Metallic nanostructures (MNs) and metal-organic frameworks (MOFs) play a pivotal role by articulating their significance in high-performance supercapacitors along with conducting polymers (CPs). The interaction and synergistic pseudocapacitive effect of MNs with CPs have contributed to enhance the specific capacitance and cyclic stability. Among various conjugated heterocyclic CPs, polypyrrole (PPy) (prevalently knows as “synthetic metal”) is exclusively studied because of its excellent physicochemical properties, ease of preparation, flexibility in surface modifications, and unique molecular structure–property relationships. Numerous researchers attempted to improve the low electronic conductivity of MNs and MOFs, by incorporating conducting PPy and/or used decoration strategy. This was succeeded by fine-tuning this objective, which managed to get outstanding supercapacitive performances. This brief technical note epitomizes various PPy-based metallic hybrid materials with different nano-architectures, emphasizing its technical implications in fabricating high-performance electrode material for supercapacitor applications.

Till to date, the application of sulfur-doped graphitic carbon nitride supported transition metal carbide interface for electrochemical sensor fabrication was less explored. In this work, we designed a simple synthesis of molybdenum carbide sphere embedded sulfur doped graphitic carbon nitride (Mo₂C/SCN) catalyst for the nanomolar electrochemical sensor application. The synthesized Mo₂C/SCN nanocatalyst was systematically characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) with elemental mapping. The SEM images show that the porous SCN network adhered uniformly on Mo₂C, causing a loss of crystallinity in the diffractogram. The corresponding elemental mapping of Mo₂C/SCN shows distinct peaks for carbon (41.47%), nitrogen (32.54%), sulfur (1.37%), and molybdenum (24.62%) with no additional impurity peaks, reflecting the successful synthesis. Later, the glassy carbon electrode (GCE) was modified by Mo₂C/SCN nanocatalyst for simultaneous sensing of uric acid (UA) and folic acid (FA). The fabricated Mo₂C/SCN/GCE is capable of simultaneous and interference free electrochemical detection of UA and FA in a binary mixture. The limit of detection (LOD) calculated at Mo₂C/SCN/GCE for UA and FA was 21.5 nM (0.09 - 47.0 μM) and 14.7 nM (0.09 - 167.25 μM) respectively by differential pulse voltammetric (DPV) technique. The presence of interferons has no significant effect on the sensor's performance, making it suitable for real sample analysis. The present method can be extended to fabricate an electrochemical sensor for various molecules.

In this paper, we propose a tiny haptic knob that creates torque feedback in consumer electronic devices. To develop the proposed haptic knob, we use a magnetorheological (MR) fluid. When an input current is applied to a solenoid coil, a magnetic field causes a change in the MR fluid’s viscosity. This change allows the proposed haptic knob to generate a resistive torque. We optimize the structure of the haptic knob, in which two operating modes of MR fluids contribute to the actuation simultaneously. We conduct magnetic path simulation and resistive torque simulation using the finite element method and perform experiments to measure the resistive torque and its torque rate according to the rotational speed and applied current. The results show that the proposed haptic knob generates sufficient torque feedback to stimulate users and creates a variety of haptic sensations.

Bio-inspiration relentlessly sparks the novel ideas to develop innovative soft robotic structures from smart materials. The conceptual soft robotic designs inspired by biomimetic routes have resulted in pioneering research contributions based on the understanding of the material selection and actuation properties. In an attempt to overcome the hazardous injuries, soft robotic systems are used subsequently to ensure safe human–robot interaction. In contrast to dielectric elastomer actuators, prolific efforts were made by understanding the photo-actuating properties of liquid crystalline elastomers (LCEs) containing azo-derivatives to construct mechanical structures and tiny portable robots for specific technological applications. The structure and material properties of these stimuli-responsive polymers can skillfully be controlled by light. In this short technical note, we highlight the potential high-tech importance and the photo-actuation behavior of some remarkable LCEs with azobenzene chromophores.

This study presents a transparent and soft haptic actuator based on an electroactive polymer designed to create abundant haptic sensations in flexible/deformable next-generation devices and to convey them to users. The haptic sensations are created in the form of vibrations and vary depending on the amplitude and frequency of the vibrations. The haptic actuator consists of a transparent and soft dielectric layer and two transparent and soft ionic conductive layers. The dielectric layer is sandwiched between the two ionic conductive layers, and is compressed in the thickness direction when an electric field is applied to the two ionic conductive layers. When the applied electric field is removed, the proposed haptic actuators are rapidly restored to their initial configuration. Owing to this effect, the actuator can easily create vibrations that are sufficiently strong for human perception. In this study, three different dielectric elastomers (silicone rubber, poly urethane, and acrylic polymer) are used for the dielectric layer. Experiments are conducted to investigate the haptic performance of the proposed soft vibrotactile actuators using an accelerometer. In the case of the silicone rubber-based actuator, the measured acceleration at the resonant frequency (80 Hz) is 1.408 g (g = 9.8 m/s2) and the response time is approximately 2.8 ms. Furthermore, the perceived intensity of the stimuli generated by the proposed actuator is verified by perceptual experiments. The results indicate that the proposed actuator can selectively stimulate human mechanoreceptors with sufficient perceptual strength.