A high-performance zinc oxide/tin dioxide (ZnO/SnO2) humidity sensor was developed using a simple solvothermal method. The sensing mechanism of the ZnO/SnO2 humidity sensor was evaluated by analyzing its complex impedance spectra. The experimental results prove that the ZnO/SnO2 composite material has a larger specific surface area than pure SnO2, which allows the composite material surface to adsorb more water to enhance the response of the ZnO/SnO2 humidity sensor. ZnO can also contribute to the generation of oxygen-rich vacancies on the ZnO/SnO2 composite material surface, allowing it to adsorb a large amount of water and rapidly decompose water molecules into conductive ions to increase the response and recovery speed of the ZnO/SnO2 humidity sensor. These characteristics allowed the Z/S-2 humidity sensor to achieve a higher response (1,225,361%), better linearity, smaller hysteresis (6.6%), faster response and recovery speeds (35 and 8 s, respectively), and long-term stability at 11–95% relative humidity. The successful preparation of the ZnO/SnO2 composite material also provides a new direction for the design of SnO2-based resistance sensors with high humidity-sensing performance.
A novel assembled biosensor was prepared for detecting 16S rRNA, a small-size persistent specific for Actinobacteria. The mechanism of the porous silicon (PS) photonic crystal biosensor is based on the fluorescence resonance energy transfer (FRET) between quantum dots (QDs) and gold nanoparticles (AuNPs) through DNA hybridization, where QDs act as an emission donor and AuNPs serve as a fluorescence quencher. Results showed that the photoluminescence (PL) intensity of PS photonic crystal was drastically increased when the QDs-conjugated probe DNA was adhered to the PS layer by surface modification using a standard cross-link chemistry method. The PL intensity of QDs was decreased when the addition of AuNPs-conjugated complementary 16S rRNA was dropped onto QDs-conjugated PS. Based on the analysis of different target DNA concentration, it was found that the decrease of the PL intensity showed a good linear relationship with complementary DNA concentration in a range from 0.25 to 10 μM, and the detection limit was 328.7 nM. Such an optical FRET biosensor functions on PS-based photonic crystal for DNA detection that differs from the traditional FRET, which is used only in liquid. This method will benefit the development of a new optical FRET label-free biosensor on Si substrate and has great potential in biochips based on integrated optical devices.
In this paper, we prepared a high-performance zinc oxide (ZnO) humidity sensor in an alkaline environment using one-step hydrothermal method. Experiments showed that the pH value of the precursor solution affects the performance of ZnO humidity sensors. There are abundant hydroxyl group and oxygen vacancies on the surface of ZnO with a precursor pH value of 10. Abundant hydroxyl groups on the surface of ZnO can adsorb a large number of water molecules and rich oxygen vacancies can accelerate the decomposition of water molecules, thus increasing the number of conductive ions (H3O+) and further improving the performance of the sensor. So, such a ZnO humidity sensor exhibited high sensitivity (14,415), good linearity, small hysteresis (0.9%), fast response/recovery time (31/15 s) in the range from 11% to 95% relative humidity (RH). Moreover, the ZnO-2 humidity sensor has good repeatability and can be effectively used for a long time. This study provides a new idea for the development of low-cost, high-performance and reusable ZnO resistive humidity sensors.