Improper land application of excess poultry waste (PW) causes environmental issues and other problems. Meanwhile there is an increasing trend of using PW as an alternative energy resource. The Higher Heating Value (HHV) is critical for designing and analyzing the PW conversion process. Several proximate-based mathematical models have been proposed to estimate the HHV of biomass, coal, and other solid fuels. Nevertheless, only a small number of studies have focused on a subclass of fuels, especially for PW. The aim of this study is to develop proximate-based regression models for an HHV prediction of PW. Sample data of PW were collected from open literature to develop regression models. The resulting models were then validated by additional PW samples and other published models. Results indicate that the most accurate model contains linear (all proximate components), polynomial terms (quadratic and cubic of volatile matter), and interaction effect (fixed carbon and ash). Moreover, results show that best-fit regression model has a higher R² (91.62%) and lower estimation errors than the existing proximate-based models. Therefore, this new regression model can be an excellent tool for predicting the HHV of PW and does not require any expensive equipment that measures HHV or elemental compositions.

The prediction and pre-evaluation of the thermal properties and combustion-related problems (e.g., emissions and ash-related problems) are critical to reducing emissions and improving combustion efficiency during the agricultural crop residues combustion process. This study integrated the higher heating value (HHV) model, specific heat model, and fuel indices as a new systematic approach to characterize the agricultural crop residues. Sixteen linear and non-linear regression models were developed from three main compositions of the ultimate analysis (e.g., C, H, and O) to predict the HHV of the agricultural crop residues. Newly developed HHV models have been validated with lower estimation errors and a higher degree of accuracy than the existing models. The specific heat of flue gas during the combustion process was estimated from the concentrations of C, H, O, S, and ash content under various excess air (EA) ratios and flue gas temperatures. The specific heat of agricultural crop residues was between 1.033 to 1.327 kJ/kg·K, while it was increased by decreasing the EA ratios and elevating the temperature of the flue gas. Combustion-related problems, namely corrosions, PM_1.0 emissions, SO_x, HCl, and ash-related problems were predicted using the fuel indices along with S and Cl concentrations, and ash compositions. Results showed that agricultural crop residues pose a severe corrosion risk and lower ash sintering temperature. This integrated approach can be applied to a wide range of biomass before the actual combustion process which may predict thermal-chemical properties and reduce the potential combustion-related emissions.

Electricity generation and emission characteristics during the poultry litter and natural gas co-combustion process has rarely been studied. In this study, a Stirling engine was successfully integrated into the existing lab-scale swirling fluidized bed combustion system in order to further investigate the poultry litter and natural gas co-combustion process. Electricity, gaseous emissions, particulate matter (PM), and fly ash composition were analyzed under various operating conditions. Results indicated that the electricity reached 905 W under a water flow rate of 13.1 L/min and an engine head temperature of 584 °C. It was found that excess air (EA) ratios between 0.79 and 1.08 can relatively produce more electricity with lower emissions. At a secondary air (SA) height of 850 mm, secondary air/total air (SA/TA) ratios between 0.22 and 0.44 may significantly reduce NO_x and CO emissions. By increasing the mixing ratio (MR), SO₂ was reduced while NO_x increased at the beginning of co-combustion process but then decreased again. Additionally, PM results were lower than Maryland emissions standards. The fly ash results showed a higher nutrient content (close to 16%). This study shows the possibility of using poultry litter as a sustainable energy source for energy production while emitting lower emissions in the small decentralized combustion system.

