A cross-section analytical study was conducted to evaluate the risk of pesticide exposure to those applying the Class II pesticides 2,4-D and paraquat in the paddy-growing areas of Kerian, Perak, Malaysia. It investigated the influence of weather on exposure as well as documented health problems commonly related to pesticide exposure. Potential inhalation and dermal exposure for 140 paddy farmers (handlers of pesticides) were assessed. Results showed that while temperature and humidity affected exposure, windspeed had the strongest impact on pesticide exposure via inhalation. However, the degree of exposure to both herbicides via inhalation was below the permissible exposure limits set by United States National Institute of Occupational Safety and Health (NIOSH). Dermal Exposure Assessment Method (DREAM) readings showed that dermal exposure with manual spraying ranged from moderate to high. With motorized sprayers, however, the level of dermal exposure ranged from low to moderate. Dermal exposure was significantly negatively correlated with the usage of protective clothing. Various types of deleterious health effects were detected among users of manual knapsack sprayers. Long-term spraying activities were positively correlated with increasing levels of the gamma-glutamyl transpeptidase (GGT) liver enzyme. The type of spraying equipment, usage of proper protective clothing and adherence to correct spraying practices were found to be the most important factors influencing the degree of pesticide exposure among those applying pesticides.
26 May 2016 in Environmental Science and Pollution Research
Environmental Context. Surfactants are present in all atmospheric aerosols with potential effects on surface tension, cloud droplets and even human health. They appear to be anionic and associated with yellow aqueous extracts, suggesting a humic-like character. These surfactants are probably derived from the oxidation of combustion-generated soot (from vehicles and forest fires). The concentration of surfactants in aerosols was determined at several sites in South East Asia, Bangi, Penang and Kota Kinabalu in Malaysia and Bangkok, Thailand, as methylene blue active substances (MBAS) and ethyl violet active substances (EVAS) for anionic surfactants and disulphine blue active substances (DBAS) for cationic surfactants. The methodology used is based on the formation of extractable ion-association complexes of surfactants and dye in organic solvents followed by spectrometric measurement of the intensity of the extracted coloured complex. Results showed surfactants in aerosols are mostly in the anionic form as MBAS and EVAS, and higher in aerosols collected in congested areas, especially in times of forest fires. Concentrations are in the range of 34.6 to 285.0 pmol m-3 for MBAS and 129.9 to 932.2 pmol m-3 for EVAS. Several different types of soot and humic acid seem possible sources of surfactants in atmospheric aerosols. Laboratory experiments suggested that combustion products, especially from motor vehicles, are important primary sources of surfactants in aerosols. There is also some laboratory evidence that there are secondary sources for these surfactants in aerosols, possibly humic-like substances (HULIS) from the oxidation and photochemical reaction of soots and humic acid.
Concentrations of particulate matter (PM) in Dhaka, Bangladesh, during November 2013 to April 2014 were found 7-8 times higher than the World Health Organization (WHO) guideline value. Probability of contribution of transboundary sources to this PM pollution was investigated through different approaches. Ninety-six-hour backward trajectories with every 3-hour interval were computed and clustered into 06 groups based on angle distance matrix. Probabilities of individual cluster to be associated with different ranges of coarse and fine particles were studied. Gazipur station near Dhaka city was found to have 68% probability of receiving PM10concentration higher than 150 μg/m3when air masses followed the route of Middle East through the Himalayan valley to the station. This channel was identified as the main route of PM transport to Bangladesh during dry season. Transboundary source-regions were spotted by concentration weighted trajectory (CWT) method and also by the monthly average aerosol optical depths (AOD) over South Asia. North-western Indian regions, Nepal and its neighboring areas, and Indian state of West Bengal were identified as the most probable zones that might have contributed to PM pollution in Gazipur, Dhaka. November to January was the high time the station had experienced fine particles from those transboundary regions.