Chitosan microspheres modified by 2-pyridinecarboxaldehyde were prepared and used in the construction of a heterogeneous catalyst loaded with nano-Cu prepared by a reduction reaction. The chemical structure of the catalyst was investigated by Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and X-ray Photoelectron Spectroscopy (XPS). Under mild conditions, such as no ligand at room temperature, the catalyst was successfully applied to catalyze the borylation of α,β-unsaturated receptors in a water-methanol medium, yielding 17%–100% of the corresponding β-hydroxy product. Even after repeated use five times, the catalyst still exhibited excellent catalytic activity.
23 November 2023 in International Journal of Biological Macromolecules
The CN/CH-2/TC, with a 2.44 eV band gap, exhibits excellent photocatalytic performance by enhancing light absorption, promoting charge separation, and defects, achieving H 2 evolution of 17 300 μmol g −1 h −1 and CO production of 205.3 μmol g −1 h −1 .
The natural polymer chitosan was modified with polyvinyl alcohol to enhance the mechanical properties of the membrane, and then, the montmorillonite-modified chitosan-loaded palladium catalyst was prepared using the excellent coordination properties of montmorillonite. The results showed that the catalyst has good tensile strength, thermal stability, catalytic activity, and recycling performance and is a green catalytic material with industrial application potential.