Nowadays, waste tire rubber (WTR) management is a growing and serious problem. Therefore, research works focused on the development of cost-effective and environmentally-friendly methods of WTR recycling are fully justified. Incorporation of WTR into polymer matrices and composite materials attracts much attention, because this approach allows sustainable development of industrially applicable waste tires recycling technologies. Generally, utilization of WTR as a filler for polymer composites noticeably reduces materials costs, while suitable modification/functionalization of WTR may significantly enhance the performance of plastics and rubbers. This work aims to summarize the literature reports related to the thermoset/WTR composites based on various matrices such as: polyurethanes, epoxy and other resins. It particularly focuses on compatibilization strategies in thermosets/WTR systems and their impact on the chemistry and physical interfacial interactions between thermoset matrix and WTR filler phase, what significantly affecting performance properties of prepared materials. Moreover, future trends and limitation related to thermoset/WTR composites development are discussed.
Composites containing natural fibers are considered environmentally friendly materials which is related to the reduced use of fossil fuels and the emission of carbon dioxide compared to petroleum-based polymers. Nevertheless, a complete evaluation of their environmental impact requires a broader view. This paper presents a carbon, ecological, and water footprints assessment of polypropylene-based composites filled with cotton, jute, and kenaf fibers based on a standardized European pallet (EUR-pallet) case study. Obtained results were compared with unmodified polypropylene and composite with glass fibers. Incorporation of 30 wt% of cotton, jute, and kenaf fibers into a polypropylene matrix reduced its carbon footprint by 3%, 18%, and 18%, respectively. Regarding the ecological footprint, an 8.2% and 9.4% reduction for jute and kenaf fibers were noted, while for cotton fibers, its value increased by 52%. For these footprints, the use of jute and kenaf fibers was more beneficial than glass fibers. Nevertheless, the application of natural fibers caused a 286%, 758%, and 891% drastic increase of water footprint of the final product, which was mainly affected by cultivation and irrigation of crops. Therefore, in a holistic view, the incorporation of natural fibers into the polypropylene matrix definitely cannot be impartially considered as an environmentally friendly solution.
Wood-polymer composites technologies are gaining more and more attention in the scientific community, positively affecting the increase in their industrial applications, for example, automotive, building, 3D printing, etc. Many research works are focused on the improvement in matrix–lignocellulosic filler interactions to produce highly filled composites with satisfying performance properties. In this field of research, using isocyanates due to their versatile structure and functionality seems to be a very promising approach. This paper aims at reporting on recent advances in compatibilization strategies of wood-polymer composites by isocyanates. Particular attention is focused on the correlation between isocyanate structure, as well as modification conditions on the matrix–lignocellulosic filler interactions and their impact on the structure–property relationships of wood-polymer composites. Furthermore, limitations and future research trends related to applications of isocyanate to wood-polymer composites technologies are also discussed.
This paper presents a water footprint assessment of polymers, polymer blends, composites, and biocomposites based on a standardized EUR-pallet case study. The water footprint analysis is based on life cycle assessment (LCA). The study investigates six variants of EUR-pallet production depending on the materials used. The system boundary included the production of each material and the injection molding to obtain a standardized EUR-pallet of complex properties. This paper shows the results of a water footprint of six composition variants of analyzed EUR-pallet, produced from biocomposites and composites based on polypropylene, poly(lactic acid), cotton fibers, jute fibers, kenaf fibers, and glass fibers. Additionally, a water footprint of applied raw materials was evaluated. The highest water footprint was observed for cotton fibers as a reinforcement of the analyzed biocomposites and composites. The water footprint of cotton fibers is caused by the irrigation of cotton crops. The results demonstrate that the standard EUR-pallet produced from polypropylene with glass fibers as reinforcement can contribute to the lowest water footprint.
19 February 2018 in The International Journal of Life Cycle Assessment
Purpose The purpose of the study was to perform a comparative life cycle assessment of current and future electricity generation systems in the Czech Republic and Poland. The paper also outlines the...
The recycling of plastics is currently one of the most significant industrial challenges. Due to the enormous amounts of plastic wastes generated by various industry branches, it is essential to look for potential methods for their utilization. In the presented work, we investigated the recycling potential of wastes originated from the agricultural films recycling line. Their structure and properties were analyzed, and they were modified with 2.5 wt % of commercially available compatibilizers. The mechanical and thermal performance of modified wastes were evaluated by tensile tests, thermogravimetric analysis, and differential scanning calorimetry. It was found that incorporation of such a small amount of modifiers may overcome the drawbacks caused by the presence of impurities. The incorporation of maleic anhydride-grafted compounds enhanced the tensile strength of wastes by 13–25%. The use of more ductile compatibilizers—ethylene-vinyl acetate and paraffin increased the elongation at break by 55–64%. The presence of compatibilizers also reduced the stiffness of materials resulting from the presence of solid particles. It was particularly emphasized for styrene-ethylene-butadiene-styrene and ethylene-vinyl acetate copolymers, which caused up to a 20% drop of Young’s modulus. Such effects may facilitate the further applications of analyzed wastes, e.g., in polymer film production. Thermal performance was only slightly affected by compatibilization. It caused a slight reduction in polyethylene melting temperatures (up to 2.8 °C) and crystallinity degree (up to 16%). For more contaminated materials, the addition of compatibilizers caused a minor reduction in the decomposition onset (up to 6 °C). At the same time, for the waste after three washing cycles, thermal stability was improved. Moreover, depending on the desired properties and application, materials do not have to go through the whole recycling line, simplifying the process, reducing energy and water consumption. The presented results indicate that it is possible to efficiently use the materials, which do not have to undergo the whole recycling process. Despite the presence of impurities, they could be applied in the manufacturing of products which do not require exceptional mechanical performance.