In the past few decades, water and air were commonly used as working fluid to evaluate shell and tube heat exchanger (STHE) performance. This study was undertaken to estimate heat transfer coefficients and evaluate performance in the pilot-scale twisted tube-based STHE using the flue gas from biomass co-combustion as working fluid. Theoretical calculation along with experimental results were used to calculate the specific heat of flue gas. A simplified model was then developed from the integration of two heat transfer methods to predict the overall heat transfer coefficient without tedious calculation of individual heat transfer coefficients and fouling factors. Performance including water and trailer temperature, heat load, effectiveness, and overall heat transfer coefficient were jointly investigated under variable operating conditions. Results indicated that the specific heat of flue gas from co-combustion ranging between 1.044 and 1.338 kJ/kg$·$K while specific heat was increased by increasing flue gas temperature and decreasing excess air ratio. The developed mathematical model was validated to have relatively small errors to predict the overall heat transfer coefficient. A flue gas mass flow rate of 61.3–98.8 kg/h, a water flow rate of 13.7–14.1 L/min, and a parallel arrangement of two water-to-air heaters in an empty trailer were found to be optimal conditions for space heating purpose. In addition, a lower poultry litter feeding rate decreased heat loss of flue gas and increased heat gain of water, while a lower water flow rate also provided a lower maximum possible heat transfer rate with a higher actual heat transfer rate to quickly achieve heat equilibrium that ultimately improves the performance. This study demonstrates the possibility of collecting residual heat from the flue gas using the pilot-scale STHE system while outlining a systematic approach and process for evaluating its performance.

Poultry litter is one type of biomass and waste generated from the farming process. This study performed a performance and process analysis of poultry litter to energy using the lab-scale shell and tube heat exchanger (STHE) system along with a Stirling engine and a swirling fluidized bed combustor (SFBC). The effects of tube shape, flow direction, and water flow rates on water and trailer temperature changes were investigated during the poultry litter co-combustion process. Energy flow analysis and emissions were also studied. Results showed that the water outlet temperature of 62.8 $°\mathrm{C}$ in the twisted tube was higher than the straight tube case (58.3 $°\mathrm{C}$ ) after 130 min of the co-combustion process. It was found that the counter-current direction had higher water temperature changes, higher logarithmic mean temperature difference (LMTD), and higher trailer temperature changes than the co-current direction. A water flow rate of 4.54 L/min showed adequate heat absorption in the lab-scale STHE system and heat rejection in the trailer. Results indicated that the lab-scale STHE system has a conversion efficiency of 42.3% and produces hot water (at about 63.9 $°\mathrm{C}$ ) along with lower emissions. This research study confirmed that poultry litter can be used to generate energy (e.g., hot water and electricity) by using a lab-scale biomass conversion system for space heating applications.

Excessive land application of poultry litter (PL) may lead to surface runoff of nitrogen (N) and phosphorus (P), which cause eutrophication, fish death, and water pollution that ultimately have negative effects on humans and animals. Increases in poultry production in the Delmarva Peninsula underscore the need for more efficient, cost-effective, and sustainable disposal technologies for processing PL instead of direct land application. The pyrolysis conversion process can potentially produce nutrient-rich poultry litter biochar (PLB), while the pyrolysis process can change the N and P to a more stable component, thus reducing its runoff. Pyrolysis also kills off any microorganisms that would otherwise trigger negative environmental health effects. This study is to apply an integrated method and investigate the effect of pyrolysis temperature (300 °C, 500 °C), poultry litter source (different feedstock composition), and bedding material mixture (10% pine shavings) on PLB qualities and quantities. Proximate and ultimate analysis showed PL sources and bedding material addition influenced the physicochemical properties of feedstock. The SEM and BET surface results indicate that pyrolysis temperature had a significant effect on changing the PLB morphology and structure, as well as the pH value (7.78 at 300 °C vs. 8.78 at 500 °C), extractable phosphorus (P) (18.73 ppm at 300 °C vs. 11.72 ppm at 500 °C), sulfur (S) (363 ppm at 300 °C vs. 344 ppm at 500 °C), and production yield of PLBs (47.65% at 300 °C vs. 60.62% at 500 °C). The results further suggest that adding a bedding material mixture (10% pine shavings) to PLs improved qualities by reducing the content of extractable P and S, as well as pH values of PLBs. This study also found the increment in both the pore volume and the area of Bethel Farm was higher than that of Sun Farm. Characterization and investigation of qualities and quantities of PLB using the integrated framework suggest that PL from Bethel Farm could produce better-quality PLB at a higher pyrolysis temperature and bedding material mixture to control N and P runoff problems.