Herein, we report the chemiresistive gas and humidity sensing properties of pristine and nickel-doped tin oxide (Ni-SnO₂) gas sensors prepared by a microwave-assisted wet chemical method.

We demonstrate a concept and fabrication of lithography-free layered metal-SiO₂ thin-film structures which have reduced reflectivity (black appearance), to as low as 0.9%, with 4.9% broadband reflectance (8.9% for soda lime) in the 500–1400 nm range. The multi-layered (four layers) thin-film metamaterial is designed so that optical impedance matching produces minimal reflectance and transmittance within the visible and infra-red (IR) spectral region for a range of incident angles. The structure has enhanced absorbance and is easily tuned for reduced minimal transmission and reflection. This approach should allow for novel anti-reflection surfaces by impedance matching to be realized.

We report on the design, fabrication, and characterization of thin ${\mathrm{Si}}_3{\mathrm{N}}_4$ ultra-high-quality (UHQ) factor ring resonators monolithically integrated on a silicon chip. The devices are based on a strip-loaded configuration and operate at both near-infrared (NIR) and third-telecom wavelengths. This approach allows us to use a guiding ${\mathrm{Si}}_3{\mathrm{N}}_4$ core that is one order of magnitude thinner than what has been reported in the past for obtaining similar device performances. Our strip-loaded devices benefit from the absence of physically etched lateral boundaries to show minute light scattering and, therefore, reducing significantly scattering-related losses. Consequently, UHQs of $3.7\times {10}^6$ in the NIR and high-quality factors of up to $9\times {10}^5$ in the C-band were measured for the guiding material thickness of 80 nm and 115 nm, respectively. These first results are subject to further improvements that may allow employing strip-loaded resonators in nonlinear frequency conversion or quantum computing schemes within the desired spectral range provided by the material transparency.

Capabilities of the attenuated total reflection (ATR) at THz wavelengths for increased sub-surface depth characterisation of (bio-)materials are presented. The penetration depth of a THz evanescent wave in biological samples is dependent on the wavelength and temperature and can reach 0.1–0.5 mm depth, due to the strong refractive index change ∼0.4 of the ice-water transition; this is quite significant and important when studying biological samples. Technical challenges are discussed when using ATR for uneven, heterogeneous, high refractive index samples with the possibility of frustrated total internal reflection (a breakdown of the ATR reflection mode into transmission mode). Local field enhancements at the interface are discussed with numerical/analytical examples. Maxwell’s scaling is used to model the behaviour of absorber–scatterer inside the materials at the interface with the ATR prism for realistic complex refractive indices of bio-materials. The modality of ATR with a polarisation analysis is proposed, and its principle is illustrated, opening an invitation for its experimental validation. The sensitivity of the polarised ATR mode to the refractive index between the sample and ATR prism is numerically modelled and experimentally verified for background (air) spectra. The design principles of polarisation active optical elements and spectral filters are outlined. The results and proposed concepts are based on experimental conditions at the THz beamline of the Australian Synchrotron.

The thermal properties of novel nanomaterials play a significant role in determining the performance of the material in technological applications. Herein, direct measurement of the temperature diffusivity of nanocellulose-doped starch–polyurethane nanocomposite films was carried out by the micro-contact method. Polymer films containing up to 2 wt%. of nanocellulose were synthesised by a simple chemical process and are biodegradable. Films of a high optical transmittance $T\approx 80\%$ (for a 200 $\mathsf{\mu }$m thick film), which were up to 44% crystalline, were characterised. Two different modalities of temperature diffusivity based on (1) a resistance change and (2) micro-thermocouple detected voltage modulation caused by the heat wave, were used for the polymer films with cross sections of ∼100 $\mathsf{\mu }$m thickness. Twice different in-plane ${\alpha }_{\Vert }$ and out-of-plane ${\alpha }_{\perp }$ temperature diffusivities were directly determined with high fidelity: ${\alpha }_{\Vert }=2.12\times {10}^{-7}$ m${}^2$/s and ${\alpha }_{\perp }=1.13\times {10}^{-7}$ m${}^2$/s. This work provides an example of a direct contact measurement of thermal properties of nanocellulose composite biodegradable polymer films. The thermal diffusivity, which is usually high in strongly interconnected networks and crystals, was investigated for the first time in this polymer nanocomposite.