Magnetic microparticles have many applications in various areas today. The aim of this study was to develop hydrophobic magnetic microparticles as an alternative to traditional methods for high capacity and low cost removal of Victoria Blue R (VBR), which is valuable for industry and commercial, from wastewater and to determine the VBR adsorption ability of this adsorbent. Fe(II)–Co(II) double salt incorporated magnetic poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-tryptophan) [m-poly(HEMA-MATrp)] microparticles were synthesized and used as adsorbent. These microparticles were synthesized in aqueous dispersion medium via microemulsion polymerization using MATrp and HEMA monomers. Magnetic hydrophobic microparticles were characterized via Fourier transform infrared spectroscopy, scanning electron microscopy, and vibrating sample magnetometer. Adsorption experiments were conducted for different conditions (pH, interaction time, amount of microparticles, temperature, and ionic strength) in batch system. VBR adsorption capacity of magnetic hydrophobic microparticles was estimated as 89.46 μmol/g. Adsorption–desorption cycles were repeated 4 times, and there was no significant decrease for the adsorption capacity observed.

Non-metal cation (NMC) pentaborate structures, in which some amino acids (valine, leucine, isoleucine, and threonine) were used as cations, were synthesized. The structural characterization of molecules was carried out by elemental analysis, FT-IR, mass, ¹¹B-NMR, and thermal analysis (TGA/DTA) methods. The hydrogen storage capacity of molecules was also calculated by taking experimental results into consideration. The FT-IR spectra support the similarity of structures. The characteristic peaks attributable to pentaborate rings and amino acids were observed. When thermal analysis data were examined, it was observed that pentaborate salts gave similar degradation steps and degradation products. As a final degradation product of all thermal analysis experiments, a glassy form of B₂O₃ was observed. The valine pentaborate is the most thermally stable. Also, the amounts of hydrate water outside the coordination sphere of the compounds were determined by thermal analysis curves. The peaks of boric acid, triborate, and pentaborate structures were obtained in ppm with the ¹¹B-NMR results of synthesized pentaborate compounds. With powder X-ray spectroscopy, all structures were found to be crystalline but not suitable for single-crystal X-ray analysis. The molecular cavities of the compounds detected by BET were found to be 3.286, 1.873, 2.309, and 1.860 g/cm³, respectively. A low number of molecular cavities can be interpreted in several existing hydrogen bonds in structures. The hydrogen storage capacities of the molecules were found to be in the range of 0.04 to 0.07% by mass.