The palm biodiesel industry is facing many challenges implementing biodiesel program in Malaysia. This paper addresses the importance of the B10 blend (10% biodiesel, 90% petroleum diesel), global challenges of palm oil import and export, and protective measures for continuous positive growth of the palm oil sector. Palm oil is the backbone of Malaysia’s economy, covering more than 5% of its gross domestic product (GDP). The key steps taken by the Malaysian government for the successful implementation of the B10 program are discussed in this review study. Till now, B5 and B7 biodiesel programs have been successfully implemented in Malaysia. The B10 biodiesel program is attractive because of the developed local palm oil sector. The B10 biodiesel program will increase the use of renewable energy sources, and is expected to increase the productivity of palm oil and biodiesel implementation in the country. Despite successful B5 and B7 programs, Malaysia is facing challenges for the implementation of biodiesel due to fluctuation in crude palm oil prices, low domestic usage of palm oil, and vehicle warranty. The improvement of palm oil and promotion of B10 through targeted agencies in the central region of Malaysia will help to implement the biodiesel program successfully.

CO₂ separation from CH₄ by using mixed matrix membranes has received great attention due to its higher separation performance compared to neat polymeric membrane. However, Robeson’s trade-off between permeability and selectivity still remains a major challenge for mixed matrix membrane in CO₂/CH₄ separation. In this work, we report the preparation, characterization and CO₂/CH₄ gas separation properties of mixed matrix membranes containing 6FDA-durene polyimide and ZIF-8 particles functionalized with different types of amine groups. The purpose of introducing amino-functional groups into the filler is to improve the interaction between the filler and polymer, thus enhancing the CO₂ /CH₄ separation properties. ZIF-8 were functionalized with three differents amino-functional group including 3-(Trimethoxysilyl)propylamine (APTMS), N-[3-(Dimethoxymethylsilyl)propyl ethylenediamine (AAPTMS) and N¹-(3-Trimethoxysilylpropyl) diethylenetriamine (AEPTMS). The structural and morphology properties of the resultant membranes were characterized by using different analytical tools. Subsequently, the permeability of CO₂ and CH₄ gases over the resultant membranes were measured. The results showed that the membrane containing 0.5 wt% AAPTMS-functionalized ZIF-8 in 6FDA- durene polymer matrix displayed highest CO₂ permeability of 825 Barrer and CO₂/CH₄ ideal selectivity of 26.2, which successfully lies on Robeson upper bound limit.

Polysulfone-based mixed matrix membranes (MMMs) incorporated with silica nanoparticles are a new generation material under ongoing research and development for gas separation. However, the attributes of a better-performing MMM cannot be precisely studied under experimental conditions. Thus, it requires an atomistic scale study to elucidate the separation performance of silica/polysulfone MMMs. As most of the research work and empirical models for gas transport properties have been limited to pure gas, a computational framework for molecular simulation is required to study the mixed gas transport properties in silica/polysulfone MMMs to reflect real membrane separation. In this work, Monte Carlo (MC) and molecular dynamics (MD) simulations were employed to study the solubility and diffusivity of CO₂/CH₄ with varying gas concentrations (i.e., 30% CO₂/CH₄, 50% CO₂/CH₄, and 70% CO₂/CH₄) and silica content (i.e., 15–30 wt.%). The accuracy of the simulated structures was validated with published literature, followed by the study of the gas transport properties at 308.15 K and 1 atm. Simulation results concluded an increase in the free volume with an increasing weight percentage of silica. It was also found that pure gas consistently exhibited higher gas transport properties when compared to mixed gas conditions. The results also showed a competitive gas transport performance for mixed gases, which is more apparent when CO₂ increases. In this context, an increment in the permeation was observed for mixed gas with increasing gas concentrations (i.e., 70% CO₂/CH₄ > 50% CO₂/CH₄ > 30% CO₂/CH₄). The diffusivity, solubility, and permeability of the mixed gases were consistently increasing until 25 wt.%, followed by a decrease for 30 wt.% of silica. An empirical model based on a parallel resistance approach was developed by incorporating mathematical formulations for solubility and permeability. The model results were compared with simulation results to quantify the effect of mixed gas transport, which showed an 18% and 15% percentage error for the permeability and solubility, respectively, in comparison to the simulation data. This study provides a basis for future understanding of MMMs using molecular simulations and modeling techniques for mixed gas conditions that demonstrate real membrane separation.

Wastewater from the oil and gas industry is notoriously challenging to treat due to its complex composition. In this work, polyvinylpyrrolidone (PVP) was used to modify graphene oxide (GO) nanoparticles for the synthesis of PSf based thin-film nanocomposite (TFN) membranes through the interfacial polymerization (IP) technique, aimed at oil removal from wastewater. The composite membrane, incorporated with GO, at different PVP loadings (0.025 wt%, 0.030 wt%, and 0.035 wt%) were fabricated and characterized using FESEM, AFM, ATR-FTIR, UV–Vis spectra, tensile strength and contact angle goniometer. It is found that with the presence of PVP-GO inside the TFN membranes, it exhibited higher surface hydrophilicity due to an increment in hydroxyl and carboxyl groups in the polyamide (PA) layer, which improves the attraction between water molecules and membrane surface. TFN membrane assimilated with 0.035 wt% PVP-GO achieved 48.871 L/m².h and flux recovery ratio of 88% of water flux with decreased contact angle up to 46° and thin film thickness of 137 nm as compared to the TFN membranes without the addition of PVP with 34.118 L/m².h of water flux. Overall, the PVP-modified GO nanocomposite membranes in this work demonstrated promising performance for oil-in-water emulsion separation, which makes them an attractive candidate for industrial water separation especially for produced water treatment.

Generation of biogas from organic substances is an attractive evolution of energy generation from fossil-based energy supply to renewable resources. In order to exhibit viability in terms of technical execution while being economically feasible, successful purification strategies for biomethane formation must be applicable to industrial gas streams at realistic pressures and temperatures. Membrane-based upgrading technologies have great potential to promote biogas processes because they involve less energy and low maintenance. However, the development of membranes with good polymer-filler contact and minimum defects remains a great challenge. Hitherto, researchers have been making many attempts at developing an established route to fabricate thin-film composite membranes. In the present work, an innovative coupling between Linde T and fluorinated polyimide was employed for biogas upgrading. A facile technique for membrane fabrication was proposed via optimization of the fabrication parameters. The results indicated that composite membrane fabricated with 2 hours of total dispersion duration demonstrated a homogeneous distribution of Linde T particles in the fluorinated polyimide matrix and improved the separation characteristics by up to 172% in upgrading biomethane quality. Thus, the fabricated membrane is feasible to be employed for large-scale and lucrative production with enhanced performance in biogas purification via the feasible fabrication method employed in this work.