Pydiflumetofen, a fungicide of the class of succinate dehydrogenase inhibitors, can disrupt energy metabolism by inhibiting the synthesis of succinate dehydrogenase, thus effectively inhibiting pathogenic fungal growth and related yield losses.We studied the adsorption and desorption behaviors and interaction mechanisms of pydiflumetofen in eight different arable soils by the infrared spectroscopy and batch equilibrium method. Pydiflumetofen adsorption and desorption property of soils conformed with the Freundlich isotherm model and the values for the adsorption capacity K_F-ads were in the range of 14.592-102.610. The adsorption constants (K_F-ads) exhibited a significantly positive and linear correlation (p < 0.1) with soil organic matter and organic carbon content. Both high and low temperatures weakened the pydiflumetofen sorption capacity of the soil. In addition, the initial pH of the solution, its ionic strength, and the addition of exogenous biochar, humic acid, and different types of surfactants at different concentrations also affected the sorption property of the soil. Pydiflumetofen is weakly mobile and leachable in most soils, and, poses some threat to surface soil and water organisms, but does not contaminate groundwater.

Clausena lansium Lour. Skeels (Rutaceae) is widely distributed in South China and has historically been used as a traditional medicine in local healthcare systems. Although the characteristic components (carbazole alkaloids and coumarins) of C. lansium have been found to possess a wide variety of biological activities, little attention has been paid toward the other components of this plant. In the current study, phytochemical analysis of isolates from a water-soluble stem and leaf extract of C. lansium led to the identification of 12 compounds, including five aromatic glycosides, four sesquiterpene glycosides, two dihydrofuranocoumarin glycosides, and one adenosine. All compounds were isolated for the first time from the genus Clausena, including a new aromatic glycoside (1), a new dihydrofuranocoumarin glycoside (6), and two new sesquiterpene glycosides (8 and 9). The phytochemical structures of the isolates were elucidated using spectroscopic analyses including NMR and MS. The existence of these compounds demonstrates the taxonomic significance of C. lansium in the genus Clausena and suggests that some glycosides from this plant probably play a role in the anticancer activity of C. lansium to some extent.