The gas shale in the Lower Silurian Longmaxi Formation contains a considerable amount of biogenic silica. Various originated silicas in shale, derived from different depositional environment, are commonly associated with different degrees of organic matter enrichment, resulting in different mechanical and physical properties of shale reservoirs. Thin section identification, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), total organic carbon (TOC) analysis, X-ray diffraction (XRD) analysis, and X-ray fluorescence (XRF) spectroscopy were used to investigate the Lower Silurian Longmaxi shale from Well Yuye 1 in southeastern Chongqing, China to obtain a better understanding of the origin of silica in the Longmaxi Shale. The results show ubiquitous cryptocrystalline silicas with poorly crystalline morphology, which differs from that of the detrital silica, authigenic silica, and hydrothermal silica, proving that the cryptocrystalline silicas may have a biogenic origin. Major element and mineral composition analysis indicate no correlations between K₂O/Al₂O₃ and SiO₂/Al₂O₃ and between illite and SiO₂, and negative correlations between TiO₂ and SiO₂/Al₂O₃, between illite and quartz and excess Si, and between Al₂O₃ and excess Si, and all samples being located in the area of non-hydrothermal origin in the Al-Fe-Mn diagram, excluding silicas of terrigenous detrital origin, clay mineral transformed origin, and hydrothermal origin. Moreover, the fact that almost all samples plot above the illite Si/Al line in the cross-plot of Si versus Al and the mean values of Al/(Al + Fe + Mn) and Si/(Si + Al + Fe + Ca) are close to the values of biogenic silica prove that the silicas are primarily of biogenic origin. Positive correlations between TOC and quartz and excess Si and numerous siliceous organisms are observed, indicating that the silicas are associated with siliceous organisms. The postmortem siliceous organisms underwent silica diagenesis via a dissolution-precipitation mechanism following the sequence of opal-A → opal-CT → cryptocrystalline biogenic silica as the burial depth and temperature increased.

During hydraulic fracturing, there is a temperature difference between the injected water and formation rock for shale gas wells. The objective of this study is to investigate how this temperature difference changes with time, and how it affects multiphase-flow modeling during the shut-in and flowback periods. We conducted numerical simulations to investigate the behaviors of fracture temperature in shale gas wells. The results show a significant increase in fracture temperature during the shut-in and flowback periods. Sensitivity analysis suggests that this temperature increase is strongly related to the thermal conductivity of formation rock, matrix permeability, and initial reservoir temperature. Simulation scenarios were further compared to investigate the effect of temperature on flowback data analysis. Without considering the thermal effect, flowback data analysis may yield an earlier fracture cleanup and overestimated fracture volume. In addition, this study suggests that the thermal effect may also have implications for optimizing flowback operations.