The Virulundo carbonatite in Angola is one of the largest in the world and contains pyrochlore as an accessory mineral in all of the carbonatite units (calciocarbonatites, ferrocarbonatites, carbonatite breccias and trachytoids). The primary magmatic pyrochlore is fluorine dominant and typically contains about equal molar quantities of Ca and Na at the A site. High-temperature hydrothermal processes have resulted in the pseudomorphic replacement of the primary pyrochlore by a second generation of pyrochlore with less F and Na. Low-temperature hydrothermal replacement of the first and second generation pyrochlore, associated with quartz-carbonate-fluorite vein formation in the carbonatite, has produced a third generation of pyrochlore, with a high Sr content. The Sr appears to have been released by low-temperature hydrothermal replacement of the primary magmatic carbonates. Finally, supergene alteration processes have produced late-stage carbonates, goethite, hollandite and rare earth element (REE) minerals (mainly synchysite-(Ce), britholite-(Ce), britholite-(La), cerite-(Ce)). Cerium separated from the other REE s in oxidizing conditions and Ce4+ was incorporated into a late generation of supergene pyrochlore, which is strongly enriched in Ba and strongly depleted in Ca and Na.
The Traspena meteorite fell on 18 January 2021 about 20 km southeast of the city of Lugo (Galiza, Spain), shortly after a huge and bright fireball crossed the sky for 4.84 seconds. Astrometric measurements obtained from the fireball cameras of the Universidade de Santiago de Compostela (USC) as well as from many casual videos were used to determine the atmospheric trajectory of this meteoroid which penetrated the atmosphere and generated sound waves that were detected at three seismic stations. The original meteoroid had a diameter of about 1.15 m and a mass around 2620 kg. It impacted the Earth’s atmosphere with a steep entry angle of about 76.○7 from a height of 75.10 km until fading away at 15.75 km with a velocity of 2.38 km s−1. Before the impact, this small asteroid was orbiting the Sun with a semimajor axis of 1.125 au, a moderate eccentricity of 0.386 and a low inclination of 4.○55. A weak evidence of dynamic link with the PHA (Potential Hazardous Asteroid) Minos was investigated. During the atmospheric entry, two major fragmentation events occurred between heights of 35 and 29 km at aerodynamic pressures between 1 and 5 MPa. The strewn field was computed after calculating the individual dark flights of the main body along with two smaller fragments. Fortunately, two months after the fireball, a 527 g meteorite was found. It was examined using several geochemical and petrographic analyses which allowed us to classify it as a moderately shocked (S3) L5 ordinary chondrite with a bulk density of 3.25 g cm−3.
The origin of intraplate carbonatitic to alkaline volcanism in Africa is controversial. A tectonic control, i.e., decompression melting associated with far-field stress, is suggested by correlation with lithospheric sutures, repeated magmatic cycles in the same areas over several million years, synchronicity across the plate, and lack of clear age progression patterns. Conversely, a dominant role for mantle convection is supported by the coincidence of Cenozoic volcanism with regions of lithospheric uplift, positive free-air gravity anomalies, and slow seismic velocities. To improve constraints on the genesis of African volcanism, here we report the first radiometric and isotopic results for the Catanda complex, which hosts the only extrusive carbonatites in Angola. Apatite (U-Th-Sm)/He and phlogopite 40Ar/39Ar ages of Catanda aillikite lavas indicate eruption at ca. 500–800 ka, more than 100 m.y. after emplacement of abundant kimberlites and carbonatites in this region. The lavas share similar high-μ (HIMU)–like Sr-Nd-Pb-Hf isotope compositions with other young mantle-derived volcanics from Africa (e.g., Northern Kenya Rift; Cameroon Line). The position of the Catanda complex in the Lucapa corridor, a long-lived extensional structure, suggests a possible tectonic control for the volcanism. The complex is also located on the Bié Dome, a broad region of fast Pleistocene uplift attributed to mantle upwelling. Seismic tomography models indicate convection of deep hot material beneath regions of active volcanism in Africa, including a large area encompassing Angola and northern Namibia. This is strong evidence that intraplate late Cenozoic volcanism, including the Catanda complex, resulted from the interplay between mantle convection and preexisting lithospheric heterogeneities.