This study aims to produce polypropylene (PP)/titanium dioxide (TiO₂) melt-blown membranes for oil/water separation and photocatalysis. PP and different contents of TiO₂ are melt-blended to prepare master batches using a single screw extruder. The master batches are then fabricated into PP/TiO₂ melt-blown membranes. The thermal properties of the master batches are analyzed using differential scanning calorimetry and thermogravimetric analysis, and their particle dispersion and melt-blown membrane morphology are evaluated by scanning electron microscopy. TiO₂ loaded on melt-blown membranes is confirmed by X-ray diffraction (XRD). The oil/water separation ability of the melt-blown membranes is evaluated to examine the influence of TiO₂ content. Results show that the thermal stability and photocatalytic effect of the membranes increase with TiO₂ content. TiO₂ shows a good dispersion in the PP membranes. After 3 wt.% TiO₂ addition, crystallinity increases by 6.4%, thermal decomposition temperature increases by 25 °C compared with pure PP membranes. The resultant PP/TiO₂ melt-blown membrane has a good morphology, and better hydrophobicity even in acetone solution or 6 h ultraviolet irradiation, and a high oil flux of about 15,000 L·m⁻²·h⁻¹. Moreover, the membranes have stabilized oil/water separation efficiency after being repeatedly used. The proposed melt-blown membranes are suitable for mass production for separating oil from water in massively industrial dyeing wastewater.

Particulate matter 2.5 (PM_2.5) has become a public hazard to people’s lives and health. Traditional melt-blown membranes cannot filter dangerous particles due to their limited diameter, and ultra-fine electrospinning fibers are vulnerable to external forces. Therefore, creating highly efficient air filters by using an innovative technique and structure has become necessary. In this study, a combination of polypropylene (PP) melt-blown and polyvinyl alcohol (PVA)/zeolite imidazole frameworks-8 (ZIF-8) electrospinning technique is employed to construct a PP/PVA/ZIF-8 membrane with a hierarchical fibrous structure. The synergistic effect of hierarchical fibrous structure and ZIF-8 effectively captures PM_2.5. The PP/PVA composite membrane loaded with 2.5% loading ZIF-8 has an average filtration efficacy reaching as high as 96.5% for PM_2.5 and quality factor (Q_f) of 0.099 Pa⁻¹. The resultant membrane resists 33.34 N tensile strength and has a low pressure drop, excellent filtration efficiency, and mechanical strength. This work presents a facile preparation method that is suitable for mass production and the application of membranes to be used as air filters for highly efficient filtration of PM_2.5.