric analysis helped to understand the time-variable application of MALDI-TOF MS in various environmental studies. The categorical literature review covers various environmental studies comprising areas like ecology, food microbiology, environmental biotechnology, agriculture, and plant sciences, which show the application of the technique for identification and characterization of pollutant-degrading, plant-associated, disease-causing, soil-beneficial, and other environmental bacteria. Further research should focus on bridging the gap between the phylogenetic identity of bacteria and their specific environmental functions or metabolic traits that can help in rapid advancements in environmental research, thereby, improving time and cost savings.

The current work presented here focuses on the remediation of mercury from water using modified low-cost materials. Modified date pits, low cost, minimal pretreatment steps and locally abundant agricultural waste materials were effectively employed as an adsorbent for remediating Hg²⁺ from aqueous media. Physical and chemical modification were developed such as thermal roasting (RDP), sulfur (SMRDP) and silane (SIMRDP) based modifications. Results showed that maximum adsorption by RDP was at pH 6, AC and both modifications was at pH 4. Furthermore, RDP has exothermic adsorption mechanism while AC, SMRDP, and SIMRDP have endothermic. All adsorbents except SIMRDP have spontaneous adsorption process. SEM analysis showed that the surface morphology of RDP was not significantly affected by different treatments while surface of AC was affected. The investigation for good adsorbents for Hg²⁺ uptake from different anthropogenic sources has been carried out by many investigators worldwide towards having a safe environment. In the current study, the highest Hg²⁺ adsorption of SMRDP was relatively high compared to other known adsorbents.