The Eureka deposit in Castell-estaó in the Catalan Pyrenees is a Cu–U–V deposit, hosted by Triassic red-bed sandstones, and classified here as a low-temperature, sandstone-hosted stratabound metamorphite U deposit. The main mineralisation is stratabound, related to coal-bearing units and produced during the Alpine deformation by migration of hydrothermal fluids. In this stage, the original sedimentary and diagenetic components (quartz and calcite, micas, hematite and locally apatite) were replaced by a complex sequence of roscoelite, fine-grained REE phosphates, sulphides and Ni–Co arsenides and sulpharsenides, Ag–Pb selenides, bismuth phases, sulphosalts and uraninite. The black shales of the Silurian sediments underlying the deposit and the nearby Carboniferous volcanoclastic rocks are interpreted as the source of the redox-sensitive elements concentrated in Eureka. The sulphur source is related to leaching of the evaporitic Keuper facies. The REE transport would be facilitated by SO₄-rich solutions. The reduction of these solutions by interaction with organic matter resulted in the widespread precipitation of REE and redox-sensitive elements, including many critical metals (V, Bi, Sb, Co), whereas barite precipitated in the oxidized domains. The occurrence of similar enrichments in critical elements can be expected in other similar large uranium deposits, which could be a source of these elements as by-products.

The essential role of Critical Elements (CE) in 21st century economy has led to an increasing demand of these metals and promotes the exploration of non-conventional deposits such as weathering profiles. The present work is focused on the study of a weathering profile located at the Archaeological Park of the Gavà Neolithic Mines, Barcelona, Catalonia, Spain. In the Gavà deposit, acid and oxidising meteoric fluids generated intense weathering during the early Pleistocene, affecting series of Llandoverian black shales and associated syn-sedimentary phosphates. The circulation of these acid fluids at deeper levels of the profile generated supergene vein-like mineralisations comprised of secondary phosphates (e.g., variscite, perhamite, crandallite, phosphosiderite) and sulphates (e.g., jarosite, alunite). This supergene mineralisation is significantly enriched in certain CE (e.g., Ga, Sc, REE, In, Co and Sb) that were mobilised from host rock components and later hosted in the crystal lattice of supergene minerals. Weathering processes and corresponding supergene enrichment of CE at the Gavà deposit could be used as an example to determine exploration guidelines of CE in weathering profiles and associated supergene phosphates worldwide.