Microplastic particles (MPs) pose a novel threat to nature. Despite being first noticed in the 1970s, research on this topic has only surged in recent years. Researchers have mainly focused on environmental plastic particles; however, studies with defined microplastic particles as the sample input are scarce. Furthermore, comparison of those studies indicates a discrepancy between the particles found (e.g., in the environment) and those used for further research (e.g., exposure studies). Obviously, it is important to use particles that resemble those found in the environment to conduct appropriate research. In this review, different categories of microplastic particles are addressed, before covering an overview of the most common separation and analysis methods for environmental MPs is covered. After showing that the particles found in the environment are mostly irregular and polydisperse, while those used in studies with plastic microparticles as samples are often not, different particle production techniques are investigated and suggestions for preparing realistic plastic particles are given.
As poultry is known to be a perishable food, the use-by date is set in such a way that food safety is guaranteed even with a higher initial bacterial count. This means, however, that some products are wasted, even if they are still safe to eat. Therefore, non-destructive measurement devices might be a good opportunity for individual shelf-life prediction, e.g., in retail. The aim of this study was therefore to use non-destructive measurement devices based on fluorescence quenching (oxygen detection) and mid-infrared laser spectroscopy (carbon dioxide detection) for the monitoring of high-oxygen-packed poultry in different storage conditions. During 15 days of storage, the gas composition of the headspace was assessed (non-destructively and destructively), while total plate count was monitored and a comprehensive sensory evaluation was performed by a trained panel. We were able to demonstrate that in most cases, non-destructive devices have comparable precision to destructive devices. For both storage conditions, the sensory attribute slime was correlated with reaching the critical microbiological value of 107 CFU/g; the attribute buttery was also useful for the prediction of regularly stored poultry. The change in the gas atmosphere as a sign of premature spoilage, however, was only possible for samples stored in irregular conditions.
1 February 2017 in Review of Scientific Instruments
Flexible organic electronic devices are often protected from degradation by encapsulation in multilayered films with very high barrier properties against moisture and oxygen. However, metrology must be improved to detect such low quantities of permeants. We therefore developed a modified ultra-low permeation measurement device based on a constant-flow carrier-gas system to measure both the transient and stationary water vapor permeation through high-performance barrier films. The accumulation of permeated water vapor before its transport to the detector allows the measurement of very low water vapor transmission rates (WVTRs) down to 2 × 10−5 g m−2 d−1. The measurement cells are stored in a temperature-controlled chamber, allowing WVTR measurements within the temperature range 23–80 °C. Differences in relative humidity can be controlled within the range 15%–90%. The WVTR values determined using the novel measurement device agree with those measured using a commercially available carrier-gas device from MOCON®. Depending on the structure and quality of the barrier film, it may take a long time for the WVTR to reach a steady-state value. However, by using a combination of the time-dependent measurement and the finite element method, we were able to estimate the steady-state WVTR accurately with significantly shorter measurement times.
8 March 2018 in Journal of Applied Polymer Science